Hydrogeological conditions and aquifers potentiality for sustainable development of the desert areas in Wadi Qena,Eastern Desert,Egypt

To increase the potentiality of development and land reclamation activities, the Egyptian government funds the construction of a new desert road in Upper Egypt. This road connects Upper Egypt with the Red Sea Governorate. Surrounding the road is 207,000 acres of land surface which is almost flat and suitable for reclamation. To ensure the sustainability of the proposed development surrounding the road, analyses of the morphometric parameters, infiltration test and the grain size distribution, geoelectrical and hydrogeological investigations were conducted in the area. The results indicated a possibility of flash flood hazards and poor drainage condition for land reclamation activities is expected. The hydrogeological and geoelectrical investigations revealed that the unconfined Quaternary and confined Nubian Sandstone aquifers are the main aquifers in the area. The depths to water in the two aquifers range from 18 to 36 and 80 to 300 m with an average thickness of 40 and 275 m, respectively. The aquifers are made of sands and silt with clay intercalations. The total dissolved solids of water ranges between 1,700 and 5,400 mg/L, whereas the sodium absorption ratio ranges between 7 and 30 meq/L, indicating the suitability of water for irrigating medium- to high-salt-tolerant crops with proper drainage facilities. Thus, water in this area is not suitable for domestic use. Based on hydrogeological equations, the available water for extraction from the aquifers in the area is about 17.195?×?10⁹ m³, and this volume is not feasible to reclaim the whole proposed area for reclamation. Meanwhile, it may be possible to water small farms (not more than 60,000 acres for 50 years). Surface water source should be considered for the sustainability development of the area.     

Calcareous nannofossil biostratigraphy and paleoecology of the Cenomanian – Turonian transition in the Tarfaya Basin, southern Morocco

An abundant and diverse nannoflora occurs across the Cenomanian/Turonian (C/T) boundary at Tazra in the Tarfaya Basin of southern Morocco. The nannoflora of this sequence permits recognition of three biozones (CC10-CC12), three subzones (CC10a, CC10b and CC10c), and thirteen important nannolith bioevents previously reported from this interval elsewhere. The floral record shows erratic species abundance fluctuations that clearly vary with lithology and reflect at least in part preservational bias and diagenetic processes. In general, four dissolution resistant taxa are dominant: Watznaueria barnesae, Eiffellithus turriseiffelii, Eprolithus floralis, and Zeugrhabdotus spp. The late Cenomanian Zone CC10 marks a rapid excursion in ∂¹³C and is characterized by the successive extinction of four taxa, which are widely recognized as reliable biomarkers: Corollithion kennedyi, Axopodorhabdus albianus, Lithraphidites acutus, and Helenea chiastia. This interval is also marked by high species richness and high abundance of the tropical species Watznaueria barnesae, suggesting warm tropical waters. The subsequent ∂¹³C plateau and organic carbon-rich black shale deposition of the oceanic anoxic event (OAE2) is characterized by low species richness, but high nannofossil abundance, and peak abundance of the cool water and high productivity indicator Zeugrhabdotus spp., followed by the first peak abundance of cool water Eprolithus floralis. This interval correlates with the planktic foraminiferal diversity minimum and the Heterohelix shift, which marks the expansion of the oxygen minimum zone (OMZ). The C/T boundary is identified based on the FO of Quadrum gartneri, which is <1 m below the FO of the planktic foraminifer C/T marker Helvetoglobotruncana helvetica. In the early and middle Turonian, the two dominant species, tropical W. barnesae and cool water E. floralis, alternate in abundance and suggest fluctuating climatic conditions.     

Development of a new connection for precast concrete walls subjected to cyclic loading

The Industrialized Building System (IBS) was recently introduced to minimize the time and cost of project construction. Accordingly, ensuring the integration of the connection of precast components in IBS structures is an important factor that ensures stability of buildings subjected to dynamic loads from earthquakes, vehicles, and machineries. However, structural engineers still lack knowledge on the proper connection and detailed joints of IBS structure construction. Therefore, this study proposes a special precast concrete wall-to-wall connection system for dynamic loads that resists multidirectional imposed loads and reduces vibration effects (PI2014701723). This system is designed to connect two adjacent precast wall panels by using two steel U-shaped channels (i.e., male and female joints). During casting, each joint is adapted for incorporation into a respective wall panel after considering the following conditions: one side of the steel channel opens into the thickness face of the panel; a U-shaped rubber is implemented between the two channels to dissipate the vibration effect; and bolts and nuts are used to create an extension between the two U-shaped male and female steel channels. The developed finite element model of the precast wall is subjected to cyclic loads to evaluate the performance of the proposed connection during an imposed dynamic load. Connection performance is then compared with conventional connections based on the energy dissipation, stress, deformation, and concrete damage in the plastic range. The proposed precast connection is capable of exceeding the energy absorption of precast walls subjected to dynamic load, thereby improving its resistance behavior in all principal directions.     

