Noble gases in the Martian meteorite Northwest Africa 2737: A new chassignite signature

Abstract— We report noble gas data for the second chassignite, Northwest Africa (NWA) 2737, which was recently found in the Moroccan desert. The cosmic ray exposure (CRE) age based on cosmogenic ³He, ²¹Ne, and ³⁸Ar around 10–11 Ma is comparable to the CRE ages of Chassigny and the nakhlites and indicates ejection of meteorites belonging to these two families during a discrete event, or a suite of discrete events having occurred in a restricted interval of time. In contrast, U‐Th/He and K/Ar ages <0.5 Ga are in the range of radiometric ages of shergottites, despite a Sm‐Nd signature comparable to that of Chassigny and the nakhlites (Misawa et al. 2005). Overall, the noble gas signature of NWA 2737 resembles that of shergottites rather than that of Chassigny and the nakhlites: NWA 2737 does not contain, in detectable amount, the solar‐like xenon found in Chassigny and thought to characterize the Martian mantle nor apparently fission xenon from ²⁴⁴Pu, which is abundant in Chassigny and some of the nakhlites. In contrast, NWA 2737 contains Martian atmospheric noble gases trapped in amounts comparable to those found in shergottite impact glasses. The loss of Martian mantle noble gases, together with the trapping of Martian atmospheric gases, could have occurred during assimilation of Martian surface components, or more likely during shock metamorphism, which is recorded in the petrology of this meteorite.     

Multibeam bathymetry and sidescan imaging of the Rivera Transform–Moctezuma Spreading Segment junction, northern East Pacific Rise: New constraints on Rivera–Pacific relative plate motion

To better understand the recent motion of the Pacific plate relative to the Rivera plate and to better define the limitations of the existing Rivera–Pacific plate motion models for accurately predicting this motion, total-field magnetic data, multibeam bathymetric data and sidescan sonar images were collected during the BART and FAMEX campaigns of the N/O L'Atalante conducted in April and May 2002 in the area surrounding the Moctezuma Spreading Segment of the East Pacific Rise, located offshore of Manzanillo, Mexico, at 106°16′W, between 17.8°N and 18.5°N. Among the main results are: (1) the principle transform displacement zone of the Rivera Transform is narrow and well defined east of 107o15′W and these azimuths should be used preferentially when deriving new plate motion models, and (2) spreading rates along the Moctezuma Spreading Segment should not be used in plate motion studies as either seafloor spreading has been accommodated at more than one location since the initiation of seafloor spreading in the area of the Moctezuma Spreading Segment, or this spreading center is not a Rivera–Pacific plate boundary as has been previously assumed. Comparison of observed transform azimuths with those predicted by the best-fit poles of six previous models of Rivera–Pacific relative motion indicate that, in the study area, a significant systematic bias is present in the predictions of Rivera–Pacific motion. Although the exact source of this bias remains unclear, this bias indicates the need to derive a new Rivera–Pacific relative plate motion model.     

The Grader layered intrusion (Havre-Saint-Pierre Anorthosite, Quebec) and genesis of nelsonite and other Fe–Ti–P ores

The Grader layered intrusion is part of the Havre-Saint-Pierre anorthosite in the Grenville Province (Quebec, Canada). This intrusion has a basin-like morphology and contains significant resources of Fe–Ti–P in ilmenite and apatite. Outcropping lithologies are massive oxide alternating with anorthosite layers, banded ilmenite–apatite–plagioclase rocks and layered oxide apatite (gabbro-)norites. Drill cores provide evidence for stratigraphic variations of mineral and whole rock compositions controlled by fractional crystallization with the successive appearance of liquidus phases: plagioclase and ilmenite followed by apatite, then orthopyroxene together with magnetite, and finally clinopyroxene. This atypical sequence of crystallization resulted in the formation of plagioclase–ilmenite–apatite cumulates or “nelsonites” in plagioclase-free layers. Fine-grained ferrodiorites that cross-cut the cumulates are shown to be in equilibrium with the noritic rocks. The high TiO₂ and P₂O₅ contents of these assumed liquids explains the early saturation of ilmenite and apatite before Fe–Mg silicates, thus the nelsonites represent cumulates rather than crystallized Fe–Ti–P-rich immiscible melts. The location of the most evolved mineral and whole rock compositions several tens of meters below the top of the intrusion, forming a sandwich horizon, is consistent with crystallization both from the base and top of the intrusion. The concentrations of V and Cr in ilmenite display a single fractionation path for the different cumulus assemblages and define the cotectic proportion of ilmenite to 21 wt.%. This corresponds to bulk cotectic cumulates with ca. 8 wt.% TiO₂, which is significantly lower than what is commonly observed in the explored portion of the Grader intrusion. The proposed mechanism of ilmenite-enrichment is the lateral removal of plagioclase due to its relative buoyancy in the dense ferrodiorite melt. This plagioclase has probably accumulated in other portions of the intrusion or has not been distinguished from the host anorthosite.     

