Methane Abundance on Titan, Measured by the Space Telescope Imaging Spectrograph

Although methane is the dominant absorber in Titan's reflection spectrum, the amount of methane in the atmosphere has only been determined to an order of magnitude. We analyzed spectra from the Space Telescope Imaging Spectrograph, looking at both a bright surface region (700-km radius) and a dark surface region. The difference between the spectra of the two regions is attributed to light that has scattered off the surface, and therefore made a round-trip through all of Titan's methane. Considering only absorption, the shape of the difference spectrum provides an upper limit on methane abundance of 3.5 km-am. Modeling the multiple scattering in the atmosphere further constrains the methane abundance to 2.63±0.17 km-am. In the absence of supersaturation and with a simplified methane vertical profile, this corresponds to a surface methane-mole fraction near 3.8% and a relative humidity of 0.32. With supersaturation near the tropopause, the surface methane mole fraction could be as low as 3%.     

Comparative analyses of East Texas forest cover maps generated from Landsat and AVHRR data

Comparing satellite data derived map products are affected by differences in data characteristics, image acquisition dates, processing techniques, and classification schemes used for assigning pixels to a thematic class. By comparing two forest maps generated from Landsat Enhanced Thematic Mapper Plus (ETM+) and Advanced Very High Resolution Radiometer (AVHRR) images acquired on the same day, and processed using identical classification scheme and methods these differences were minimized. The ETM+ derived map had higher classification accuracy values and more precise area estimates than the AVHRR derived map. In the ETM+ derived map, 87 of the 599 verification data were misclassified, whereas in the AVHRR derived map, 155 of the 469 verification data were misclassified. Detailed error analyses by land cover class revealed that a land use based definition of forest accounted for 74% (64 out of 87) and 57% (89 out of 155) of the classification errors in ETM+ and AVHRR derived maps, respectively.     

Cross-shelf exchange in a model of the Ross Sea circulation and biogeochemistry

Transport of warm, nutrient-rich Circumpolar Deep Water (CDW) onto Antarctic continental shelves and coastal seas has important effects on physical and biological processes. The present study investigates the locations of this transport and its dynamics in the Ross Sea with a high-resolution three-dimensional numerical model. The model circulation is forced by daily wind stress along with heat and salt fluxes calculated from atmospheric climatologies by bulk formulae. All surface fluxes are modified by an imposed climatological ice cover. Waters under the Ross Ice Shelf are not included explicitly, but their effect on temperature and salinity is imposed in a buffer zone at the southern end of the model domain. A simple nutrient uptake is calculated based on the climatological chlorophyll distribution and Monod uptake kinetics.Model circulation is strongly affected by bottom topography, due to weak stratification, and agrees with schematics of the general flow and long-term current measurements except near the southern boundary. The sea-surface temperature is similar to satellite estimates except that the warmest simulated temperatures are slightly higher than observations. There is a significant correlation between the curvature of the shelf break and the transport across the shelf break. A momentum term balance shows that momentum advection helps to force flow across the shelf break in specific locations due to the curvature of the bathymetry (that is, the isobaths curve in front of the flow). For the model to create a strong intrusion of CDW onto the shelf, it appears two mechanisms are necessary. First, CDW is driven onto the shelf at least partially due to momentum advection and the curvature of the shelf break; then, the general circulation on the shelf takes the CDW into the interior.     

Tracing variability of run‐off generation in mountainous permafrost of semi‐arid north‐eastern Mongolia