An efficient Co-ZSM-5 catalyst for the abatement of volatile organics in air: effect of the synthesis protocol

Co supported on ZSM-5 (Co-ZSM-5) catalysts was synthesized by wet ion exchange (WIE), impregnation (IM), and in situ hydrothermal (IHT) methods. Their adsorptive catalytic activities for the removal of VOC’s [Benzene, Toluene, Ethylbenzene and Toluene (BTEX)] in air were tested. The physicochemical properties were investigated by XRD, FTIR, SEM, XPS, and low-temperature N₂ adsorption. The results indicate that the catalytic performance of Co-ZSM-5 for VOC’s abatement is effective and the synthesis methods reasonably influence the catalytic activity of Co-ZSM-5. Among three samples prepared by three different methods, the catalyst synthesized by the hydrothermal method possesses the highest adsorptive catalytic activity for BTEX oxidation. The optimized contact time was 60 min. The catalytic activities of the prepared catalysts are varied in the order of IHT > IM > WIE based on the combined removal capacity 59.24 > 34.46 > 23.82 (mg/g). For the Co-ZSM-5 WIE catalysts, the procedure has an evident effect on their catalytic performance. For example, the WIE catalysts prepared with cobalt chloride (II) by ion exchange have a higher acidity and surface area than the catalyst prepared with cobalt chloride (II) by impregnation method but less cobalt content. The excellent performance of IHT catalysts may be endorsed to the better availability of the oxidized form (Co³⁺), due to high content, higher surface area and acidity. Moreover, the Co-ZSM-5 catalyst synthesized by the IHT method shows high stability after being used.     

Seismic based characterization of total organic content from the marine Sembar shale,Lower Indus Basin,Pakistan

The exploration and production of unconventional resources has increased significantly over the past few years around the globe to fulfill growing energy demands. Hydrocarbon potential of these unconventional petroleum systems depends on the presence of significant organic matter; their thermal maturity and the quality of present hydrocarbons i.e. gas or oil shale. In this work, we present a workflow for estimating Total Organic Content (TOC) from seismic reflection data. To achieve the objective of this study, we have chosen a classic potential candidate for exploration of unconventional reserves, the shale of the Sembar Formation, Lower Indus Basin, Pakistan. Our method includes the estimation of TOC from the well data using the Passey’s ΔlogR and Schwarzkofp’s methods. From seismic data, maps of Relative Acoustic Impedance (RAI) are extracted at maximum and minimum TOC zones within the Sembar Formation. A geostatistical trend with good correlation coefficient (R²) for cross-plots between TOC and RAI at well locations is used for estimation of seismic based TOC at the reservoir scale. Our results suggest a good calibration of TOC values from seismic at well locations. The estimated TOC values range from 1 to 4% showing that the shale of the Sembar Formation lies in the range of good to excellent unconventional oil/gas play within the context of TOC. This methodology of source rock evaluation provides a spatial distribution of TOC at the reservoir scale as compared to the conventional distribution generated from samples collected over sparse wells. The approach presented in this work has wider applications for source rock evaluation in other similar petroliferous basins worldwide.     

Elemental characterization of black shales of Khyber Pakthunkhawa (KPK) region of Pakistan using AAS

Black shale samples were collected from Chimiari Khyber Pakthunkhawa region of Pakistan and were analyzed for elemental compositions. Atomic Absorption Spectrophotometry (AAS) was utilized for the determination of elements in the digested solutions. The analysis of black shale was performed precisely with relative standard deviation (RSD) lower than 2%. Results showed that the samples contained high concentrations of Ca (11.98 %), Al (7.09%), Fe (3.03%), Mg (0.59%) and Ti (0.58%).     

Runoff Estimation and Morphometric Analysis for Hesaraghatta Watershed Using IRS–1D LISS III FCC Satellite Data

The study area, Hesaraghatta watershed is located between 77° 20′ to 77° 42′ E longitude and 13° 10′ to 13° 24′ N latitude with an area of 600.01 km². Thematic layers such as Land Use/Land Cover, drainage, soil and hydrological soil group were generated from IRS–1D LISS III satellite data (FCC). An attempt was made to estimate runoff using Soil Conservation Service (SCS) curve number model and it was estimated to be 1960, 2066, 1870 and 1810 mm for sub-watersheds 1, 2, 3 and 4 respectively. Quantitative morphometric analysis was carried out for the entire watershed and the four sub-watersheds independently by estimating their (a) linear aspects like stream order, stream length, stream length ratio, bifurcation ratio, length of overland flow, drainage pattern (b) aerial aspects like shape factor, circulatory ratio, elongation ratio and drainage density and (c) relief aspects like basin relief, relief ratio, relative relief and ruggedness number. Drainage density was estimated to be 1.23 km/km² designating the study area as a very coarse textured watershed.     

