NEAR Infrared Spectrometer Photometry of Asteroid 433 Eros

We present near-infrared spectrometer (NIS) observations (0.8 to 2.4 μm) of the S-type asteroid 433 Eros obtained by the NEAR Shoemaker spacecraft and report results of our Hapke photometric model analysis of data obtained at phase angles ranging from 1.2° to 111.0° and at spatial resolutions of 1.25×2.5 to 2.75×5.5 km/spectrum. Our Hapke model fits successfully to the NEAR spectroscopic data for systematic color variations that accompany changing viewing and illumination geometry. Model parameters imply a geometric albedo at 0.946 μm of 0.27±0.04, which corresponds to a geometric albedo at 0.550 μm of 0.25±0.05. We find that Eros exhibits phase reddening of up to 10% across the phase angle range of 0-100°. We observe a 10% increase in the 1-μm band depth at high phase angles. In contrast, we observe only a 5% increase in continuum slope from 1.486 to 2.363 μm and essentially no difference in the 2-μm band depth at higher phase angles. These contrasting phase effects imply that there are phase-dependent differences in the parametric measurements of 1- and 2-μm band areas, and in their ratio. The Hapke model fits suggest that Eros exhibits a weaker opposition surge than either 951 Gaspra or 243 Ida (the only other S-type asteroids for which we possess disk-resolved photometric observations). On average, we find that Eros at 0.946 μm has a higher geometric albedo and a higher single-scatter albedo than Gaspra or Ida at 0.56 μm; however, Eros's single-particle phase function asymmetry and average surface macroscopic roughness parameters are intermediate between Gaspra and Ida. Only two of the five Hapke model parameters exhibit a notable wavelength dependence: (1) The single-scatter albedo mimics the spectrum of Eros, and (2) there is a decrease in angular width of the opposition surge with increasing wavelength from 0.8 to 1.7 μm. Such opposition surge behavior is not adequately modeled with our shadow-hiding Hapke model, consistent with coherent backscattering phenomena near zero phase.     

Ice Age mystery: a proposed theory for the cause of long term climate change

Summary ?Analysis of available data shows that the duration of the glacial/interglacial cycle is determined by the time for the ocean to go through one major temperature cycle. At the start of an interglacial period, clear skies with consequent release of CO₂ from the ocean, warms the atmosphere, which in turn eventually warms the ocean to its maximum. Cloudy skies then cause the climate (land and air temperature) to cool and the CO₂ to be reabsorbed to start glaciation preliminaries. The albedo feedback effect of the glacial ice, a relatively warm ocean, which produces enhanced cloud cover, and the increased solubility of CO₂ in cold seawater ensure a long period of glaciation. Glacial periods end when pack ice spreads out on the ocean cooling it until reduced cloud cover once again allows the Sun’s heat, unreflected by cloud cover, to melt the ice and release CO₂ back into the atmosphere. Received May 22, 2002; accepted June 20, 2002     

Challenges and strategies for better use of scientific information in the management of coastal estuaries

Numerous studies have concluded that better use of scientific information could improve the quality of coastal and estuarine environmental management. Approaches for effecting such a change include ecosystem-based, integrated, and adaptive management, but such basic re-orientation of estuarine and coastal management has proved difficult to achieve. Even environmental indicators, seemingly straightforward ways of injecting scientific information into decision making, have achieved broad on-the-ground use in relatively few instances—principally the largest estuary management programs. A conceptual framework useful for examining environmental management systems affecting the five PNCERS (Pacific Northwest coastal Ecosystems Regional Study) estuaries conceives of environmental managers, researchers, and interested and affected parties in the public as interacting through the multi-layered institutional arrangements that currently promote the utilization, management, or protection of coastal and estuarine resources. Considerable variation exists in the approach and effectiveness of the region's environmental management organizations. Interaction between science and management in the region appears to be limited to an extent by high transaction costs; a cultural divide between environmental scientists and environmental managers is perceived by members of both groups who work with the PNCERS estuaries as inhibiting communications between them. Mechanisms that both groups identify as useful for improving the flow of information between science and management are little used, perhaps as a result. The two groups have very different patterns of information dissemination and acquisition, and though both chose agency archives and databases as their top methods for disseminating information, neither group relies much on these vehicles for information they seek. Both residents' and practitioners' perceptions of threats to the PNCERS estuaries show patterns of estuary-to-estuary variation. One theme that emerges is that problems associated with poor land management in adjacent uplands are common to most of these estuaries, potentially providing a sense of commonality through which a more regional approach to estuary management could emerge. A common set of estuarine environmental indicators implemented for all estuaries could help instigate such a regional approach, but resource constraints, especially at the local level, will have to be overcome for that to occur. There is currently substantial lack of common vision among coastal practitioners as to the purpose and desirability of indicators, and relatively little experience or knowledge of their use, particularly at the local level. Use of estuarine science in the management of these estuaries appears to be greatest during periods in which the largest programmatic shifts in environmental management approaches occur, an observation consistent with other studies that have concluded that the use of environmental science in environmental management tends to be episodic.     

