The energetics and structure of the hydrogarnet defect in grossular: A computer simulation study

We have used computer simulation methods to model the structure and energetics of the hydrogarnet defect in grossular. The predicted structure is in good agreement with experimental data. The calculated energy for the reaction of water with grossular to form the hydrogarnet defect is 1.02 Ev (98 kJ mol^-1). This low energy of reaction suggests that such defects will be common in garnets where they could play an important role in effecting processes such as atomic transport.     

Dispersal of river sediments in coastal seas: Six contrasting cases

The fate of sediment seaward of river mouths involves at least four stages: supply via plumes; initial deposition; resuspension and transport by marine processes; and long-term net accumulation. The processes that operate at each stage, and relative roles of each stage in governing the long-term accumulation patterns, vary appreciably with river regime and coastal ocean environment. To illustrate the diversity and illuminate the process of dispersal, information is synthesized for six systems: Amazon, Changjiang, Mississippi, Columbia, Purari, and Huanghe. These systems differ markedly in terms of water discharge, sediment discharge, and coastal energy regime and much of the diversity of dispersal patterns is attributed to these differences as well as to the temporal sequencing of river discharge relative to oceanographic transport processes. Although the sediment: water ratio of the discharge of the Mississippi River is 70 times less than that of the Huanghe, both of these systems exhibit rapid deposition and accumulation of sediments near the river mouths. In contrast, sediments dispersed by, the other four systems are transported greater distances from the mouths by oceanographic processes, and are accumulating over relatively wide areas.     

Marble mylonites in the Bancroft shear zone, Ontario, Canada: microstructures and deformation mechanisms

Mylonitization of medium-grade marbles in the Bancroft shear zone, Ontario, Canada, is characterized by decreasing grain-size of both calcite and graphite, and a variety of textures. Calcite grain-sizes vary from several millimeters in the protolith, to 50–200 μm in mylonite, to <30 μm in ultramylonite. Corresponding calcite grain shapes are equant in the protolith, elongate in protomylonite (first-developed dimensional preferred orientation), equant in coarse mylonite, elongate in fine mylonite (second-developed dimensional preferred orientation) and generally equant in ultramylonite, which suggests that external energy (applied stress) that tends to elongate grains competed with internal energy sources (e.g. distortional strain) that favor equant shapes. Graphite grain-size changes from several millimeters to centimeters in the protolith to submicroscopic in ultramylonite. In the mylonitic stages, graphite is present as dark bands, while in the ultramylonitic stage it is preserved as a fine coating on calcite grains.Based on textural evidence, twinning (exponential creep; regime I), dynamic recrystallization (power law creep; regime II) and possibly grain boundary sliding superplasticity (regime III) are considered the dominant deformation mechanisms with increasing intensity of mylonitization; their activity is largely controlled by calcite grain-size. Calcite grain-size reduction occurred predominantly by the process of rotation recrystallization during the early stages of mylonitization, as indicated by the occurrence of core and mantle or mortar structures, and by the grain-size of subgrains and recrystallized grains. Grain elongation in S-C structures indicates the activity of migration recrystallization; these structures are not the result of flattening of originally equant grains. Differential stress estimates in coarse mylonites and ultramylonites, based on recrystallized grain-size, are 2–5 and 14–38 MPa, respectively. Initial grain-size reduction of graphite occurred by progressive separation along basal planes, analogous to mica fish formation in quartzo-feldspathic mylonites.Calcite-graphite thermometry on mylonitic and ultramylonitic samples shows that the metamorphic conditions during mylonitization were 475 ± 50°C, which, combined with a differential stress value of 26 MPa, gives a strain rate of 1.2 x 10⁻¹⁰s⁻¹ based on constitutive equations; corresponding displacement rates are <38 mmyr⁻¹.     

A mechanism for preferential H2O leakage from fluid inclusions in quartz,based on TEM observations

Preferential leakage of H₂O from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic H₂O-CO₂-rich inclusions in natural quartz. Knowledge of the physical and chemical characteristics of the leakage mechanism, which may be very complex, increases the value of natural fluid inclusions to metamorphic geology. It is proposed that crystal defects play a major role in nondecrepitative preferential H₂O leakage through quartz, and remain effective during metamorphism. Inclusions with either an internal overpressure or underpressure produce strain in the adjacent quartz crystal via the nucleation of many dislocations and planar defects (like Dauphiné twin boundaries). These defects allow preferential loss of H₂O from H₂O-CO₂-rich inclusions at supercritical conditions. The transport capacity of this leakage mechanism is enhanced by nucleation of small bubbles on defect structures. The nucleation of these bubbles seems to be a recovery process in strained crystals. Solubility gradients of quartz in water in a crystal with internally underpressurized inclusions may result in optical visible implosion halos in a three dimensional spatial arrangement, caused by the growth of small bubbles at the expense of the larger original fluid inclusion. Natural fluid inclusions from Naxos (Greece) are always associated with numerous interlinked dislocations. These dislocations may have been produced by plastic derormation or by crystal growth related processes (e.g. crack healing). The presence of small bubbles on these dislocations indicates that a similar leakage mechanism for H₂O must have occurred in these rocks.     

Notes on late Cenomanian and Turonianammonites from Touraine,Western France

Recent collecting in the type area of the Turonian stage and adjacent parts of Touraine in western France provides new geographic and stratigraphic records as well as additional systematic information on species of the ammonite genera Puzosia, Watinoceras, Metoicoceras, Mammites, Prohauericeras, Collignoniceras, Lecointriceras, Subprionocyclus and Sciponoceras.     

Late glacial and late Holocene moraines in the Cerros Cuchpanga, central Peru

Small ice fields on the western cordillera northeast of Lima were expanded to three times their present size in the recent past, and the regional snow line was probably about 100 m lower than it is today. Outwash from the expanded glaciers formed deltas of silt in valley-bottom lakes. When the ice lobes retreated, the reduced outwash was trapped behind recessional moraines, and the clear meltwater infiltrated into the limestone bedrock and emerged at the heads of the deltas in spring pools. The delta surfaces then became covered with peat, and radiocarbon dates for the base of the peat (1100 ± 70 and 430 ± 70 yr B.P. for two different deltas) indicate that the maximum ice advance was older than those dates and, thus, older than the Little Ice Age of many north-temperate regions. Much older moraines date from expansion of the same local summit glaciers to even lower levels in the main valleys, which had previously been inundated by the cordilleran ice field. The cordilleran deglaciation and this expansion of local glaciers probably occurred between 12,000 and 10,000 yr ago, on the basis of slightly contradictory radiocarbon dates.     

A direct measurement of the distribution in depth of 26Al in the Estacado meteorite

The two-dimensional distribution of ²⁶Al across a slice of the Estacado meteorite was measured using non-destructive γ-γ coincidence counting. The maximum activity was found to be 60 ± 2 dpm kg^?1 and the variation across the slice rather small. The intensity and distribution are in moderate agreement with existing theoretical models if the pre-atmospheric shape of the meteorite had been a sphere of radius 0.35 ± 0.05 m, but it was more likely to have been slightly non-spherical.