Serpentinization of the martian crust during Noachian

This paper proposes a model of serpentinization of the Southern martian crust that may explain the topographic dichotomy, the absence of an associated free-air gravity anomaly and the presence of strong magnetic anomalies in the Southern Hemisphere. The thermodynamical conditions for serpentinization were likely met in the lithosphere during the Noachian period. This process may have decreased the density in the Southern crust and created the topographic dichotomy. Different reactions of serpentinization that can form magnetite have been considered. Assuming an intense magnetic field (core dynamo), we obtain chemical remanent magnetizations that are in the order of the estimates deduced from martian magnetic anomaly studies. The pertinence and the implications of our model concerning the early thermal evolution of Mars are discussed, with emphasis on the intensity of the paleo-magnetic field.     

The non‐trivial problem of meteorite pairing

Abstract— Pairing is the procedure of identifying fragments of a single meteorite fall (that were separated during atmospheric passage or during terrestrial history) by establishing the similarity of two or more meteorite fragments. We argue that pairing is governed by two principles, that only a single mismatch of properties is required to refute a proposed pairing, and that virtually all pairings bear some degree of uncertainty. Using data distributions for modern falls, we take a probability approach to estimate degrees of certainty associated with proposed pairings, emphasizing the importance of unusual features. For new pairing criteria or new analytical additions to old criteria, the degree of variation within individual meteorites must be delineated and the degree of variation within meteorite classes must be quantified. Criteria for pairing can be divided into (1) parent body history indicators, (2) meteoroid space history indicators, and (3) terrestrial history indicators. Included in these categories are 11 specific criteria, including petrographic textures, mineralogy and mineral composition, terrestrial age estimates, cosmic‐ray exposure ages, and natural thermoluminescence (TL) levels. Not all criteria are applicable to all meteorite types. About 2275 pairings suggested in the literature have been subjected to this analysis. Many literature pairings, especially those involving common meteorite types, bear large uncertainties due to lack of data.     

Variably saturated groundwater modelling for optimizing managed aquifer recharge using trench infiltration

Spreading‐basin methods have resulted in more than 130 million cubic metres of recharge to the unconfined Navajo Sandstone of southern Utah in the past decade, but infiltration rates have slowed in recent years because of reduced hydraulic gradients and (or) clogging. Trench infiltration is a promising alternative technique for increasing recharge and minimizing evaporation. This paper uses a variably saturated flow model to further investigate the relative importance of the following variables on rates of trench infiltration to unconfined aquifers: saturated hydraulic conductivity, trench spacing and dimensions, initial water‐table depth, alternate wet/dry periods, and number of parallel trenches. Modelling results showed (1) increased infiltration with higher hydraulic conductivity, deeper initial water tables, and larger spacing between parallel trenches, (2) deeper or wider trenches do not substantially increase infiltration, (3) alternating wet/dry periods result in less overall infiltration than keeping the trenches continuously full, and (4) larger numbers of parallel trenches within a fixed area increases infiltration but with a diminishing effect as trench spacing becomes tighter. An empirical equation for estimating expected trench infiltration rates as a function of hydraulic conductivity and initial water‐table depth was derived and can be used for evaluating feasibility of trench infiltration in other hydrogeologic settings. Copyright © 2014 John Wiley & Sons, Ltd.     

Thermoluminescence survey of 12 meteorites collected by the European 1988 Antarctic meteorite expedition to Allan Hills and the importance of acid washing for thermoluminescence sensitivity measurements

Abstract— Natural and induced thermoluminescence (TL) data are reported for 12 meteorites recovered from the Allan Hills region of Antarctica by the European field party during the 1988/89 field season. The samples include one with extremely high natural TL, ALH88035, suggestive of exposure to unusually high radiation doses (i.e., low degrees of shielding), and one, ALH88034, whose low natural TL suggests reheating within the last 10⁵ years. The remainder have natural TL values suggestive of terrestrial ages similar to those of other meteorites from Allan Hills. ALH88015 (L6) has induced TL data suggestive of intense shock. TL sensitivities of these meteorites are generally lower than observed falls of their petrologic types, as is also observed for Antarctic meteorites in general. Acid-washing experiments indicate that this is solely the result of terrestrial weathering rather than a nonterrestrial Antarctic—non-Antarctic difference. However, other TL parameters, such as natural TL and induced peak temperature-width, are unchanged by acid washing and are sensitive indicators of a meteorite's metamorphic and recent radiation history.     