Provenance and diagenesis of the evaporite-bearing Burns formation, Meridiani Planum, Mars

Impure reworked evaporitic sandstones, preserved on Meridiani Planum, Mars, are mixtures of roughly equal amounts of altered siliciclastic debris, of basaltic provenance (40 ± 10% by mass), and chemical constituents, dominated by evaporitic minerals (jarosite, Mg-, Ca-sulfates ± chlorides ± Fe-, Na-sulfates), hematite and possibly secondary silica (60 ± 10%). These chemical constituents and their relative abundances are not an equilibrium evaporite assemblage and to a substantial degree have been reworked by aeolian and subaqueous transport. Ultimately they formed by evaporation of acidic waters derived from interaction with olivine-bearing basalts and subsequent diagenetic alteration. The rocks experienced an extended diagenetic history, with at least two and up to four distinct episodes of cementation, including stratigraphically restricted zones of recrystallization and secondary porosity, non-randomly distributed, highly spherical millimeter-scale hematitic concretions, millimeter-scale crystal molds, interpreted to have resulted from dissolution of a highly soluble evaporite mineral, elongate to sheet-like vugs and evidence for minor synsedimentary deformation (convolute and contorted bedding, possible teepee structures or salt ridge features). Other features that may be diagenetic, but more likely are associated with relatively recent meteorite impact, are meter-scale fracture patterns, veins and polygonal fractures on rock surfaces that cut across bedding. Crystallization of minerals that originally filled the molds, early cement and sediment deformation occurred syndepositionally or during early diagenesis. All other diagenetic features are consistent with formation during later diagenesis in the phreatic (fluid saturated) zone or capillary fringe of a groundwater table under near isotropic hydrological conditions such as those expected during periodic groundwater recharge. Textural evidence suggests that rapidly formed hematitic concretions post-date the primary mineral now represented by crystal molds and early pore-filling cements but pre-date secondary moldic and vug porosity. The second generation of cements followed formation of secondary porosity. This paragenetic sequence is consistent with an extended history of syndepositional through post-depositional diagenesis in the presence of a slowly fluctuating, chemically evolving, but persistently high ionic strength groundwater system.     

Contaminated ground and contaminated estuary sediment illustrated by two case histories

 Contaminated ground forms a problem in all of the industrialized countries of the world. Contaminated ground may give rise to hazards and that implies a degree of risk which also involves a problem of definition. The investigation of a site which is suspected of being contaminated differs somewhat from a routine site investigation. Sampling of soil, groundwater and gas-producing material may be required. Various precautions may be necessary to do this and personnel may have to wear protective clothing. The first case history considered involves a site investigation for a relief sewer in Glasgow. As the site investigation progressed it ran into made-ground which contained chemical waste. The presence of this waste meant that the nature of the investigation changed and much more stringent safety precautions had to be taken. It also meant that the initial location of the sewer tunnel had to be repositioned at greater depth in uncontaminated sandstone rather than in the superficial deposits above. The other case history considers the contamination of sediments in the Forth Estuary. When trace metals are released into the water column they can be transferred rapidly to the sediment phase by adsorption onto suspended particulate matter, followed by sedimentation. Intertidal flats may be considered as important trace metal sinks since they accumulate large amounts of suspended matter. Hence, in polluted estuaries the deposition of suspended particles on intertidal flats may thus cause severe contamination. The Forth Estuary has unique contamination for British estuaries; it is experiencing significant Hg pollution. In addition, due to the presence of a nuclear submarine base in the Forth Estuary, ⁶⁰Co is detectable in the intertidal sediments. Temporal and spatial contamination patterns were analysed in relation to historical and present pollution point sources. The effect of fluvial and marine sediment mixing on trace metals and other processes controlling contaminant levels is reviewed. Preliminary results on quantifying sediment accretion rates using Caesium levels are discussed. Received: 9 August 1996 · Accepted: 17 December 1996     

Stone preservation with illustrative examples from the United Kingdom

Interest in the preservation of rapidly decaying monuments, especially in urban areas, has increased appreciably over the last three decades. A stone preservative can be defined as a chemical treatment, which, when applied to stone, combats the harmful effects of time and environment, thereby prolonging the life of a stone by either restoring its physical integrity or by inhibiting its decay. Any preservative applied to stone must not change the natural appearance or architectural value of the stone to any appreciable extent. There are two principal means by which stone can be preserved. One involves the formation of an outer stabilized zone around the stone; the other alters the chemical composition of the stone.A number of examples of stone preservation carried out on ancient monuments in the United Kingdom are taken to illustrate stone preservation methods. Their relative success is evaluated, and some more recent developments in stone preservation referred to.     

