Gallium behaviour in some contrasting lateritic profiles from Cameroon and Brazil

In the supergene environment under tropical climates, the behaviour of gallium depends on the physico-chemical conditions which control the evolution stages of the residual mantle and this element is not necessarily linked to aluminum, as was formerly believed. Ga vs. Al correlation is positive in weathering profiles from West Cameroon developed on granodiorite, basalt and trachyte, which essentially result from the leaching of alkalis, alkali-earths and silicon. However, in the upper part of the profile on trachyte, which underwent later aluminization, no significant Ga vs. Al correlation was evidenced. In lateritic and bauxitic profiles from Eastern Brazilian Amazonia developed on basalt and siliciclastic sedimentary rocks, the dissociation between gallium and aluminum is clearly expressed by a negative or lack of Ga vs. Al correlation in the bauxitic horizons, resulting mainly from intense aluminization, as well as in the ferruginous horizons. In turn, Ga vs. Fe correlation is markedly positive in both cases. Thus, when dissolution of early formed Ga-containing gibbsite and kaolinite occurs, aluminum migrates and concentrates in well differentiated zones while gallium tends to be leached out of the profile or is retained by Fe-oxyhydroxides.     

Coral- and oyster-microbialite patch reefs in the aftermath of the Triassic–Jurassic biotic crisis (Sinemurian,Southeast France)

The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.     

Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis

Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l^?1), (c) relative repeatability of approximately 3% obtained on ⁷⁴Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g^?1, 2.41 ± 0.18 μg g^?1, 1.89 ± 0.10 μg g^?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g^?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure.     

Forest carbon storage and tree carbon pool dynamics under natural forest protection program in northeastern China

The Natural Forest Protection(NFP) program is one of the Six Key Forestry Projects which were adopted by the Chinese Government since the 1980s to address important natural issues in China. It advanced to protecting and restoring the structures and functions of the natural forests through sustainable forest management. However, the role of forest carbon storage and tree carbon pool dynamics since the adoption of the NFP remains unknown. To address this knowledge gap, this study calculated forest carbon storage(tree, understory, forest floor and soil) in the forest region of northeastern(NE) China based on National Forest Inventory databases and field investigated databases. For tree biomass, this study utilized an improved method for biomass estimation that converts timber volume to total forest biomass; while for understory, forest floor and soil carbon storage, this study utilized forest type-specific mean carbon densities multiplied by their areas in the region. Results showed that the tree carbon pool under the NFP in NE China functioned as a carbon sink from 1998 to 2008, with an increase of 6.3 Tg C/yr, which was mainly sequestrated by natural forests(5.1 Tg C/yr). At the same time, plantations also acted as a carbon sink, reflecting an increase of 1.2 Tg C/yr. In 2008, total carbon storage in forests covered by the NFP in NE China was 4603.8 Tg C, of which 4393.3 Tg C was stored in natural forests and 210.5 Tg C in planted forests. Soil was the largest carbon storage component, contributing 69.5%–77.8% of total carbon storage; followed by tree and forest floor, accounting for 16.3%–23.0% and 5.0%–6.5% of total carbon storage, respectively. Understory carbon pool ranged from 1.9 to 42.7 Tg C, accounting for only 0.9% of total carbon storage.     

REDD+ projects and national-level Readiness processes: a case study from Kenya

The Bali Action Plan and Cancun agreements on Reducing Emissions from Deforestation and forest Degradation, plus forest conservation, sustainable management of forests and enhancement of forest carbon stocks (REDD+) have encouraged demonstration activities as part of Readiness and a step towards national approaches. This has enabled important growth in pilot and demonstration projects. Yet an understanding about how these projects are connected and contribute to national-level technical, policy, and institutional preparedness (Readiness) for REDD+ is lacking. This article examines the linkages between national processes and the private-sector-driven Kasigau Corridor REDD+ project in Kenya. The study reveals interesting cross-scale interactions that have increased over time and have high potential for harnessing national-level processes through lessons from the project level. Key innovations from the Kasigau Corridor Project include the implementation of REDD+ in dry forests, operationalization of conservation easements in the context of REDD+, and demonstration of potential ways of obtaining upfront finance for REDD+. The study also provides a number of key recommendations for Kenya and REDD+ in general, including official endorsement of stand-alone REDD+ projects under national Readiness schemes and exploring jurisdictional and nested REDD+ approaches. Additionally, more accommodating national-level frameworks for attracting private-sector engagement and investments, and for integrating, scaling-out, or scaling-up lessons from such projects, would be needed to enhance national REDD+ Readiness.     

