Exploring seven hundred years of transhumance,climate dynamic,fire and human activity through a historical mountain pass in central Spain

A high-altitude peat sequence from the heart of the Spanish Central System (Gredos range) was analysed through a multi-proxy approach to determine the sensitivity of high-mountain habitats to climate, fire and land use changes during the last seven hundred years, providing valuable insight into our understanding of the vegetation history and environmental changes in a mountain pass close to a traditional route of transhumance. The pollen data indicate that the vegetation was dominated by shrublands and grasslands with scattered pines in high-mountain areas, while in the valleys cereals, chestnut and olive trees were cultivated. Strong declines of high-mountain pines percentages are recorded at 1540, 1675, 1765, 1835 and 1925 cal AD, which may be related to increasing grazing activities and/or the occurrence of anthropogenic fires. The practice of mountain summer farming and transhumance deeply changed and redesigned the landscape of the high altitudes in central Spain (Gredos range) since the Middle Ages, although its dynamics was influenced in some way by climate variability of the past seven centuries.     

Development and setting of the Alcudia Bay beach–dune system (Mallorca, Spain)

The beach–dune system of Alcudia Bay is located in the north of the island of Mallorca. The system includes both simple and compound parabolic dunes formed by N to NNE winds and is made up of two dune areas with different dynamics: 1) the northern area, where, despite the fact that the source of beach sediment is from the south, dunes are formed by northerly winds and develop a narrow and linear barrier which separates a marsh from the bay; and 2) the southern area, where complex parabolic dunes formed by north-northeasterly winds, prograde south-southwest landward extending several kilometers inland. The broad pattern of the dunefield size is limited to the southeast by a mountain range and to the west by the effects of a topographic corridor, oriented north–south, which channels the prevailing northerly wind, causing a southward dune progression and limiting the westward extension of the dunefield.     

The influence of upper-crust lithology on topographic development in the central Coast Ranges of California

A fundamental geological tenet is that as landscapes evolve over graded to geologic time, geologic structures control patterns of topographic distribution in mountainous areas such that terrain underlain by competent rock will be higher than terrain underlain by incompetent rock. This paper shows that in active orogens where markedly weak and markedly strong rocks are juxtaposed along contacts that parallel regional structures, relatively high topography can form where strain is localized in the weak rock. Such a relationship is illustrated by the topography of the central Coast Ranges between the Pacific coastline and the San Andreas fault zone (SAFZ), and along the length of the Gabilan Mesa (the “Gabilan Mesa segment” of the central Coast Ranges). Within the Gabilan Mesa segment, the granitic upper crust of the Salinian terrane is in contact with the accretionary-prism mélange upper crust of the Nacimiento terrane along the inactive Nacimiento fault zone. A prominent topographic lineament is present along most of this lithologic boundary, approximately 50 to 65 km southwest of the SAFZ, with the higher topography formed in the mélange on the southwest side of the Nacimiento fault.This paper investigates factors influencing the pattern of topographic development in the Gabilan Mesa segment of the central Coast Ranges by correlating shortening magnitude with the upper-crust compositions of the Salinian and Nacimiento terranes. The fluvial geomorphology of two valleys in the Gabilan Mesa, which is within the Salinian terrane, and alluvial geochronology based on optically-stimulated luminescence (OSL) age estimates, reveal that the magnitude of shortening accommodated by down-to-the-southwest tilting of the mesa since 400 ka is less than 1 to 2 m. Our results, combined with those of previous studies, indicate that at least 63% to 78% of late-Cenozoic, northeast-southwest directed, upper-crustal shortening across the Gabilan Mesa segment has been accommodated within the Nacimiento terrane. This is significant because perpendicular to orogenic strike the Nacimiento terrane constitutes less than ¼ of the distance between the coast and the SAFZ, and the other ¾ (or greater) of the distance between the coast and the SAFZ is underlain by the granitic upper crust of the Salinian terrane. We propose that strain and mountain building are localized within the Nacimiento terrane because it consists predominantly of the relatively weak Franciscan Complex mélange, and because the upper crust of the Salinian terrane is composed of relatively strong granitic rocks. Our hypothesis is supported by the distribution of post-seismic surface uplift associated with the 2003, 6.5 M_W San Simeon earthquake, which mimics the topography of the southwestern part of the Gabilan Mesa segment of the central Coast Ranges.     

A length-biased version of the Birnbaum-Saunders distribution with application in water quality

In this article, we develop a new model based on the Birnbaum-Saunders distribution that results to be both useful and practical for environmental sciences. The density, distribution and hazard functions, moments and properties of this new model are presented. A graphical analysis of the density is also provided. Furthermore, we estimate parameters, propose asymptotic inference and discuss influence diagnostics by using likelihood methods for the new distribution. An illustrative example with real data related to water quality indicates the adequacy on the new distribution.     

Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.     