The headwaters of mountainous, discontinuous permafrost regions in north‐eastern Mongolia are important water resources for the semi‐arid country, but little is known about hydrological processes there. Run‐off generation on south‐facing slopes, which are devoid of permafrost, has so far been neglected and is totally unknown for areas that have been affected by recent forest fires. To fill this knowledge gap, the present study applied artificial tracers on a steppe‐vegetated south‐facing and on two north‐facing slopes, burned and unburned. Combined sprinkling and dye tracer experiments were used to visualize processes of infiltration and water fluxes in the unsaturated zone. On the unburned north‐facing slope, rapid and widespread infiltration through a wet organic layer was observed down to the permafrost. On the burned profile, rapid infiltration occurred through a combusted organic and underlying mineral layer. Stained water seeped out at the bottom of both profiles suggesting a general tendency to subsurface stormflow (SSF). Ongoing SSF could directly be studied 24 h after a high‐intensity rainfall event on a 55‐m hillslope section in the burned forest. Measurements of water temperature proved the role of the permafrost layer as a base horizon for SSF. Repeated tracer injections allowed direct insights into SSF dynamics: A first injection suggested rather slow dispersive subsurface flow paths; whereas 18 h later, a second injection traced a more preferential flow system with 20 times quicker flow velocities. We speculate that these pronounced SSF dynamics are limited to burned slopes where a thermally insulating organic layer is absent. On three south‐facing soil profiles, the applied tracer remained in the uppermost 5 cm of a silt‐rich mineral soil horizon. No signs of preferential infiltration could be found, which suggested reduced biological activity under a harsh, dry and cold climate. Instead, direct observations, distributed tracers and charcoal samples provided evidence for the occurrence of overland flow. Copyright © 2014 John Wiley & Sons, Ltd.     

A Sensitivity Analysis of the Waterline Method of Constructing a Digital Elevation Model for Intertidal Areas in ERS SAR scene of Eastern England

A sensitivity analysis of the waterline method of constructing a Digital Elevation Model (DEM) of an intertidal zone using remote sensing and hydrodynamic modelling is described. Variation in vertical height accuracy as a function of beach slope is investigated using a set of nine ERS Synthetic Aperture Radar (SAR) images of the Humber/Wash area on the English east coast acquired between 1992 and 1994. Waterlines from these images are heighted using a hydrodynamic tide-surge model and interpolated using block kriging. On 1:500 slope beaches, an average block height estimation standard deviation of 18–22 cm is achieved. This rises to 27 cm on 1:100 slope beaches, and 32 cm on 1:30 slope beaches. The average heighting error at different slopes is decomposed into components due to waterline heighting error, inadequate sensor resolution and interpolation inaccuracy. It is shown that, at 1:500 slope, waterline heighting error and interpolation inaccuracy are the main error sources, whilst at 1:30 slope, errors due to inadequate sensor resolution become dominant. The ability of the technique to generate intertidal DEMs for almost the entire coastal zone in a complete ERS SAR scene covering 100×100 km is demonstrated.     

Late Holocene environmental conditions in Coronation Gulf,southwestern Canadian Arctic Archipelago: evidence from dinoflagellate cysts,other non‐pollen palynomorphs,and pollen

Boxcore 99LSSL‐001 (68.095° N, 114.186° W; 211 m water depth) from Coronation Gulf represents the first decadal‐scale marine palynology and late Holocene sediment record for the southwestern part of the Northwest Passage. The record was studied for organic‐walled microfossils (dinoflagellate cysts, non‐pollen palynomorphs), pollen, terrestrial spores, and sediment characteristics. ²¹⁰Pb, ¹³⁷Cs, and three accelerator mass spectrometry ¹⁴C dates constrain the chronology. Three prominent palaeoenvironmental zones were identified. During the interval AD 1470–1680 (Zone I), the climate was warmer and wetter than at present, and environmental conditions were more favourable to biological activity and northward boreal forest migration, with reduced sea‐ice and a longer open‐water (growing) season. The interval AD 1680–1940 (Zone II) records sea‐ice increase, and generally cool, polar conditions during the Little Ice Age. During AD 1940–2000 (Zone III), organic microfossils indicate an extended open‐water season and decreased sea‐ice, with suggested amelioration surpassing that of Zone I. Although more marine studies are needed to place this record into an appropriate context, the succession from ameliorated (Zone I) to cooler, sea‐ice influenced conditions (Zone II) and finally to 20th‐century warming (Zone III) corresponds well with several terrestrial climatic records from the neighbouring mainland and Victoria Island, and with lower‐resolution marine records to the west. Copyright © 2011 John Wiley & Sons, Ltd.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.