小刺豆荚软珊瑚化学成分研究

对采自南海南沙群岛永暑礁水域的小刺豆荚软珊瑚Lobophytummicrospiculatum的化学成分进行了研究,分离出7个化合物。其中化合物1为新的神经酰胺,命名为小刺酰胺。化合物3为22－表－孕马烷甾醇,首次从软珊瑚中分离到。     

On the identification of ship coupled heave–pitch motions using neural networks

This paper outlines a procedure for the derivation of the differential equations describing the free response of a heaving and pitching ship from its stationary response to random waves. The coupled heave–pitch motion of a ship in random seas is modelled as a multi-dimensional Markov process. The partial differential equation describing the transition probability density function, known as the Fokker-Planck equation, for this process is derived. The Fokker-Planck equation is used to derive the random decrement equations for the coupled heave–pitch motion. The parameters in these equations are then identified using a neural network approach. The method is validated using numerical simulations and experimental results. The experimental data was obtained using an icebreaker ship model heaving and pitching in random waves. It is shown that the method produces good results when the system is lightly damped. An extension for using this method to identify couple heave–pitch motion in realistic seas is suggested.     

Magnetic susceptibility of ultrahigh pressure eclogite: The role of retrogression

Retrograde metamorphism played the dominant role in changing the low-field rock magnetic properties and density of 198 specimens of variably retrograded eclogites from the main borehole of the Chinese Continental Scientific Drilling Project (CCSD) and from surface outcrops in the Donghai area in the southern part of the Sulu UHP belt, China. Bulk magnetic susceptibility (κ) of unretrogressed UHP eclogite is controlled by whole-rock chemical composition and ranges from 397 to 2312 μSI with principal magnetic susceptibility carrying minerals paramagnetic garnet, omphacite, rutile and phengite. Partially retrograded eclogites show large variations in magnetic susceptibility between 804 and 24,277 μSI, with high mean magnetic susceptibility values of 4372 ± 4149 μSI caused by appreciable amounts of Fe-Ti oxide minerals such as magnetite, ilmenite and/or titanohematite produced by retrograde metamorphic reactions. Completely retrograded eclogites have lower susceptibilities of 1094 ± 600 μSI and amphibolite facies mineral assemblages lacking high magnetic susceptibility minerals. Jelínek's corrected anisotropy (P_j) of eclogites ranges from 1.001 to 1.540, and shows a positive correlation with low-field magnetic susceptibility (κ). Arithmetic mean bulk density (ρ) shows a steady decrease from 3.54 ± 0.11 g/cm³ (fresh eclogite) to 2.98 ± 0.06 g/cm³ (completely retrograded eclogite). Retrograde metamorphic changes in mineral composition during exhumation appear to be the major factor causing variations in low field magnetic susceptibility and anisotropy. Retrograde processes must be taken into account when interpreting magnetic surveys and geophysical well logs in UHP metamorphic terranes, and petrophysical properties such as density and low-field magnetic susceptibility could provide a means for semi-quantifying the degree of retrogression of eclogite during exhumation.     

干旱区典型绿洲耕地扩张及其人文驱动研究——以新疆且末绿洲为例

近年来,在全国耕地面积持续减少的背景下,西北干旱区耕地呈扩张趋势,现有研究关注其自然因素驱动力,对人文因素驱动力,特别是灌溉设施和方式、政策、经济利益和市场导向等因素关注较少。选取干旱区典型绿洲——且末绿洲,采用最大似然法和人机交互式分类相结合的方法从1972,1990,2001,2011年影像中提取耕地信息,结合统计学方法分析且末绿洲耕地变化的时空趋势、耕地复种指数的动态变化;在充分考虑人口因素的前提下,增加灌溉设施和方式、政策、经济利益和市场导向等因素,探讨了绿洲耕地扩张的人文驱动力。研究结果表明:1970年以来,且末绿洲耕地面积时增时减,总体呈增长趋势;耕地复种指数波动上升;人口增长、灌溉设施和方式、政策、经济利益和市场等因素在不同阶段以不同方式影响着该绿洲耕地面积的扩张。政策、经济利益和市场因素是近10年绿洲耕地迅速扩张的主要驱动因素。     

始新统油气系统:泰国湾东北部油气勘探新层系

泰国湾区域经历了前裂谷期、裂谷期、裂后期的构造演化阶段,形成了多个裂谷盆地。泰国湾区域东北部在渐新世经历了一次明显构造反转,较泰国湾区域大部分地区强烈。通过对比区内钻井,结合地震解释,对该区的沉积特征和构造演化进行了分析,认为这次反转构造导致了反转构造带上构造、沉积特征与邻区有较大的不同。由于这次反转构造,泰国湾东北部在新层系发育新类型的油气系统,即深部的始新统油气系统:烃源岩为中始新统湖相泥岩,储层为上始新统-渐新统三角洲相砂岩,盖层为下中新统三角洲前缘相泥岩和上中新统以上的海相泥岩。该油气成藏系统已被钻井钻遇油气显示,是本区有效油气成藏系统。     