Analysis of China vegetation dynamics using NOAA-AVHRR data from 1982 to 2001

The authors derived the normalized difference vegetation index (NDVI) from the NOAA/AVHRR Land dataset, at a spatial resolution of 8km and 15-day intervals, to investigate the vegetation variations in China during the period from 1982 to 2001. Then, GIS is used to examine the relationship between precipitation and the Normalized Difference Vegetation Index (NDVI) in China, and the value of NDVI is taken as a tool for drought monitoring. The results showed that in the study period, China’s vegetation cover had tended to increase, compared to the early 1980s; mean annual NDVI increased 3.8%. The agricultural regions (Henan, Hebei, Anhui and Shandong) and the west of China are marked by an increase, while the eastern coastal regions are marked by a decrease. The correlation between monthly NDVI and monthly precipitation/temperature in the period 1982 to 2001 is significantly positive (R2=0.80, R2=0.84); indicating the close coupling between climate conditions (precipitation and temperature) and land surface response patterns over China. Examination of NDVI time series reveals two periods: (1) 1982–1989, marked by low values below average NDVI and persistence of drought with a signature large-scale drought during the 1982 and 1989; and (2) 1990–2001, marked by a wetter trend with region-wide high values above average NDVI and a maximum level occurring in 1994 and 1998.     

Improvement in Engineering Properties of Expansive Soils using Ground Granulated Blast Furnace Slag

Improvement in engineering properties of expansive soils by mixing ground granulated blast furnace slag (GGBFS) is the main focus of this research. For this purpose two expansive soil samples were collected from DG Khan and Sialkot areas (Pakistan). Classification tests revealed that DG Khan sample belonged to fat clay (CH) while Sialkot soil was lean clay (CL) as classified by Unified Soil Classification System. GGBFS has been added in varying proportions between 0 and 55% in these soil samples to study its role in stabilizing these expansive soils. Based on the laboratory test performed on composite soil samples, it was observed that maximum dry unit weight increased up to 10 % by adding 50% GGBFS in both samples. California bearing ratio (CBR) value showed an increase from 3.2 % to 11.5% for DG Khan soil while CBR values varied from 2.4% to 10.7% for Sialkot soil by mixing 50% GGBFS. Addition of 30 % GGBFS to DG Khan soil reduced swell potential from 8 % to 2 % while in Sialkot soil, 20 % addition of GGBFS reduced swell potential from 5 % to 2 %. Unconfined compressive strength of remoulded sample cured for 28 days increased by about 35% with the addition of 30%GGBFS. The results indicated that mixing of GGBFS in the expansive soil samples have a marked increase in their engineering properties. Also, it is an affective and environmental friendly means to dispose waste of steel industry.     

SWAT manual calibration and parameters sensitivity analysis in a semi-arid watershed in North-western Morocco

Being a laborious approach, manual calibration of hydrologic model in a semi-arid context requires in-depth knowledge of the watershed and as much as possible field input data to obtain reliable simulations. In this study, manual calibration and relative sensitivity analysis approaches of the SWAT model (Soil and Water Assessment Tool) were applied for water balance in a 1993 km² watershed (on the R’dom river) located in North-western Morocco. The watershed is located in a semi-arid area dominated by agro-forestry activities. The objectives of this study were (i) to perform a local sensitivity analysis of the SWAT model taking into consideration the watershed characteristics and (ii) to implement a detailed methodology of manual calibration and validation of the model in a semi-arid context. Sensitivity analysis has been carried out on 12 different SWAT input parameters, and has revealed that 4 input parameters only were the most influential ones on flow components of the R’dom watershed. Model manual calibration was conducted along 2006 and 2007 by comparing measured and predicted monthly and daily discharges and taking Nash-Sutcliffe coefficient (NSE), determination coefficient (R ²), and percent bias (PBIAS) as goodness-of-fit indicators. Validation has been performed by the same approach through 2008 and 2009 period. All final NSE values were above 0.5, R ² values exceeded 0.7, and PBIAS lower than 25% demonstrating satisfactory model performances over the study watershed conditions. The SWAT model set-up with measured input data, manually calibrated and validated, reflects well the real hydrologic processes occurring in the R’dom watershed and can be used to assess current and future conditions and to evaluate alternative management practices.