The significance of silica precipitation on the formation of the permeable–impermeable boundary within Earth's crust

The hydrological system within Earth's crust is divided into the permeable zone and the underlying, much less permeable zone. In this study, we investigated the solubility and precipitation kinetics of silica in water under the conditions of the Kakkonda geothermal field, Japan, where well WD‐1a penetrates the boundary between the hydrothermal convection zone and the heat conduction zone. We found that quartz solubility has a local minimum at the depth of the hydrological boundary, at ~3100‐m depth (380 °C and 24 MPa), in the case of either hydrostatic conditions or fluid pressure increase above hydrostatic at deeper levels. The hydrothermal experiments reveal that rapid quartz precipitation occurs via nucleation when fluids are brought from the liquid region to the supercritical region. The preferential precipitation of quartz at a specific depth plays a significant role in forming and sustaining the permeable–impermeable boundary in the crust.     

Analysis of dust events in 2008 and 2009 using the lidar network, surface observations and the CFORS model

The Asian dust events in 2008 (May 24–June 4 in 2008) and in 2009 (March 12–25, October 13–26, and December 15–28 in 2009) were analyzed with the lidar network observations, surface observations in China, Korea, Japan, and Mongolia, and with the chemical transport model CFORS. Transport of Asian dust and mixing of dust with air pollution aerosols were studied. The event of May 24 to June 4 in 2008 was a significant event unusually late in the spring dust season. The dust event of March 12–25, 2009 was an interesting example of elevated dust layer, and transport of dust from the elevated dust layer to the ground by the boundary layer activity was observed with the lidars and surface observations in Japan. The concentration of air pollution aerosols was relatively high during the dust event, and the results suggest that vertical structure as well as transport path is important for the mixing of dust and air pollution aerosols. The dust events in October and December 2009 were examples of dust events in autumn and winter. The online mode CFORS reproduced the observation data generally well, except for the event of May 24 to June 4 in 2008. The results of the fourdimensional variational assimilation of the lidar network data reproduced the dust concentration in Korea and Japan reasonably in that event.     

Strain localization analysis by elasto-viscoplastic softening model for frozen sand

The aim of the present paper is to numerically analyse the behaviour of frozen sand by using a viscoplastic constitutive model with strain softening. A constitutive model has been developed introducing the stress history tensor which is a functional of the stress history, with respect to a generalized time measure. It is shown that Adachi and Oka's model is applicable to the results of triaxial tests on a frozen Toyoura sand at different strain rates. First, the instability of the model is discussed within the framework of bifurcation theory. The model is then implemented into a FEM code to numerically simulate the behaviour under plane strain conditions. From the numerical results, it is revealed that the formation of shear bands is possible and the characteristics of strain localization, such as shear banding, depend on the strain rates.     

Physical behavior of the SEEDS iron-fertilized patch by sulphur hexafluoride tracer release

The first iron (Fe) – fertilization experiment in the western North Pacific was carried out using SF₆ to trace the Fe-fertilized water mass. A solution in 10,800 liters of seawater of 350 kg of Fe and 0.48 M of SF₆ tracer was released into the mixed layer over a 8 × 10 km area. On the first underway transects through the patch after the Fe release, we observed a significant increase of dissolved Fe (ave. 2.89 nM). The fertilized patch was traced for 14 days by on-board SF₆ analysis. A Lagrangian frame of reference was maintained by the use of a drogued GPS buoy released at the center of the patch. The patch moved westward at a rate of 6.8 km d⁻¹. Mixed layer depth increased from 8.5 to 15 m during the experiment. Horizontal diffusivity was determined by the change of SF₆ concentration in the patch. The horizontal diffusivity increased during the experiment. We evaluate here the fate of Fe in a Fe-fertilized patch using the dilution rate determined from sulphur hexafluoride (SF₆) concentration. Dissolved Fe concentrations subsequently decreased rapidly to 0.15 nM on Day 13. However, the dissolved Fe half-life of 43 h was relatively longer than in previous Fe-enrichment studies, and we observed a larger increase of the centric diatom standing stock and corresponding drawdown of macro-nutrients and carbon dioxide than in the previous studies. The most important reason for the larger response was the phytoplankton species in the western North Pacific. In addition, the smaller diffusivity and shallower mixed layer were effective to sustain the higher dissolved Fe concentration compared to previous experiments. This might be one reason for the larger response of diatoms in SEEDS.     

