Petrography, geochemistry, and geochronology of granitoid rocks in the Neoproterozoic-Paleozoic Lufilian–Zambezi belt, Zambia: Implications for tectonic setting and regional correlation

There are several pre-orogenic Neoproterozoic granitoid and metavolcanic rocks in the Lufilian–Zambezi belt in Zambia and Zimbabwe that are interpreted to have been emplaced in a continental-rift setting that is linked to the break-up of the Rodinia supercontinent. However, no geochemical data were previously available for these rocks in the Zambian part of the belt to support this model. We conducted petrographic and whole-rock chemical analyses of the Neoproterozoic Nchanga Granite, Lusaka Granite, Ngoma Gneiss and felsic metavolcanic rocks from the Lufilian–Zambezi belt in Zambian, in order to evaluate their chemical characteristics and tectonic settings. Other magmatic rocks of importance for understanding the evolution of the belt in Zambia, included in this study, are the Mesoproterozoic Munali Hills Granite and associated amphibolites and the Mpande Gneiss. The Neoproterozoic rocks have monzogranitic compositions, aluminum-saturation indices (ASI) < 1.1, and high contents of high field strength elements (HFSE) and rare earth elements (REE). The chondrite-normalised spider diagrams are similar to those of A-type granites from the Lachlan fold belt and show negative Sr, P, and Ti anomalies. On various tectonic discrimination diagrams the Neoproterozoic rocks plot mainly in A-type granite fields. These petrographic and trace element compositions indicate that these rocks are A-type felsic rocks, but they do not have features of granites and rhyolites emplaced in true continental-rift settings, as previously suggested. On the basis of the A-type features and independent regional geological and geochronological data, we suggest that the Neoproterozoic granitoid and felsic metavolcanic rocks were emplaced during the earliest extensional stages of continental rifting in the Lufilian–Zambezi belt. The apparent continental-arc like chemistry of the granitoid and felsic metavolcanic rocks is thus inferred to be inherited from calcalkaline sources. The Mesoproterozoic Munali Hills Granite and Mpande Gneiss have trace element features e.g., Nb–Ta depletions, which indicate that that these gneisses were emplaced in a convergent-margin setting. The MORB-normalised spider diagram of co-magmatic amphibolites exhibit a fractionated LILE/HFSE pattern recognized in subduction zones. This inference is consistent with remnants of ocean crust, juvenile Island arcs and ophiolites elsewhere in the Mesoproterozoic Irumide belt in Zambia and Zimbabwe. In addition, we report the first U–Pb zircon age of 1090.1 ± 1.3 Ma for the Munali Hills Granite. The age for the Munali Hills Granite provides new constraints on correlation and tectono-thermal activity in the Lufilian–Zambezi belt. The age of the Munali Hills Granite indicates that some supracrustal rocks in the Zambezi belt of Zambia, which were previously thought to be Neoproterozoic and correlated with the Katanga Supergroup in the Lufilian belt, are Mesoproterozoic or older. Consequently, previous regional lithostratigraphic correlations in the Lufilian–Zambezi belt would require revision.     

Changes in the geomagnetic field and solar wind — causes of changes of climate and atmospheric circulation

Summary The analyses of various types of geomagnetic and atmospheric manifestations have disclosed certain associations. The agreement in the occurrence of the increased spectral densities as regards geomagnetic activity and the variations of atmospheric pressure over the geomagnetic pole proves the relation between their periodicities. The results imply that the changes in the intensity of corpuscular radiation, indicated by geomagnetic activity, affect the pressure patterns over the geomagnetic pole and polar region significantly, so that a pronounced modification of the general circulation may take place, as shown schematically in Figs 14a,b.Dedicated to Prof. RNDr. Emil Buchar, DrSc., Corresponding Member of the Czechoslovak Academy of Sciences, on the Occasion of His 75^th Birthday     

Coastal morphometry as regulator of water exchange—a Swedish example

This is a paper from the Swedish research project ‘The coastal zone—scientific criteria for planners’. The goal has been to establish simple, general scientific methods for management of Swedish coastal waters. In this paper the focus is on a set of empirical data from 21 so-called type areas and on the exchange of surface water. The working hypothesis has been that the water retention (or residence) time is regulated by the morphometry. The theory has been verified. It has been shown that the water retention time can be determined from a formula based on only two key morphometric parameters, the exposure and the mean coastal width. It provides an 86% degree of explanation (r²=0·86) of the variation in empirically determined retention times and can be physically linked to the basic mass balance equation. The formula is valid for the bioproductive season (May–Oct.) and for small (1–100 km²) Swedish coastal areas. It cannot be directly applied to areas affected by heavy tides.     

