Investigation of the fate of nitrogen in Palaeozoic shales of the Central European Basin

Nitrogen geochemistry of Upper Carboniferous shales from the Central European Basin (CEB) was investigated by elemental analysis, stable isotope mass spectrometry and non-isothermal pyrolysis. Total N-contents of Namurian shales from four deep wells (4400–7000 m) in NE Germany ranged between 520 and 2680 ppm. Up to 90% of this nitrogen occurs as ammonium in minerals with δ¹⁵N values between + 1‰ and + 3.5‰. Low nitrogen contents (down to 460 ppm) and high δ¹⁵N values (up to + 5.6‰) in one well in the basin centre suggest a large-scale release of nitrogen associated with isotopic fractionation. Pyrolytic liberation of N₂ from pelagic Namurian A shales of NW and NE Germany occurred at significantly lower temperatures than from paralic Namurian B shales and terrestrial Westphalian samples. On-line isotope analysis of N₂ liberated between 400 and 1200 °C indicates the presence of precursor pools with different thermal stability and nitrogen isotopic composition.     

Multi-stage thrusting at the "Penninic Front" in the Western Alps between Mont Blanc and Pelvoux massifs

The different segments of the tectonic boundary between external (European) and internal (Penninic) units in the Western Alps, the so-called Penninic Front (PF), formed at different times and according to different kinematic scenarios. During a first episode (Eocene), the PF corresponds to a transpressive suture zone between Penninic and European units. North- to NNW-trending stretching lineations, found along internal nappe contacts within the Penninic units, are related to this episode. This subduction zone was sealed by the Priabonian flysch of the Aiguilles d'Arves, a detrital trench formation that formed during the final stages of subduction. During a second episode, starting in mid-Oligocene times, the PF, imaged along the ECORS-CROP profile, acted as a WNW-directed thrust. This thrust, the Roselend Thrust (RT), only partially coincides with the PF. South of Moûtiers, the RT propagates into the Dauphinois units, carrying the former Eocene PF (including the Priabonian flysch) passively in its hangingwall. South of the Pelvoux massif the RT finds its continuation along the "Briançonnais Front", an out-of-sequence thrust behind the Embrunais-Ubaye nappes. On a larger scale, our findings indicate oblique (sinistral) collision within the future Western Alps during the Eocene, followed by westward indentation of the Adriatic block.     

Stabilitätsbedingungen Grossular-führender Paragenesen im System CaO-Al2O3-SiO2-CO2-H2O

Ohne Zusammenfassung

---

Stability conditions of grossularite-bearing parageneses in the system CaO-Al₂O₃-SiO₂-CO₂-H₂O

---

Herrn Prof. Dr. H. G. F. Winkler danke ich vielmals für sein Interesse an dieser Arbeit, für anregende Diskussionen und die kritische Durchsicht des Manuskriptes. Auch den Herren Doz. Dr. P. Metz, Dr. K.-H. Nitsch und Doz. Dr. V. Trommsdorff danke ich herzlich für wertvolle Diskussionen und Hinweise. Herrn Dr. E-an Zen danke ich für einen Hinweis zur Phasentheorie und Herrn Prof. Dr. E. Schwarzmann für die Durchführung von IR-Aufnahmen. — Der Deutschen Forschungsgemeinschaft gilt mein Dank für die Arheitsmöglichkeiten an den Herrn Prof. Dr. Winkler zur Verfügung gestellten Apparaturen.     

Vertical displacement rates in the Upper Rhine Graben area derived from precise leveling

The recent vertical displacement field of the Upper Rhine Graben (URG) located in the tri-national region between Germany, France and Switzerland is investigated using repeatedly measured leveling data. We estimate vertical displacement rates at leveling benchmarks by applying a kinematic network adjustment on more than 40,000 height differences measured by German, French and Swiss surveying agencies. Focusing on an optimal solution for the adjusted rates in the URG area also historical data (measured before 1900) are used, significantly increasing the time span of available measurements and the number of transnational connections between the three countries. To account for inhomogeneities apparent in the database, we apply an iterative variance component estimation within the adjustment procedure, particularly revealing more realistic information on the accuracy of the estimated rates. A special focus within our analysis is put on the statistical testing of gross errors in the observations and model-related errors at benchmarks with non-linear movement. As some of the estimated vertical rates behave significantly different compared to the vertical rates of adjacent benchmarks, a filtering of outliers is applied after the adjustment procedure. The resulting map of linear height changes in an area of 280 km in N–S and 230 km in E–W direction provides detailed insight into the recent vertical displacements of the URG and neighboring regions. In the German part of the study area, it was possible for the first time to consistently constrain an average subsidence rate of 0.5 mm/a ( \(\pm \) 0.2 mm/a) of the Graben interior w.r.t. the Black Forest. In addition to the tectonic displacements, some man-induced surface movements, e.g., caused by oil and groundwater extraction, are observed and discussed.     