Rapid changes in the nature of the H chondrites falling to Earth

Abstract— We have previously identified a subgroup of Antarctic H chondrites that are significantly different from H chondrites among the modern falls in terms of induced thermoluminescence (TL), metallographic cooling rate, and cosmogenic inert gas contents. Here we examine their terrestrial and thermal history as apparent in their natural TL and radioactive cosmogenic isotope abundances. These meteorites have a tendency towards high ²⁶Al activities and fairly short ¹⁴C and ³⁶Cl terrestrial ages (generally <100 ka). They also sometimes exhibit unusually high natural TL levels, which we have previously interpreted as indicating orbital evolution from perihelia >1.2 AU to ～1 AU within the last <10⁵ years. We suggest that the nature of the meteorites falling to Earth is not independent of time but depends on stochastic events, such as the breakup of parent bodies and recent variations in orbit.     

Chemical and physical studies of type 3 chondrites XII: The metamorphic history of CV chondrites and their components

Abstract— The induced thermoluminescence (TL) properties of 16 CV and CV-related chondrites, four CK chondrites and Renazzo (CR2) have been measured in order to investigate their metamorphic history. The petrographic, mineralogical and bulk compositional differences among the CV chondrites indicate that the TL sensitivity of the ～130 °C TL peak is reflecting the abundance of ordered feldspar, especially in chondrule mesostasis, which in turn reflects parent-body metamorphism. The TL properties of 18 samples of homogenized Allende powder heated at a variety of times and temperatures, and cathodoluminescence mosaics of Axtell and Coolidge, showed results consistent with this conclusion. Five refractory inclusions from Allende, and separates from those inclusions, were also examined and yielded trends reflecting variations in mineralogy indicative of high peak temperatures (either metamorphic or igneous) and fairly rapid cooling. The CK chondrites are unique among metamorphosed chondrites in showing no detectable induced TL, which is consistent with literature data that suggests very unusual feldspar in these meteorites. Using TL sensitivity and several mineral systems and allowing for the differences in the oxidized and reduced subgroups, the CV and CV-related meteorites can be divided into petrologic types analogous to those of the ordinary and CO type 3 chondrites. Axtell, Kaba, Leoville, Bali, Arch and ALHA81003 are type 3.0–3.1, while ALH84018, Efremovka, Grosnaja, Allende and Vigarano are type 3.2–3.3 and Coolidge and Loongana 001 are type 3.8. Mokoia is probably a breccia with regions ranging in petrologic type from 3.0 to 3.2. Renazzo often plots at the end of the reduced and oxidized CV chondrite trends, even when those trends diverge, suggesting that in many respects it resembles the unmetamorphosed precursors of the CV chondrites. The low-petrographic types and low-TL peak temperatures of all samples, including the CV3.8 chondrites, indicates metamorphism in the stability field of low feldspar (i.e., <800 °C) and a metamorphic history similar to that of the CO chondrites but unlike that of the ordinary chondrites.     