Functional roles of interzonal migrating mesozooplankton in the western subarctic Pacific

Grazing experiments and production estimation based on life-history analysis of Neocalanus copepods (N. cristatus, N. plumchrus and N. flemingeri) were carried out in the Oyashio region to understand the carbon flows associated with the interzonal migrating copepods. These copepods, and also Eucalanus bungii, fed on nano- and micro-sized organisms non-selectively throughout the season. However, diatoms were the dominant food resource until May and organisms, such as ciliates were the major resource after May. Daily growth rate was estimated from the Ikeda–Motoda, Huntley–Lopez and Hirst–Sheader models. Since the growth rates were considered to be overestimates for the Huntley–Lopez model and underestimates for the other two models, we applied the weight-specific growth rates previously reported for these species in the Bering Shelf. Surface biomass of Neocalanus increased rapidly in June during the appearance of C5, and a successive increase of overwintering stock was evident in the deeper layer. The deep biomass decreased gradually from September to May during the dormant and reproduction period. N. cristatus has the largest annual mean biomass (2.3 gC m⁻²), followed by N. plumchrus (1.1) and N. flemingeri (0.4). Daily production rate of Neocalanus varied from 0.4 to 363.4 mgC m⁻² day⁻¹, to which N. cristatus was the largest contributor. Annual production was estimated as 11.5 gC m⁻² year⁻¹ for N. cristatus, 5.7 for N. plumchrus and 2.1 for N. flemingeri, yielding annual P/B ratio of 5 for each species. The annual production of Neocalanus accounted for 13.2% of the primary production in the Oyashio region. Their fecal pellets were estimated to account for 14.9% (0.7 gC m⁻² year⁻¹) of sinking flux of organic carbon at 1000-m depth. Moreover, their export flux by ontogenetic vertical migration, which is not measured by sediment trap observations, is estimated to be 91.5% (4.3 gC m⁻² year⁻¹) of carbon flux of sinking particles at 1000-m depth. These results suggest the important role of interzonal migrating copepods in the export flux of carbon.     

Contributions of individual countries?? emissions to climate change and their uncertainty

We have compiled historical greenhouse gas emissions and their uncertainties on country and sector level and assessed their contribution to cumulative emissions and to global average temperature increase in the past and for a the future emission scenario. We find that uncertainty in historical contribution estimates differs between countries due to different shares of greenhouse gases and time development of emissions. Although historical emissions in the distant past are very uncertain, their influence on countries?? or sectors?? contributions to temperature increase is relatively small in most cases, because these results are dominated by recent (high) emissions. For relative contributions to cumulative emissions and temperature rise, the uncertainty introduced by unknown historical emissions is larger than the uncertainty introduced by the use of different climate models. The choice of different parameters in the calculation of relative contributions is most relevant for countries that are different from the world average in greenhouse gas mix and timing of emissions. The choice of the indicator (cumulative GWP weighted emissions or temperature increase) is very important for a few countries (altering contributions up to a factor of 2) and could be considered small for most countries (in the order of 10%). The choice of the year, from which to start accounting for emissions (e.g. 1750 or 1990), is important for many countries, up to a factor of 2.2 and on average of around 1.3. Including or excluding land-use change and forestry or non-CO₂ gases changes relative contributions dramatically for a third of the countries (by a factor of 5 to a factor of 90). Industrialised countries started to increase CO₂ emissions from energy use much earlier. Developing countries?? emissions from land-use change and forestry as well as of CH₄ and N₂O were substantial before their emissions from energy use.     

Nitrogen concentration within Saxifraga oppositifolia in different successional stages on a glacier foreland in the high Arctic

We measured and compared the δ¹³C values and nitrogen concentrations within the photosynthetic parts (Np) of phototrophs growing in different successional stages and different soil conditions at Ny-Ålesund, Svalbard, Norway. At all study sites, the Np value of vascular plants ranged from 1.0 to 2.2%. The Np value for most moss species was less than 1.0%; values for lichens were about 0.5%. No significant correlation was detected between Np and δ¹³C; however, different plant species occupied distinct fields on a δ¹³C–Np plot, with minimal overlap between species. The Np value of Saxifraga oppositifolia, which grew at all of the study sites, ranged from 1.1 to 1.5%. Differences in growth form had no effect on Np. The Np and δ¹³C values obtained for S. oppositifolia were confined to within a narrow range regardless of site conditions.     