Effects of heterogeneous land use/cover types on river channel morphology in the Solo River catchment,Eastern Uganda

In the tropics, unmonitored land use/cover types cause significant effects on the narrowing and widening of river channels which affects the integrity of water resources. River channel planform extent was characterized using Landsat images, while water and bedload samples were collected and analysed for a period of one year. The results revealed that in 1986, the channel planform covered 3.7 sq km in length than in 2013 where it increased to 4.2 sq km. Wetland (537.1mgl^?1) and bushland (186.3mgl^?1) cover types had the highest concentration of suspended sediments. Fine sand (0.25 mm), silty sand (1 mm) and silty clay (0.125 mm) bedload particle types dominated the riverbed along the channel from the sampled land use/cover types. The high concentration of sediments, bedload materials, bank instability, and streamflow were significant contributors to the narrowing and widening of the channel (p < 0.05). Agricultural land use was the major contributor of channel aggradation (0.8 m) and degradation (0.25 m) compared to tree plantations, bushlands, forest and wetland cover types.     

Evidence of quaternary transtensional tectonics in the Nekor basin (NE Morocco)

The geodynamic processes in the western Mediterranean are driven by both deep (mantle) processes such as slab‐rollback or delamination, oblique plate convergence and inherited structures. The present‐day deformation of the Alboran Sea and in particular the Nekor basin area is linked to these coeval effects. The seismically active Nekor basin is an extensional basin formed in a convergent setting at the eastern part of the Rif Chain whose boundaries extend both onshore and offshore Morocco. We propose a new structural model of the Nekor basin based on high‐resolution offshore data compiled from recent seismic reflection profiles, swath bathymetry acquisitions and industrial seismic reflection profiles. The new data set shows that the northern limit of the basin is oriented N49° with right‐stepping faults from the Bousekkour–Aghbal fault to the sinistral Bokkoya fault zone. This pattern indicates the presence of an inherited left‐lateral basement fault parallel to the major inherited Nekor fault. This fault has been interpreted as a Quaternary active left‐lateral transfer fault localized on weak structural discontinuities inherited from the orogenic period. Onshore and offshore active faults enclose a rhombohedral tectonic Nekor Basin. Normal faults oriented N155° offset the most recent Quaternary deposits in the Nekor basin, and indicate the transtensional behaviour of this basin. The geometry of these faults suggests a likely rollover structure and the presence at depth of a crustal detachment. Inactive Plio‐Quaternary normal faults to the east of the Ras Tarf promontory and geometries of depocentres seem to indicate the migration of deformation from east to west. The local orientations of horizontal stress directions deduced from normal fault orientations are compatible with the extrusion of the Rifian units and coherent with the westward rollback of the Tethyan slab and the localization of the present‐day slab detachment or delamination.     

Computation and visualisation of the accuracy of old maps using differential distortion analysis

The accuracy of old maps can hold interesting historical information, and is therefore studied using distortion analysis methods. These methods start from a set of ground control points that are identified both on the old map and on a modern reference map or globe, and conclude with techniques that compute and visualise distortion. Such techniques have advanced over the years, but leave room for improvement, as the current ones result in approximate values and a coarse spatial resolution. We propose a more elegant and more accurate way to compute distortion of old maps by translating the technique of differential distortion analysis, used in map projection theory, to the setting where an old map and a reference map are directly compared. This enables the application of various useful distortion metrics to the study of old maps, such as the area scale factor, the maximum angular distortion and the Tissot indicatrices. As such a technique is always embedded in a full distortion analysis method we start by putting forward an optimal analysis method for a general-purpose study, which then serves as the foundation for the development of our technique. Thereto, we discuss the structure of distortion analysis methods and the various options available for every step of the process, including the different settings in which the old map can be compared to its modern counterpart, the techniques that can be used to interpolate between both, and the techniques available to compute and visualise the distortion. We conclude by applying our general-purpose method, including the differential distortion analysis technique, to an example map also used in other literature.     