SPIRE point source photometry: within the Herschel interactive processing environment (HIPE)

The different algorithms appropriate for point source photometry on data from the SPIRE instrument on-board the Herschel Space Observatory, within the Herschel Interactive Processing Environment (HIPE) are compared. Point source photometry of a large ensemble of standard calibration stars and dark sky observations is carried out using the 4 major methods within HIPE: SUSSEXtractor, DAOphot, the SPIRE Timeline Fitter and simple Aperture Photometry. Colour corrections and effective beam areas as a function of the assumed source spectral index are also included to produce a large number of photometric measurements per individual target, in each of the 3 SPIRE bands (250, 350, 500μm), to examine both the accuracy and repeatability of each of the 4 algorithms. It is concluded that for flux densities down to the level of 30mJy that the SPIRE Timeline Fitter is the method of choice. However, at least in the 250 and 350μm bands, all 4 methods provide photometric repeatability better than a few percent down to at approximately 100mJy. The DAOphot method appears in many cases to have a systematic offset of ～8 % in all SPIRE bands which may be indicative of a sub-optimal aperture correction. In general, aperture photometry is the least reliable method, i.e. largest scatter between observations, especially in the longest wavelength band. At the faintest fluxes, <30mJy, SUSSEXtractor or DAOphot provide a better alternative to the Timeline Fitter.     

Herschel SPIRE fourier transform spectrometer: calibration of its bright-source mode

The Fourier Transform Spectrometer (FTS) of the Spectral and Photometric Imaging REceiver (SPIRE) on board the ESA Herschel Space Observatory has two detector setting modes: (a) a nominal mode, which is optimized for observing moderately bright to faint astronomical targets, and (b) a bright-source mode recommended for sources significantly brighter than 500 Jy, within the SPIRE FTS bandwidth of 446.7–1544 GHz (or 194–671 microns in wavelength), which employs a reduced detector responsivity and out-of-phase analog signal amplifier/demodulator. We address in detail the calibration issues unique to the bright-source mode, describe the integration of the bright-mode data processing into the existing pipeline for the nominal mode, and show that the flux calibration accuracy of the bright-source mode is generally within 2 % of that of the nominal mode, and that the bright-source mode is 3 to 4 times less sensitive than the nominal mode.     

Can the EU emission trading scheme support CDM forestry?

Abstract

The European Commission is mandated to consider the inclusion of credits from land-use projects under the clean development mechanism (CDM) and joint implementation (JI), beginning with the second period of the European Union's emission trading scheme (ETS) in its report due in July 2006. Temporary credits from afforestation and reforestation under the CDM are seen by many as posing a technical problem for their use under the ETS. This article summarizes three feasible, efficient and environmentally sound alternatives for achieving the integration of such temporary credits in the European emissions trading market starting in 2008. The first proposal integrates tCERs and lCERs (temporary credits) into the EU ETS by allowing for their direct use for compliance purposes. The second proposal builds on the idea of swapping temporary credits for EU allowances (EUAs) by Member States. The third proposal would not require a political decision at the EU level. Instead supportive Member States or private carbon fund operators would agree to swap temporary credits for the CERs or ERUs they hold in their accounts. All three solutions would be linked to a risk-mitigation strategy based on levying a fee or fixing an exchange rate, which would allow governments to hedge the risk of losing temporary credits.     

Stock changes or fluxes? Resolving terminological confusion in the debate on land-use change and forestry

Abstract

This article collates definitions of some key terms commonly used in greenhouse gas reporting and accounting for the Land Use, Land-Use Change and Forestry (LULUCF) sector, and highlights areas of ambiguity and divergent interpretations of key concepts. It uses the example of harvested wood products to demonstrate the impact of different interpretations. The objective is to facilitate clear communication amongst negotiators and practitioners in relation to the terms emissions, removals, sources and sinks. Confusion and misunderstandings that have arisen in the past are rooted in diverging interpretations of the terms ‘emissions’ and ‘removals’ in the context of land use and wood products. One interpretation sees emissions and removals to be approximated by a change in carbon stocks in a number of selected carbon pools that may include or exclude harvested wood products. Another interpretation views emissions and removals as gross fluxes between the atmosphere and the land/wood products system. The various alternative approaches that have been proposed for reporting for harvested wood products are applicable to one or the other of these interpretations: the stock-change and production approaches, focused on stock changes, are applicable to the first interpretation; whereas the atmospheric flow and simple decay approaches focus on fluxes, as in the second interpretation. Whether emissions/removals are approximated by stock change or from gross fluxes, it is critical that a consistent approach is applied across the whole LULUCF/AFOLU sector. Approaches based on stock change are recommended over those based on fluxes.