Beta diversity of tropical marine benthic assemblages in the Spermonde Archipelago, Indonesia

In order to preserve diversity it is essential to understand how assemblages change across space. Despite this fact, we still know very little about how marine diversity is spatially distributed, especially among lesser‐studied invertebrate taxa. In the present study beta‐diversity patterns of sea urchins, sponges, mushroom corals and larger foraminifera were assessed in the Spermonde Archipelago (Indonesia). Using ordinations we showed that the inshore zone (<5 km offshore), midshore zone (5 < x < 30 km offshore) and distance offshore zone (>30 km offshore) all contained distinct assemblages of sponges and corals, while only foraminifera assemblages from the inshore (<5 km offshore) zone were distinct. There was a significant spatial pattern of community similarity for all taxa surveyed, but this pattern proved to be wholly related to environmental variables for sponges and foraminifera, and primarily for mushroom corals and sea urchins. The lack of a pure spatial component suggests that these taxa may not be dispersal limited within the spatial scales of this study (c. 1600 km²). The analyses of the corals and foraminifera were additionally tested at two spatial scales of sampling. Both taxa were primarily associated with local‐scale environmental variables at the local scale and larger‐scale variables at the larger scale. Mean inter‐plot similarity was also higher and variation lower at the larger scale. The results suggest that substantial variation in similarity can be predicted using simple locally assessed environmental variables combined with remotely sensed parameters.     

Scanning reflectance spectroscopy (380–730 nm): a novel method for quantitative high-resolution climate reconstructions from minerogenic lake sediments

High-resolution (annual to sub-decadal) quantitative reconstructions of climate variables are needed from a variety of paleoclimate archives across the world to place current climate change in the context of long-term natural climate variability. Rapid, high-resolution, non-destructive scanning techniques are required to produce such high-resolution records from lake sediments. In this study we explored the potential of scanning reflectance spectroscopy (VIS-RS; 380–730 nm) to produce quantitative summer temperature reconstructions from minerogenic sediments of proglacial, annually laminated Lake Silvaplana, in the eastern Swiss Alps. The scanning resolution was 2 mm, which corresponded to sediment deposition over 1–2 years. We found correlations up to r = 0.84 (p < 0.05) for the calibration period 1864–1950, between six reflectance-dependent variables and summer (JJAS) temperature. These reflectance-dependent variables (e.g. slope of the reflectance 570/630 nm, indicative of illite, biotite and chlorite; minimum reflectance at 690 nm indicative of chlorite) indicate the mineralogical composition of the clastic sediments, which is, in turn, related to climate in the catchment of this particular proglacial lake. We used multiple linear regression (MLR) to establish a calibration model that explains 84% of the variance of summer (JJAS) temperature during the calibration period 1864–1950. We then applied the calibration model downcore to develop a quantitative summer temperature reconstruction extending back to AD 1177. This temperature reconstruction is in good agreement with two independent temperature reconstructions based on documentary data that extend back to AD 1500 and tree ring data that extend back to AD 1177. This study confirms the great potential of in situ scanning reflectance spectroscopy as a novel non-destructive technique to rapidly acquire high-resolution quantitative paleoclimate information from minerogenic lake sediments.     

Climate Change Policy Targets and the Role of Technological Change

In this paper, we present results of simulationexperiments with the TIME-model on the issue ofmitigation strategies with regard to greenhouse gases.The TIME-model is an integrated system dynamics worldenergy model that takes into account the fact that the systemhas an inbuilt inertia and endogenouslearning-by-doing dynamics, besides the more commonelements of price-induced demand response and fuelsubstitution. First, we present four scenarios tohighlight the importance of assumptions on innovationsin energy technology in assessing the extent to whichCO₂ emissions have to be reduced. The inertia ofthe energy system seems to make a rise ofCO₂ emissions in the short term almostunavoidable. It is concluded that for the populationand economic growth assumptions of the IPCC IS92ascenario, only a combination of supply- anddemand-side oriented technological innovations incombination with policy measures can bring the targetof CO₂-concentration stabilization at 550 ppmv bythe year 2100 within reach. This will probably beassociated with a temporary increase in the overallenergy expenditures in the world economy. Postponingthe policy measures will be more disadvantageous,and less innovation in energy technology willhappen.     

Pilot-Scale Electrochemical Treatment of a 1,4-Dioxane Source Zone

Electrochemical treatment is a promising emerging technology in which direct current is applied to drive the degradation of aqueous contaminants. Several bench-scale studies have demonstrated the capability of electrochemical oxidation to fully mineralize refractory organics such as pesticides and perfluorinated compounds. However, insights into large-scale design and field performance are critically lacking. Here, we designed six pilot-scale reactors and tested their performance and efficiency for the treatment of groundwater contaminated with 1,4-dioxane (1,4-DX) at concentrations exceeding 1000 mg/L. Anode surface area-normalized degradation rates increased with increasing potential applied, while the process was more energy-efficient per mass unit removed at low potentials. While not all 1,4-DX was completely mineralized, the detected ring-opening intermediates are known to be readily biodegradable. Analyses of potential by-products from chloride oxidation revealed the generation of chloromethanes and perchlorate at low mg/L concentrations. Towards the end of the 8.5-month pilot test, decreasing currents and degradation rates indicated progressing passivation of the electrodes, likely due to cathodic carbonate precipitation and/or poisoning by the uniquely high organic carbon load of this source zone groundwater. The findings of our study demonstrate that electrochemical groundwater remediation is a capable approach for the treatment of persistent organic pollutants. Our pilot-scale test provides practitioners with a basis for evaluating its efficiency under site-specific conditions and collecting critical performance metrics for technology scale-up.