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941.
Understanding the formation of laminated, organic-rich sediments is an essential topic for researchers interested in fossil fuels, biogeochemical cycles, Earth's environmental history and global change. Biologists have very recently demonstrated that some marine phytoplankton blooms actively govern their own sedimentation by the formation of sticky transparent gels that facilitate rapid aggregation, accelerated sinking and efficient export flux. Here we present fossil evidence of unfragmented, low-diversity phytoplankton assemblages preserved as sedimentary laminae and irregular flocs that are attributable to a similar phytoplankton-driven sedimentary mechanism we term ‘self-sedimentation’. The geological evidence suggests that self-sedimentation precludes significant heterotrophic grazing, propels the formation of some conspicuous hemipelagic sedimentary laminae and results in efficient carbon and opal flux to the sediments. We suggest that the self-sedimentation phenomenon may have broad implications for the geological history of biogeochemical cycling, oceanic ecological dynamics, and abrupt atmospheric/environmental change. Broader recognition of the self-sedimentation phenomenon as explicitly defined here is a prerequisite to testing these unconventional hypotheses. 相似文献
942.
943.
Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden 总被引:7,自引:2,他引:7
This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying
podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists
of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe
analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation
horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation
zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite
and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite).
Received: 28 October 1996 · Accepted: 24 February 1997 相似文献
944.
Whole-rock and sulfide lead-isotope data from the hydrothermal JADE field in the Okinawa back-arc trough 总被引:7,自引:0,他引:7
The mineralization of the active hydrothermal JADE field resembles in many aspects the Kuroko-type mineralization. The JADE
field is located in a back-arc graben and is associated with a bimodal volcanism. Lead isotope data from igneous rocks, sediments,
and ores further emphasize the similarities with the Kuroko ores and suggest that both sediments and volcanic rocks contributed
comparable amounts of lead to the deposit. When compared to the sediments, a much larger volume of volcanic rocks must have
contributed lead to the deposit, because of the considerably lower lead concentration of volcanic rocks. In contrast to the
crustal type lead of the JADE field and the Kuroko-type sulfide deposits the lead isotope signatures of VMS-type deposits
at mid-ocean ridges is distinctly different. In the absence of a sedimentary cover it reflects the composition of the mantle
source, whereas in the presence of a sedimentary cover it is either a mixture of mantle and sedimentary lead or it may even
be completely dominated by the latter.
Received: 5 October 1995 / Accepted: 10 May 1996 相似文献
945.
Yucca Mountain, the proposed site for the high-level nuclear waste repository, is located just south of where the present
water table begins a sharp rise in elevation. This large hydraulic gradient is a regional feature that extends for over 100 km.
Yucca Mountain and its vicinity are underlain by faulted and fractured tuffs with hydraulic conductivities controlled by flow
through the fractures. Close to and parallel with the region of large hydraulic gradient, and surrounding the core of the
Timber Mountain Caldera, there is a 10- to 20-km-wide zone containing few faults and thus, most likely, few open fractures.
Consequently, this zone should have a relatively low hydraulic conductivity, and this inference is supported by the available
conductivity measurements in wells near the large hydraulic gradient. Also, slug injection tests indicate significantly higher
pressures for fracture opening in wells located near the large hydraulic gradient compared to the opening pressures in wells
further to the south, hence implying that lower extensional stresses prevail to the north with consequently fewer open fractures
there. Analytical and numerical modeling shows that such a boundary between media of high and low conductivity can produce
the observed, large hydraulic gradient, with the high conductivity medium having a lower elevation than the water table. Further,
as fractures can close due to tectonic activity, the conductivity of the Yucca Mountain tuffs can be reduced to a value near
that for the hydraulic barrier due to strain release by a moderate earthquake. Under these conditions, simulations show that
the elevation of the steady-state water table could rise between 150 and 250 m at the repository site. This elevation rise
is due to the projected shift in the location of the large hydraulic gradient to the south in response to a moderate earthquake,
near magnitude 6, along one of the major normal faults adjacent to Yucca Mountain. As the proposed repository would only be
200–400 m above the present water table, this predicted rise in the water table indicates a potential hazard involving water
intrusion.
Received: 7 June 1996 / Accepted: 19 November 1996 相似文献
946.