西南印度洋深海热液硫化物区沉积物微生物群落结构和固氮基因多样性

A sediment sample was collected from a deep-sea hydrothermal vent field located at a depth of 2 951 m on the Southwest Indian Ridge. Phylogenetic analyses were performed on the prokaryotic community using polymerase chain reaction（PCR） amplification of the 16 S rRNA and nifH genes. Within the Archaea, the dominant clones were from marine benthic group E（MBGE） and marine group I（MGI） belonging to the phyla Euryarchaeota and Thaumarchaeota, respectively. More than half of the bacterial clones belonged to the Proteobacteria, and most fell within the Gammaproteobacteria. No epsilonproteobacterial sequence was observed. Additional phyla were detected including the Actinobacteria, Bacteroidetes, Planctomycetes, Acidobacteria, Nitrospirae, Chloroflexi, Chlorobi, Chlamydiae, Verrucomicrobia, and candidate divisions OD1, OP11, WS3 and TM6, confirming their existence in hydrothermal vent environments. The detection of nifH gene suggests that biological nitrogen fixation may occur in the hydrothermal vent field of the Southwest Indian Ridge. Phylogenetic analysis indicated that only Clusters I and III NifH were present. This is consistent with the phylogenetic analysis of the microbial 16 S rRNA genes, indicating that Bacteria play the main role in nitrogen fixation in this hydrothermal vent environment.     

杭州湾海域春、秋季鱼类种类组成和数量分布

采用底层拖网法,用渔获率作为鱼类资源数量分布的指标,进行了杭州湾调查海域2012年5月(春季)、10月(秋季)2个季节的鱼类种类组成、区系特点、数量分布等研究。结果表明:(1)杭州湾海域春、秋两季共获得并鉴定出的鱼类有31种,隶属于9目15科,其中以石首鱼科和■虎鱼科的种类为最多,各有5种,分别占总种数的16.7%;鳀科鱼类次之,有4种,占总种数的13.3%,优势种有睛尾蝌蚪■虎鱼、龙头鱼、刀鲚、棘头梅童鱼;(2)根据鱼类适温性可将该海域的鱼类分为暖水性、暖温性和冷温性3种适温类型,以暖温性种类为主,暖水性种类次之,而冷温性种类极少,仅有1种;(3)根据其生态习性,可分为河口性、沿岸性和近海性3种生态类群;(4)渔获数量分布规律是春季在调查海域的内侧或者说中西部较高,而湾口较低,秋季则正好相反。     

黄海中南部近岸海域春季鱼类浮游生物群落空间格局研究

根据2015年春季在黄海中南部近岸海域进行的鱼类浮游生物大型浮游生物网水平拖网数据,采用生态多样性指数和多元统计分析等方法,研究了该海域鱼类浮游生物的种类组成和群落空间格局及其与环境因子的关系。结果表明,本次调查共采集到鱼类浮游生物35种,其中鱼卵21种,仔稚鱼23种。鱼类浮游生物隶属于8目18科34属,优势种为鳀（Engraulis japonicus）、鲬（Platycephalus indicus）、鱼衔属（Callionymus spp.）和小黄鱼（Pseudosciaena polyactis）。其中,鳀和鱼衔属主要分布于海州湾渔场海域,鲬主要分布于吕泗渔场海域,小黄鱼多分布于吕泗渔场北部海域。生态类型包括半咸水型、沿岸型和近海型种类。聚类分析表明,鱼类浮游生物群落可划分为以鱼衔属、鳀为优势种的站位组A（主要分布于海州湾海域）、以小黄鱼、黄鲫（Setipinna taty）等为优势种的站位组B（主要位于江苏沿岸海域）和以鲬为优势种的站位组C（主要位于江苏沿岸-近海海域）,以站位组B的群落物种多样性指数和均匀度指数最高。各站位组的鱼类浮游生物的生态类型和适温类型组成不同,这与其所处的海域生境有关。典范对应分析（CCA）表明,影响春季黄海中南部鱼类浮游生物群落空间结构的主要环境因子为水深和表层温度。同时也受洋流、底质类型等多种因素的综合影响。研究结果初步揭示了黄海中南部近岸海域鱼类浮游生物群落的空间格局,可为今后科学制定该海域水产种质资源保护区、资源量化管理等资源养护管理措施提供科学依据与技术支撑。     

渤海主要汇入河流碎屑磷灰石地球化学特征及成因

渤海的碎屑物质详细记录了源区的地质信息,对其进行物源示踪研究有助于提高我们对周围造山带及黄河的演化、中国东部陆架海碎屑物质扩散等的认识。本文利用激光剥蚀电感耦合等离子质谱分别对辽东湾、渤海湾及莱州湾周围主要汇入河流的碎屑磷灰石进行原位微量元素分析,结合Kolmogorov-Smirnov统计方法的多维判别图与反向传播神经网络等方法,分析渤海主要汇入河流碎屑磷灰石的微量元素与稀土元素。结果表明在汇入渤海的主要河流中,碎屑磷灰石的微量元素主要以Sr元素与Y元素为主,且都出现较为明显的HREE富集,但在不同河流之间的碎屑磷灰石Sr元素与REE也存在一定差异,这可能与其母岩不同相关。     

Pore-water geochemistry in methane-seep sediments of the Makran accretionary wedge off Pakistan: Possible link to subsurface methane hydrate

Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.