Increase in medium-size rainfall events will enhance the C-sequestration capacity of biological soil crusts

Biological soil crusts(BSCs) play important roles in the carbon(C) balance in arid regions. Net C balance of BSCs is strongly dependent on rainfall and consequent activation of microbes in the BSCs. The compensation-rainfall size for BSCs(the minimum rainfall amount for a positive net C balance) is assumed to be different with BSCs of different developmental stages. A field experiment with simulated rainfall amount(SRA) of 0, 1, 5, 10, 20, and 40 mm was conducted to examine the C fluxes and compensation-rainfall size of BSCs in different parts of fixed dunes in the ecotone between the Badain Jaran Desert and the Minqin Oasis. We found algae-lichen crust on the interdunes and crest, algae crust on the leeward side, and lichen-moss crust on the windward. Even a small rainfall(1 mm) can activate both photosynthesis and respiration of all types of BSCs. The gross ecosystem production, ecosystem respiration, and net ecosystem exchange were significantly affected by SRA, hours after the simulated rainfall, position on a dune, and their interactions. The rapid activation of photosynthesis provides a C source and therefore could be responsible for the increase of C efflux after each rewetting. C-uptake and-emission capacity of all the BSCs positively correlated with rainfall size, with the lowest C fluxes on the leeward side. The compensation rainfall for a net C uptake was 3.80, 15.54, 8.62, and 1.88 mm for BSCs on the interdunes, the leeward side, the crest, and the windward side, respectively. The whole dune started to show a net C uptake with an SRA of 5 mm and maximized with an SRA of about 30 mm. The compensation-rainfall size is negatively correlated with chlorophyll content. Our results suggest that BSCs will be favored in terms of C balance, and sand dune stabilization could be sustained with an increasing frequency of 5-10 mm rainfall events in the desert-oasis transitional zone.-     

Analyzing the runoff response to soil and water conservation measures in a tropical humid Ethiopian highland

Abstract

Different soil and water conservation (SWC) practices have been implemented in many drought-prone parts of Ethiopia since the 1980s. We assessed the effect of SWC practices on runoff response and experimentally derived and tested the validity of the runoff curve number (CN) model parameter for the tropical humid highland climate of the Kasiry watershed in northwestern Ethiopia. We recorded daily rainfall and runoff depth from 18 runoff plots (30 m long × 6 m wide) representing the five main land-use types with various SWC practices and two slope classes (gentle and steep). CN values were derived using the lognormal geometric mean CN procedure. Runoff was significantly less from plots with SWC measures, with average reductions of 44 and 65% observed in cultivated and non-agricultural lands, respectively. Runoff on plots representing non-agricultural land was relatively accurately predicted with the derived CN method, but predictions were less accurate for plots treated with a SWC practice. We conclude that predicting the effect of SWC practices on runoff requires parameterization with separate sets of CN value for each SWC practice.     

Quasigeostrophic planetary waves in a two-layer ocean with one-dimensional periodic bottom topography

Although the study of topographic effects on the Rossby waves in a stratified ocean has a long history, the wave property over a periodic bottom topography whose lateral scale is comparable to the wavelength is still not clear. The present paper treats this problem in a two-layer ocean with one-dimensional periodic bottom topography by a simple numerical method, in which no restriction on the wavelength and/or the horizontal scale of the topography is required. The dispersion diagram is obtained for a wavenumber range of [?π/L _b , π/L _b ], where L _b is the periodic length of the topography. When the topographic?β?is not negligible compared to the planetary β, the Rossby wave solutions around the wavenumbers which satisfy the resonant condition among the waves and topography disappear and separate into an infinite number of discrete modes. For convenience, each mode is numbered in order of frequency. As topographic height is increased, the high frequency barotropic Rossby wave (mode 1) becomes a topographic mode which can exist even on the f plane, and the highfrequency baroclinic mode (mode 2) becomes a surface intensified mode. Behaviors of low frequency modes are somewhat complicated. When the topographic amplitude is small, the low frequency baroclinic modes tend to be bottom trapped and the low frequency barotropic modes tend to be surface intensified. As topographic amplitude further increases, the relation between the mode number and vertical structure changes. This change can be attributed to the increase of the frequency of the topographic mode with the topographic amplitude.