The western end of the Eoalpine High‐Pressure Belt (Texel unit,South Tyrol / Italy)

Eclogites in the Texel Unit (Eastern Alps; South Tyrol, Italy) represent the westernmost outcrops of the E–W striking Eoalpine High‐Pressure Belt (EHB). East of the Tauern Window, the EHB forms part of a Cretaceous intracontinental south‐dipping subduction/collision zone; however, the same nappe stack displays a northwest dip at its western end. This prominent change in dip direction gave rise to discussions on the general setting of the Eoalpine collision. Based on our own observations and literature data, we present a new tectonic model for the western end of the EHB. Due to the special situation of this area at the tip of the Southalpine indenter, originally south(east) dipping structures became overturned, and former thrusts appear as normal faults (e.g. Schneeberg fault zone) while former normal faults presently display thrust geometries (e.g. Jaufen fault). Thus, we explain the current configuration with a coherent Eoalpine subduction direction.     

Die Reaktion 2 Zoisit+1 CO2 ⇌ 3 Anorthit+1 Calcit+1 H2O

The equilibrium conditions of the following reaction 2 zoisite +1 CO₂?3 anorthite+1 calcite+1 H₂O 2 Ca₂Al₃[O/OH/SiO₄/Si₂O₇]+1 CO₂?3 CaAl₂Si₂O₈+1 CaCO₃+1 H₂O have been determined experimentally at total pressures of P _j= 2000 bars, P _f =5000 bars, and P _f =7000 bars. Owing to the vertical position of the equilibrium curves in isobaric T- \(X_{{\text{CO}}_{\text{2}} }\) diagrams, the composition of the binary H₂O-CO₂ fluid phase coexisting with zoisite is independent of temperature in the temperature interval investigated. According to our experiments, orthorhombic zoisite is only stable in equilibrium with a fluid phase at a concentration of CO₂ which is less than, respectively, ca. 2 Mol% CO₂ at P _f =2000 bars, ea. 6 Mol% at P _f =5000 bars, and ca. 10 Mol% at P _f =7000 bars. Thus, the fluid phase coexisting with zoisite is rich in H₂O. While this is independent of temperature the experimental data demonstrate that the influence of pressure cannot be neglected: With increasing pressure the concentration of CO₂ of the fluid phase coexisting with zoisite can rise a little. The position of the reaction studied, which is independent of temperature and exhibits small values of \(X_{{\text{CO}}_{\text{2}} }\) ,leads to two important petrogenetic conclusions:

1. The occurrence of zoisite is an indicator for a CO₂-poor and H₂O-rich fluid composition during metamorphism of marly calcsilicates.
2. If the concentration of CO₂ of the fluid phase coexisting with zoisite exceeds the equilibrium value of \(X_{{\text{CO}}_{\text{2}} }\) calcite+anorthite+H₂O is formed from zoisite+CO₂. Thus, a considerable increase in the anorthite-content of plagioelase is possible.

     

Impact of an 0.2 km3 Rock Avalanche on Lake Eibsee (Bavarian Alps,Germany) – Part I: Reconstruction of the paleolake and Effects of the Impact

Rock avalanches destroy and reshape landscapes in only a few minutes and are among the most hazardous processes on Earth. The surface morphology of rock avalanche deposits and the interaction with the underlying material are crucial for runout properties and reach. Water within the travel path is displaced, producing large impact waves and reducing friction, leading to long runouts. We hypothesize that the 0.2 km³ Holocene Eibsee rock avalanche from Mount Zugspitze in the Bavarian Alps overran and destroyed Paleolake Eibsee and left a unique sedimentological legacy of processes active during the landslide. We captured 9.5 km of electrical resistivity tomography (ERT) profiles across the rock avalanche deposits, with up to 120 m penetration depth and more than 34 000 datum points. The ERT profiles reveal up to ~50 m thick landslide debris, locally covering up to ~30 m of rock debris with entrained fine-grained sediments on top of isolated remnants of decametre-wide paleolake sediments. The ERT profiles allow us to infer processes involved in the interaction of the rock avalanche with bedrock, lake sediments, and morainal sediments, including shearing, bulging, and bulldozing. Complementary data from drilling, a gravel pit exposure, laboratory tests, and geomorphic features were used for ERT calibration. Sediments overrun by the rock avalanche show water-escape structures. Based on all of these datasets, we reconstructed both position and size of the paleolake prior to the catastrophic event. Our reconstruction of the event contributes to process an understanding of the rock avalanche and future modelling and hazard assessment. Here we show how integrated geomorphic, geophysical, and sedimentological approaches can provide detailed insights into the impact of a rock avalanche on a lake. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Modelling transport dynamics of contaminated sediments in the headwater of a hydropower plant at the Upper Rhine River

Sediments are an essential habitat compartment in rivers, which is a subject to dynamic transport processes. In many rivers, the fine deposited sediments are contaminated with heavy metals and organic compounds. Contaminated deposits are considered as potential hot spots because of the risk of the mobilization under erosive hydraulic conditions. Numerical models for particulate contaminant transport are then necessary and can be applied to estimate and predict the potential impact of mobilized contaminants as an important contribution to sediment management. This paper focuses on the quantification of the amount of contaminated sediments resuspended during the extreme flood event in 1999 and the prediction of deposition one year after the flood event. To assess such erosive flood event, a 2D numerical transport model was developed to analyse the dynamics of erosion and sedimentation processes in the headwater of a cross dam at the Upper Rhine River. The dam consists of a weir, a hydropower plant, and a navigation lock. As the weir is operating only for flood management, a huge amount of sediment highly contaminated with the hexachlorobenzene (HCB) was deposited in the weir zone. Therefore, numerical simulations were performed to determine the spatial and temporal distribution of deposited contaminated sediments as depending on the river discharge and its distribution to the hydraulic structures. The numerical investigation presented here is taken as a retrospective analysis of the contaminated sediment dynamics in the headwater to improve future sediment management.     