High-pressure melting relations in Fe-C-S systems: Implications for formation, evolution, and structure of metallic cores in planetary bodies

We present new high-pressure temperature experiments on melting phase relations of Fe-C-S systems with applications to metallic core formation in planetary interiors. Experiments were performed on Fe-5 wt% C-5 wt% S and Fe-5 wt% C-15 wt% S at 2-6 GPa and 1050-2000 °C in MgO capsules and on Fe-13 wt% S, Fe-5 wt% S, and Fe-1.4 wt% S at 2 GPa and 1600 °C in graphite capsules. Our experiments show that: (a) At a given P-T, the solubility of carbon in iron-rich metallic melt decreases modestly with increasing sulfur content and at sufficiently high concentration, the interaction between carbon and sulfur can cause formation of two immiscible melts, one rich in Fe-carbide and the other rich in Fe-sulfide. (b) The mutual solubility of carbon and sulfur increases with increasing pressure and no super-liquidus immiscibility in Fe-rich compositions is likely expected at pressures greater than 5-6 GPa even for bulk compositions that are volatile-rich. (c) The liquidus temperature in the Fe-C-S ternary is significantly different compared to the binary liquidus in the Fe-C and Fe-S systems. At 6 GPa, the liquidus of Fe-5 wt% C-5 wt% S is 150-200 °C lower than the Fe-5 wt% S. (d) For Fe-C-S bulk compositions with modest concentration of carbon, the sole liquidus phase is iron carbide, Fe₃C at 2 GPa and Fe₇C₃ at 6 GPa and metallic iron crystallizes only with further cooling as sulfur is concentrated in the late crystallizing liquid. Our results suggest that for carbon and sulfur-rich core compositions, immiscibility induced core stratification can be expected for planets with core pressure less than ∼6 GPa. Thus planetary bodies in the outer solar system such as Ganymede, Europa, and Io with present day core-mantle boundary (CMB) pressures of ∼8, ∼5, and 7 GPa, respectively, if sufficiently volatile-rich, may either have a stratified core or may have experienced core stratification owing to liquid immiscibility at some stage of their accretion. A similar argument can be made for terrestrial planetary bodies such as Mercury and Earth’s Moon, but no such stratification is predicted for cores of terrestrial planets such as Earth, Venus, and Mars with the present day core pressure in the order ?136 GPa, ?100 GPa, and ?23 GPa. (e) Owing to different expected densities of Fe-rich (and carbon-bearing) and sulfur-rich metallic melts, their settling velocities are likely different; thus core formation in terrestrial planets may involve rain of more than one metallic melt through silicate magma ocean. (f) For small planetary bodies that have core pressures <6 GPa and have a molten core or outer core, settling of denser carbide-rich liquid or flotation of lighter, sulfide-rich melt may contribute to an early, short-lived geodynamo.     

Paleoflood events recorded by speleothems in caves

Speleothems are usually composed of thin layers of calcite (or aragonite). However, cemented detrital materials interlayered between laminae of speleothemic carbonate have been also observed in many caves. Flowstones comprising discontinuous carbonate layers form due to flowing water films, while flood events introduce fluviokarstic sediments in caves that, on occasion, are recorded as clayey layers inside flowstones and stalagmites. This record provides a potential means of understanding the frequency of palaeofloods using cave records. In this work, we investigate the origin of this type of detrital deposit in El Soplao Cave (Northern Spain). The age of the lowest aragonite layer of a flowstone reveals that the earliest flood period occurred before 500 ka, though most of the flowstone formed between 422 +69/‐43 ka and 400 +66/‐42 ka. This suggests that the cave was periodically affected by palaeoflood events that introduced detrital sediments from the surface as a result of occasional extreme rainfall events, especially at around 400 ka. The mineralogical data enable an evolutionary model for this flowstone to be generated based on the alternation of flood events with laminar flows and carbonate layers precipitation that can be extrapolated to other caves in which detrital sediments inside speleothems have been found. Copyright © 2014 John Wiley & Sons, Ltd.     

Decompression reactions and P–T conditions in high-pressure granulites from Casares-Los Reales units of the Betic-Rif belt (S Spain and N Morocco)

High-pressure granulites are exposed in the Casares-Los Reales group (internal zones of Betic-Rif belt, S Spain–N Morocco) as part of the crustal envelope of Beni Bousera-Ronda Peridotites. They are mostly metapelitic but include intercalations of mafic composition. The metamorphic history is marked by the preservation of early high-pressure assemblages together with secondary low-pressure assemblages suggesting a state of textural and compositional disequilibrium. The P–T path constrained by geothermobarometry and reaction textures from mafic and pelitic lithotypes passes from 800 °C/15 kbar to 600 °C/5 kbar, to indicating a strong decompression related to cooling, followed by a near-isobaric cooling 430 °C and 4 kbar. Such P–T evolution of granulites is thought to reflect some sort of rapid tectonic collapse of crust previously thickened through collision.