From Cadomian arc to Ordovician passive margin: geochemical records preserved in metasedimentary successions of the Orlica-Śnieżnik Dome in SW Poland

The chemical composition of metamorphosed siliciclastic rocks in the Orlica-?nie?nik Dome (Bohemian Massif) identifies the main sources for the Neoproterozoic [the M?ynowiec Formation (MF)], Early Cambrian [the Stronie Formation (SF)] and Late Cambrian/Early Ordovician [the Goszów quartzites (GQ)] sediments. The MF developed from erosion of a Cadomian magmatic arc along the northern Gondwana margin. The variegated SF, with supra-subduction affinities, shows chemical characteristics pointing to erosion of the freshly exhumed Cadomian orogen and detritus deposition in the back-arc basin. The very different chemical features of the GQ indicate deposition in a basin sited on a passive continental margin. The explanation proposed for the observed changes in chemical composition involves three main stages: (1) The pre ~540 Ma evolution of an active continental margin and related back-arc basin ceased with the collision and accretion of the magmatic arc to the Gondwana margin; (2) Early Cambrian rift to drift transition (540–500 Ma) and development of a depositional basin filled with detritus derived from remnants of the magmatic arc; (3) Peri-Gondwana break-up leading to the formation of shallow-water passive margin depositional basins filled with quartz-rich detritus resembling Early Ordovician Armorican quartzites known from other parts of the Variscan Belt.     

Analysis of labile form of aluminum and heavy metals in bottom sediments from Kongsfjord, Isfjord, Hornsund fjords

The paper presents study results obtained for the bottom sediment samples of fjords Kongsfjord, Isfjord, Hornsund in the form of surface samples and their core profiles. The concentrations of labile form of aluminum and heavy metals were determined using the single-stage extraction with 3 mol L^?1 HCl. The obtained results allowed defining the occurrence of variability of labile aluminum form in the samples of bottom sediments of the studied fjords depending on the point and depth of sample collection. The conducted chemometric analysis allowed for the study of spatial variability of aluminum occurrence in the area of the investigated fjords. Based on the analysis, the correlations between aluminum and heavy metals were determined.     

Luminescence and other spectroscopic properties of purple and green Cr-clinochlore

For the first time ever, the luminescence spectra of Cr³⁺ centers in two chlorite crystals are presented. Chromium ions occupy the strong crystal-field site M4 in the brucite sheet and the intermediate crystal-field site in the inner octahedral sheet for purple and green chlorite, respectively. We discuss the influence of an effective positive charge on the Cr³⁺ ion and an effective negative charge of ligands on the differences in the values of the Dq and B parameters. It is concluded that the presence of Fe²⁺ ions and other point defects, as well as concentration quenching, causes the very short luminescence lifetimes of chromium ions.     

Periglacial and Fluvial Factors Controlling the Sedimentation of Pleistocene Breccia in NW Poland

Breccias were investigated on the terrace of the Toruń‐Eberswalde ice‐marginal valley at Rozwarzyn (NW Poland). Breccia layers include soft‐sediment clasts with diameters between 2 and 256 mm and soft‐sediment megaclasts with diameters from 256 mm to 7 m. The shape of the soft‐sediment clasts and megaclasts (derived from frozen sediments) in the breccia is diverse: from angular and irregular in the case of debris‐flow breccias to slightly rounded and tabular in fluvial breccias. These two types of breccias were developed during the Late Weichselian when the periglacial climate favored extensive lateral erosion by currents of frozen braided channels in the ice‐marginal valley. The dual presence of breccias of fluvial and debris‐flow origin in channel deposits is unique for Quaternary sediments. Zones of breccias existed in the channels where scours and obstacle marks related to megaclasts developed. The study of breccias shed new light on the fluvial processes in ice‐marginal valleys during the Pleistocene and can be considered as diagnostic for fluvio‐periglacial conditions.     

Zircon geochronology and geochemistry to constrain the youngest eruption events and magma evolution of the Mid-Miocene ignimbrite flare-up in the Pannonian Basin,eastern central Europe

A silicic ignimbrite flare-up episode occurred in the Pannonian Basin during the Miocene, coeval with the syn-extensional period in the region. It produced important correlation horizons in the regional stratigraphy; however, they lacked precise and accurate geochronology. Here, we used U–Pb (LA-ICP-MS and ID-TIMS) and (U–Th)/He dating of zircons to determine the eruption ages of the youngest stage of this volcanic activity and constrain the longevity of the magma storage in crustal reservoirs. Reliability of the U–Pb data is supported by (U–Th)/He zircon dating and magnetostratigraphic constraints. We distinguish four eruptive phases from 15.9 ± 0.3 to 14.1 ± 0.3 Ma, each of which possibly includes multiple eruptive events. Among these, at least two large volume eruptions (>10 km³) occurred at 14.8 ± 0.3 Ma (Demjén ignimbrite) and 14.1 ± 0.3 Ma (Harsány ignimbrite). The in situ U–Pb zircon dating shows wide age ranges (up to 700 kyr) in most of the crystal-poor pyroclastic units, containing few to no xenocrysts, which implies efficient recycling of antecrysts. We propose that long-lived silicic magma reservoirs, mostly kept as high-crystallinity mushes, have existed in the Pannonian Basin during the 16–14 Ma period. Small but significant differences in zircon, bulk rock and glass shard composition among units suggest the presence of spatially separated reservoirs, sometimes existing contemporaneously. Our results also better constrain the time frame of the main tectonic events that occurred in the Northern Pannonian Basin: We refined the upper temporal boundary (15 Ma) of the youngest counterclockwise block rotation and the beginning of a new deformation phase, which structurally characterized the onset of the youngest volcanic and sedimentary phase.     

Integral Turbulence Statistics Over a Central European City Centre

Atmospheric measurements over 5 years (2005–2010) at two sites in ?ód?, central Poland have been analyzed to develop a better understanding of turbulence in urban areas. Fast response wind velocity, temperature, humidity and CO₂ concentration were measured using sonic anemometers and gas analyzers, placed on narrow masts at 37 and 42 m above the ground. The measurements were used to calculate standard deviations of each parameter, and were then normalized according to local Monin–Obukhov similarity theory and plotted as a function of stability parameter ζ = z′/L. Results for the wind components show typical scaling with a power law with exponent ±1/3 in the free convection limit, and that approaches a constant value close to neutral stratification. For stable conditions, the constant value in the neutral limit remains the same for stability parameters lower than 0.1–0.2, then increases. The normalized standard deviation of temperature fits the ?1/3 law in the free convection limit, approaching a constant value within a stable limit. However, it exhibits hyperbolic characteristics for close to neutral stratification. The normalized standard deviations for humidity and CO₂ concentration exhibit scaling similar to the wind components in the unstable regime and remain constant in the stable domain. The results for the wind components and for temperature are in the range of various functions found in other studies. The absolute values for humidity and CO₂ concentration seem to be slightly higher, but only single examples of such investigations can be found in the literature.