煤系有机质多阶段成气的分子碳同位素表征及其对高过成熟干酪根生气潜力评价的启示

采用开放体系在线程序升温裂解-色谱-碳同位素比值质谱技术(PY/GC-IRMS)考察了煤系有机质热演化过程中甲烷瞬时生成速率与碳同位素组成特征,提出煤系有机质不同热演化进程甲烷生成的四个阶段:生油窗阶段、主生气阶段、晚期生气阶段(芳环侧链断裂)、开环-缩聚作用阶段.以一级反应动力学为基础,采用高斯分布算法,计算了各阶段甲烷产出的动力学参数.研究结果对煤成气资源量的正确评价,特别是近年来有机质高演化阶段成气潜力的评价具有重要指示意义.     

Identification of groundwater recharge sources and processes in a heterogeneous alluvial aquifer: results from multi‐level monitoring of hydrochemistry and environmental isotopes in a riverside agricultural area in Korea

We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO₃^? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO₃^?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ¹⁸O and δ²H values of groundwater were also different between the two zones. Hydrochemical and δ¹⁸O? δ²H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO₃^?. The ³H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ¹⁸O and δ²H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Characterisation of deformation and flow mechanics around porphyroclasts in a calcite marble ultramylonite by means of EBSD analysis

This paper studies the flow heterogeneity around porphyroclasts associated with greenschist facies deformation of a calcite marble shear zone. Microstructural data from electron backscatter diffraction analyses (EBSD) are used to constrain the flow mechanics of this dominantly non-coaxial type of deformation. The microstructure of the undisturbed ultramylonite (grain-size range 5–100 μm, mean 40 μm) is interpreted to represent steady-state (time-independent) flow conditions with flow planes parallel to the shear zone boundary. Single calcite porphyroclasts (grain-size 1–3 mm) caused flow perturbation in the fine-grained marble ultramylonite. It is the shape, in particular, of these rigid porphyroclasts that controls their rotational behaviour during deformation and, therefore, the development of specific flow fabrics. The flow planes around elongated-rhomboidal, stable porphyroclasts change the orientation to become roughly parallel to the porphyroclast margin, whereas the geometry of flow planes around nearly equant, rotating porphyroclasts describes a δ-type flow pattern. We infer that to some extent decoupling at the clast–matrix interface has occurred to guarantee a stable orientation of elongated porphyroclasts, but was not sufficient to reduce the rotation rate of equant clasts to zero. According to the flow deflection, the general crystallographic preferred orientation (CPO) with its single c-axis maximum perpendicular to the flow plane is rotated about an axis which is (sub)parallel to the kinematic rotation axis of the shear zone. Ultramylonite microstructures, CPOs and misorientation data are best explained by the dual operation of grain-size-insensitive (dislocation creep with recovery and recrystallization) and grain-size-sensitive (diffusion creep) mechanisms. The limited grain-size reduction around porphyroclasts suggests that the grain-size-insensitive mechanisms controlled rheology.     

Late‐stage deformation in a collisional orogen (Western Alps): nappe refolding,back‐thrusting or normal faulting?

ABSTRACT Nappe refolding, back-thrusting and normal faulting frequently cause severe late-stage overprinting of the architecture of an orogen. A combined investigation of nappe stack polarity, kinematics of shearing and metamorphic gradients in the Western Alps develops criteria for distinguishing between these three modes of late-stage deformation. This distinction is a prerequisite for any retro-deformation necessary for understanding the main tectonic and metamorphic evolution of collisional orogens. In the case of the Western Alps overprint was by mega-scale nappe refolding in the Oligocene. This implies exhumation of the HP-rocks prior to postnappe folding, i.e. during nappe stacking and by foreland-directed ascent within a subduction channel.     

Real-time raster projection for web maps

The virtual globe is the default visualization for Digital Earth applications, but it can only show one half of the Earth. This article introduces user-adjustable, on-the-fly projection of georeferenced raster images for web mapping and web GIS applications. This technique allows users to center a map on arbitrary locations, while still seeing the entire Earth surface. Modern web mapping libraries can apply map projection transformations to vector data in the browser, but they do not currently support the projection of raster images at interactive frame rates. We use the cross-platform WebGL (Web Graphics Library) graphics pipeline for hardware-accelerated projection of raster data in web browsers. Two algorithmic techniques – inverse per-fragment projection, and combined forward per-triangle and inverse per-fragment projection – for georeferenced raster imagery are documented. The resulting raster maps combine the ease of use and flexibility of interactive virtual globes with the ability to show the entire Earth. The adjustable projection of raster imagery allows users to observe global phenomena that are difficult to visualize on virtual globes or traditional maps with static projections.     

XFEM,strong discontinuities and second-order work in shear band modeling of saturated porous media

We investigate shear band initiation and propagation in fully saturated porous media by means of a combination of strong discontinuities (discontinuities in the displacement field) and XFEM. As a constitutive behavior of the solid phase, a Drucker–Prager model is used within a framework of non-associated plasticity to account for dilation of the sample. Strong discontinuities circumvent the difficulties which appear when trying to model shear band formation in the context of classical nonlinear continuum mechanics and when trying to resolve them with classical numerical methods like the finite element method. XFEM, on the other hand, is well suited to deal with problems where a discontinuity propagates, without the need of remeshing. The numerical results are confirmed by the application of Hill’s second-order work criterion which allows to evaluate the material point instability not only locally but also for the whole domain.