Nd and Sr isotope systematics of the Oka complex,Quebec, and their bearing on the evolution of the sub-continental upper mantle

A detailed isotopic study of minerals and whole rocks from the Cretaceous Oka complex, Quebec, Canada, shows a very small variation in initial Nd and Sr isotopic compositions. Assuming an age of 109 Ma for the complex, apatite, calcite, garnet, melilite, monticellite, olivine and pyroxene and whole rocks yield a range for initial ⁸⁷Sr/⁸⁶Sr of 0.70323–0.70333; and for initial ¹⁴³Nd/¹⁴⁴Nd of 0.51271–0.51284 ( _SR(T)= –14.8 to –16.2; _Nd(T)=+4.1 to +6.6). The negative _SR and positive _Nd indicate derivation of the Nd and Sr from a source with a time-integrated depletion in the large-ion lithophile (LIL) elements. This agrees with data from other Canadian carbonatites and confirms that a large part of the Canadian Shield is underlain by a source region depleted in the LIL elements. The new data from Oka suggest that the depleted source may have remained coupled to the continental crust until recent time.     

What it takes to make a planet

What lay behind the decision to reclassify Pluto as a "dwarf planet" at August's IAU General Assembly in Prague?     

Temporal Variability in Ecological Stoichiometry and Material Exchange in a Tidally Dominated Estuary (North Inlet,South Carolina) and the Impact on Community Nutrient Status

Across the coastal zone, rates of carbon and nutrient exchange are defined by the spatiotemporal heterogeneity of individual estuarine systems. Elemental stoichiometry provides a mechanism for simplifying overlapping physical, chemical, and biological drivers into proxies that can be used to compare and monitor estuarine biogeochemistry. To this end, the seasonal and tidal variability of estuarine stoichiometry was examined over an annual cycle in North Inlet (NI), South Carolina. Surface samples for dissolved and particulate carbon (C), nitrogen (N), and phosphorus (P) were collected every 20 days (August 2014 to August 2015) over a semi-diurnal tidal cycle. Dissolved nutrient flux estimates of an individual tidal creek were also made. Overall, the results demonstrated the dominance of seasonal versus tidal forcing on water column C:N:P stoichiometry. This seasonal behavior mediated the relative exchange of N and P into and out of the tidal creek and influenced the nutrient status index (NSI) of NI plankton communities. These communities were largely N deficient with the magnitude of this deficiency impacted by assumptions of inorganic versus organic plankton P demand and nutrient supply. Persistent N deficiency appeared to help drive the net import of N, while temporary P surplus likely drives its seasonal export. Combined, these results indicate that material delivery must be considered on seasonal time frames, as net annual fluxes do not reflect the short-term deliveries of C and nutrients into nearshore ecosystems.     

Stratigraphic hierarchy and three-dimensional evolution of an exhumed submarine slope channel system

Submarine slope channel systems have complicated three-dimensional geometries and facies distributions, which are challenging to resolve using subsurface data. Outcrop analogues can provide sub-seismic-scale detail, although most exhumed systems only afford two-dimensional constraints on the depositional architecture. A rare example of an accessible fine-grained slope channel complex set situated in a tectonically quiescent basin that offers seismic-scale, down-dip and across-strike exposures is the Klein Hangklip area, Tanqua-Karoo Basin, South Africa. This study investigates the three-dimensional architecture of this channel complex set to characterise the stratigraphic evolution of a submarine channel-fill and the implications this has for both sediment transport to the deep-oceans and reservoir quality distribution. Correlated sedimentary logs and mapping of key surfaces across a 3 km² area reveal that: (i) the oldest channel elements in channel complexes infill relatively deep channel cuts and have low aspect-ratios. Later channel elements are bound by comparatively flat erosion surfaces and have high aspect-ratios; (ii) facies changes across depositional strike are consistent and predictable; conversely, facies change in successive down depositional dip positions indicating longitudinal variability in depositional processes; (iii) stratigraphic architecture is consistent and predictable at seismic-scale both down-dip and across-strike in three-dimensions; (iv) channel-base-deposits exhibit spatial heterogeneity on one to hundreds of metres length-scales, which can inhibit accurate recognition and interpretations drawn from one-dimensional or limited two-dimensional datasets; and (v) channel-base-deposit character is linked to sediment bypass magnitude and longevity, which suggests that time-partitioning is biased towards conduit excavation and maintenance rather than the fill-phase. The data provide insights into the stratigraphic evolution and architecture of slope channel-fills on fine-grained continental margins and can be utilised to improve predictions derived from lower resolution and one-dimensional well data.