Metamorphism and aqueous alteration in low petrographic type ordinary chondrites

Abstract— In order to investigate the relative importance of dry metamorphism and aqueous alteration in the history of chondrules, chondrules were hand-picked from the Semarkona (petrographic type 3.0), Bishunpur (3.1), Chainpur (3.4), Dhajala (3.8) and Allegan (5) chondrites, and matrix samples were extracted from the first three ordinary chondrites. The thermoluminescence (TL) properties of all the samples were measured, and appropriate subsets of the samples were analyzed by electron-microprobe and radiochemical neutron activation and the water and H-isotopic composition determined. The TL data for chondrules from Semarkona and Bishunpur scatter widely showing no unambiguous trends, although group B1 chondrules tend to have lower sensitivities and lower peak temperatures compared with group A5 chondrules. It is argued that these data reflect the variety of processes accompanying chondrule formation. The chondrules show remarkably uniform contents of the highly labile elements, indicating mineralogical control on abundance and volatile loss from silicates and loss and recondensation of mobile chalcophiles and siderophiles in some cases. Very high D/H values (up to ～8000‰ SMOW) are observed in certain Semarkona chondrules, a confirmation of earlier work. With increasing petrographic type, mean TL sensitivities of the chondrules increase, the spread of values within an individual meteorite decreases, and peak temperatures and peak widths show trends indicating that the TL is mainly produced by feldspar and that dry, thermal metamorphism is the dominant secondary process experienced by the chondrules. The TL sensitivities of matrix samples also increase with petrographic type. Chainpur matrix samples show the same spread of peak temperatures and peak widths as Chainpur chondrules, indicating metamorphism-related changes in the feldspar are responsible for the TL of the matrix. The TL data for the Semarkona and Bishunpur matrix samples provide, at best, only weak evidence for aqueous alteration, but the matrix contains H with approximately terrestrial D/H values, even though it contains much water. Secondary processes (probably aqueous alteration) presumably lowered the D/H of the matrix and certain chondrules. While chondrule properties appear to be governed primarily by formation processes and subsequent metamorphism, the matrix of Semarkona has a more complex history involving aqueous alteration as a meteorite-wide process.     

A new adiabatic kernel for the MC2 model

Abstract

Traditional semi‐implicit formulations of nonhydrostatic compressible models may not be stable in the presence of steep terrain when pressure gradient terms are split and lagged in time. If all pressure gradient terms and the divergence are treated implicitly, the resulting wave equation for the pressure contains off‐diagonal cross‐derivative terms leading to a highly nonsymmetric linear system of equations. In this paper we present a more implicit formulation of the Mesoscale Compressible Community (MC2) model employing a Generalized Minimal Residual (GMRES) Krylov iterative solver and a more efficient semi‐Lagrangian advection scheme. Open boundaries now permit exact upwind interpolation and the ability to reproduce simulations to machine precision is illustrated for one‐way nesting at equivalent resolution. Numerical simulations of hydrostatic and nonhydrostatic mountain waves demonstrate the stability and accuracy of the new adiabatic kernel. The computational efficiency of the model is reported for 1D Jacobi and 3D Alternating Direction Implicit (ADI) line relaxation preconditioned implemented with a parallel data transposition strategy.     

Can the EU emission trading scheme support CDM forestry?

Abstract

The European Commission is mandated to consider the inclusion of credits from land-use projects under the clean development mechanism (CDM) and joint implementation (JI), beginning with the second period of the European Union's emission trading scheme (ETS) in its report due in July 2006. Temporary credits from afforestation and reforestation under the CDM are seen by many as posing a technical problem for their use under the ETS. This article summarizes three feasible, efficient and environmentally sound alternatives for achieving the integration of such temporary credits in the European emissions trading market starting in 2008. The first proposal integrates tCERs and lCERs (temporary credits) into the EU ETS by allowing for their direct use for compliance purposes. The second proposal builds on the idea of swapping temporary credits for EU allowances (EUAs) by Member States. The third proposal would not require a political decision at the EU level. Instead supportive Member States or private carbon fund operators would agree to swap temporary credits for the CERs or ERUs they hold in their accounts. All three solutions would be linked to a risk-mitigation strategy based on levying a fee or fixing an exchange rate, which would allow governments to hedge the risk of losing temporary credits.