The time evolution of stratospheric aerosol layer formed after a volcanic eruption is studied taking into account the aerosol
microphysical processes of growth, coagulation and sedimentation. Using a simple model we could explain the observed evolution
of the Pinatubo volcanic layer which decayed in about 3 years. The experimental data obtained by Nd:YAG backscatter lidar
over Ahmedabad further supports this finding. The data obtained after the El Chichon volcanic eruption also showed that the
El Chichon aerosol layer decayed in about 3 years time. Thus, though the amount of SO2 injected has been higher, in the case of Pinatubo, about two to three times more than El Chichon, it has resulted in the
production of larger aerosol particles due to faster growth and coagulation processes, and subsequently a faster removal rate,
to give more or less a similar background aerosol amount at the stratosphere in about 3 years time. 相似文献
947.
948.
Electrokinetic remediation of metal contaminated glacial tills 总被引:2,自引:0,他引:2
This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed. 相似文献
949.
The 1900–1700 Ma Waterberg Group in the main Waterberg fault-bounded basin consists of dominantly coarse siliciclastic red
beds with minor volcanic rocks. The sedimentary rocks were deposited mainly by alluvial fans, fluvial braidplains and transgressive
shallow marine environments, with lesser lacustrine and aeolian settings. Uplifted, largely granitic source areas were located
along the Thabazimbi-Murchison lineament (TML) fault system in the south, and along the Palala shear zone in the northeast.
Palaeoplacer titanomagnetite-ilmenite-zircon heavy mineral deposits, best developed in the Cleremont Formation in the centre
of the basin, reflect initial fluvial reworking and subsequent littoral marine concentration. Coarse alluvial cassiterite
placer deposits are found in the Gatkop area in the southwest of the basin, and appear to have been derived from stanniferous
Bushveld Complex lithologies south of the TML. Hydrothermal zinc and U-Cu mineralisation in the Alma lithologies in the same
area appears to be related to the TML fault system. Small manganese deposits and anomalous tungsten values occur in the south
of the basin, where they are again closely spatially associated with the TML. Copper-barium mineralisation is found associated
with dolerite dykes, and in stratigraphically controlled, inferred syngenetic settings. The most interesting of these apparently
syngenetic occurrences is found within green coloured reduced mudrocks and inferred volcanic rocks, at an unconformity developed
within the overall red bed sequence of the Waterberg Group, adjacent to the TML in the southwest of the basin. The most important
potential mineralisation in the main Waterberg basin thus encompasses shoreline placer Ti and the possibility of substantial
sediment-hosted copper deposits.
Received: 31 May 1996 / Accepted: 17 February 1997 相似文献
950.
Diffusion of tetravalent cations in zircon 总被引:18,自引:1,他引:18
D. J. Cherniak J. M. Hanchar E. B. Watson 《Contributions to Mineralogy and Petrology》1997,127(4):383-390
Diffusion rates for the three tetravalent cations U, Th and Hf have been measured in synthetic zircon. Diffusant sources
included oxide powders and ground pre-synthesized silicates. Rutherford backscattering spectrometry (RBS) was used to measure
depth profiles. Over the temperature range 1400–1650 °C, the following Arrhenius relations were obtained (diffusion coefficients
in m2sec−1):
log D
Th = (1.936 ± 0.9820) + (− 792 ± 34 kJ mol−1 /2.303 RT)
log D
U = (0.212 ± 2.440) + (− 726 ± 83 kJ mol−1 /2.303 RT)
log D
Hf = (3.206 ± 1.592) + (− 812 ± 54 kJ mol−1 /2.303 RT)
The data show a systematic increase in diffusivity with decreasing ionic radius (i.e., faster diffusion rates for Hf than
for U or Th), a trend also observed in our earlier study of rare earth diffusion in zircon. Diffusive fractionation may be
a factor in the Lu-Hf system given the much slower diffusion rates of tetravalent cations when compared with the trivalent
rare earths. The very slow diffusion rates measured for these tetravalent cations suggest that they are essentially immobile
under most geologic conditions, permitting the preservation of fine-scale chemical zoning and isotopic signatures of inherited
cores.
Received: 12 July 1996 / Accepted: 2 December 1996 相似文献