A stochastic inversion workflow for monitoring the distribution of CO<Subscript>2</Subscript> injected into deep saline aquifers

We present a two-step stochastic inversion approach for monitoring the distribution of CO₂ injected into deep saline aquifers for the typical scenario of one single injection well and a database comprising a common suite of well logs as well as time-lapse vertical seismic profiling (VSP) data. In the first step, we compute several sets of stochastic models of the elastic properties using conventional sequential Gaussian co-simulations (SGCS) representing the considered reservoir before CO₂ injection. All realizations within a set of models are then iteratively combined using a modified gradual deformation algorithm aiming at reducing the mismatch between the observed and simulated VSP data. In the second step, these optimal static models then serve as input for a history matching approach using the same modified gradual deformation algorithm for minimizing the mismatch between the observed and simulated VSP data following the injection of CO₂. At each gradual deformation step, the injection and migration of CO₂ is simulated and the corresponding seismic traces are computed and compared with the observed ones. The proposed stochastic inversion approach has been tested for a realistic, and arguably particularly challenging, synthetic case study mimicking the geological environment of a potential CO₂ injection site in the Cambrian-Ordivician sedimentary sequence of the St. Lawrence platform in Southern Québec. The results demonstrate that the proposed two-step reservoir characterization approach is capable of adequately resolving and monitoring the distribution of the injected CO₂. This finds its expression in optimized models of P- and S-wave velocities, density, and porosity, which, compared to conventional stochastic reservoir models, exhibit a significantly improved structural similarity with regard to the corresponding reference models. The proposed approach is therefore expected to allow for an optimal injection forecast by using a quantitative assimilation of all available data from the appraisal stage of a CO₂ injection site.     

Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis

Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l^?1), (c) relative repeatability of approximately 3% obtained on ⁷⁴Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g^?1, 2.41 ± 0.18 μg g^?1, 1.89 ± 0.10 μg g^?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g^?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure.     

Coral- and oyster-microbialite patch reefs in the aftermath of the Triassic–Jurassic biotic crisis (Sinemurian,Southeast France)

The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.     

A Study of the Local Geometric Accuracy of Count de Ferraris's Carte de cabinet (1770s) Using Differential Distortion Analysis

The eighteenth century Carte de cabinet of count de Ferraris is the first large-scale (1:11?520) topographic map of the entire Belgian territory, making it a valuable source of historical information. In the past, a number of studies have tried to assess the geometric accuracy of this map, but they all suffer from restricted technical capabilities for computing and visualizing the distortions, and most of them only focus on a limited number of the 275 map sheets. This paper therefore seeks to provide the first systematic and in-depth investigation of the map’s local geometric accuracy. Recently, two Belgian government agencies georeferenced the Flemish and Walloon part of the Carte de cabinet with a high level of detail, using some 30,000 ground control points to link the old map to the modern topographic map of Belgium. These data sets represent a new and unprecedented potential source of accuracy information. However, the high number of control points and our desire to compute distortions in an exact, local, quantitative and continuous way meant prominent techniques for studying the geometric accuracy of old maps, such as displacement vectors, distortion grids, triangular nets and the popular MapAnalyst software, were unsuited for this task. To meet all our requirements a new technique called Differential Distortion Analysis, which is influenced by the treatment of distortions in map projection theory, was used instead. Its advantages, structure and application to the Carte de cabinet are discussed in detail. The new technique allows calculating and displaying the map’s local angular and surface distortions with a very high spatial resolution. Consequently, it was possible to identify trends in the obtained levels of accuracy and to relate these to historical facts about the Carte de cabinet’s production process. This has resulted in important new insights into the map’s geometric accuracy.