Seasonal variability of the equatorial undercurrent termination and associated salinity maximum in the Gulf of Guinea

The termination of the Equatorial Undercurrent (EUC) in the eastern equatorial Atlantic during boreal summer and fall, and the fate of the associated saline water masses, are analyzed from in situ hydrological and currents data collected during 19 hydrographic cruises between 2000 and 2007, complemented by observations from Argo profiling floats and PIRATA moorings, and from a numerical simulation of the Tropical Atlantic Ocean for the period 1993–2007. An intense variability of the circulation and hydrological properties is evidenced from observations in the upper thermocline (24.5–26.2 isopycnal layer) between June and November. During early boreal summer, saline water masses are transported eastward in the upper thermocline to the African coast within the EUC, and recirculate westward on both sides of the EUC. In mid-boreal summer, the EUC weakens in the upper thermocline and the equatorial salinity maximum disappears due to intense mixing with the surface waters during the upwelling season. The extra-equatorial salinity maxima are also partially eroded during the boreal summer, with a slight poleward migration of the southern hemisphere maximum until late boreal summer. The upper EUC reappears in September, feeding again the eastern equatorial Atlantic with saline waters until boreal spring. During December–January, numerical results suggest a second seasonal weakening of the EUC in the Gulf of Guinea, with a partial erosion of the associated equatorial salinity maximum.     

Are opinions expressed in land-use planning documents?

A great deal of research on information extraction from textual datasets has been performed in specific data contexts, such as movie reviews, commercial product evaluations, campaign speeches, etc. In this paper, we raise the question on how appropriate these methods are for documents related to land-use planning. The kind of information sought concerns the stakeholders, sentiments, geographic information, and everything else related to the territory. However, it is extremely challenging to link sentiments to the three dimensions that constitute geographic information (location, time, and theme). After highlighting the limitations of existing proposals and discussing issues related to textual data, we present a method called OPILAND (OPinion mIning from LAND-use planning documents) designed to semi-automatically mine opinions related to named-entities in specialized contexts. Experiments are conducted on a Thau lagoon dataset (France), and then applied on three datasets that are related to different areas in order to highlight the relevance and the broader applications of our proposal.     

Stability and accuracy in a hybrid test example

This paper presents an example of the application of error monitoring techniques to the results of a pseudodynamic test performed at variable testing speeds. For the faster testing speeds, the control errors increased and the test reliability was lost in terms of accuracy and stability, as observed by the evolution of the monitoring parameters. The applied monitoring methods were the spatial model identification of frequency and damping distortions and the error energy, which have been proposed in previous publications. Copyright © 2012 John Wiley & Sons, Ltd.     

Reynolds stress and sand transport over a foredune

Reynolds shear stress (RS = –u′ w′) and sand transport patterns over a vegetated foredune are explored using three‐dimensional velocity data from ultrasonic anemometers (at 0 · 2 and 1 · 2 m) and sand transport intensity from laser particle counters (at 0 · 014 m). A mid‐latitude cyclone on 3–4 May 2010 generated storm‐force winds (exceeding 20 m s^–1) that shifted from offshore to obliquely alongshore. Quadrant analysis was used to characterize the spatial variation of RS quadrant components (Q1 through Q4) and their relative contributions were parameterized using the flow exuberance relation, EX_FL = (Q1 + Q3)/(Q2 + Q4). The magnitudes of RS and sand transport varied somewhat independently over the dune as controlled by topographic forcing effects on flow dynamics. A ‘flow exuberance effect’ was evident such that Q2 (ejection‐like) and Q4 (sweep‐like) quadrants (that contribute positively to RS) dominated on the beach, dune toe, and lower stoss, whereas Q1 and Q3 (that contribute negatively to RS) dominated near the crest. This exuberance effect was not expressed, however, in sand transport patterns. Instead, Q1 and Q4, with above‐average streamwise velocity fluctuations (+u′), were most frequently associated with sand transport. Q4 activity corresponded with most sand transport at the beach, toe, and stoss locations (52, 60, 100%). At the crest, 25 to 86% of transport was associated with Q1 while Q4 corresponded with most of the remaining transport (13 to 59%). Thus, the relationship between sand transport and RS is not as straightforward as in traditional equations that relate flux to stress in increasing fashion. Generally, RS was poorly associated with sand transport partly because Q1 and Q4 contributions offset each other in RS calculations. Thus, large amounts of transport can occur with small RS. Turbulent kinetic energy or Reynolds normal stresses (u′², w′²) may provide stronger associations with sand transport over dunes, although challenges exist on how to normalize and compare these quantities. Copyright © 2013 John Wiley & Sons, Ltd.