Electrodialytic remediation of CCA-treated waste wood in pilot scale

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

From economic integration to socioeconomic inclusion: day labor worker centers as social intermediaries

Day labor worker centers have emerged as an important mode of regulatory action in the informal economy of major US cities. Research suggests that these organizations are beneficial in improving employment outcomes experienced by migrant workers engaged in this labor market sector. Yet, the extent to which these organizations impact the social integration of this working population remains relatively undeveloped in the literature. Using data from the National Day Labor Survey, we examine the impact of day labor worker centers on the level of social inclusion experienced by migrant day laborers. We find that worker centers have a modest, but statistically significant, impact on the levels of social integration experienced by this working population and that this varies from city to city. Ultimately we argue that the social intermediary role of these organizations may offer a type of counter mobilization necessary to promote the socioeconomic integration of this working population, but that issues of capacity remain.     

On the optimal siting of cubic kilometre scale neutrino telescope infrastructure on the deep-sea floor

The aim of this paper is to propose an approach for optimal siting of the KM3NeT neutrino telescope on the sea floor. The method is based on Geographic Information System (GIS) spatial analyses and cost assessment. GIS techniques initially aim to derive depth and slope characteristics of the sea floor, and estimate the distance from shore. Subsequently, GIS methods are used to pre-select sites meeting the KM3NeT infrastructure criteria. Finally, the candidate locations are evaluated in terms of cost estimation. A convex combination of instantaneous cost functions (ICFs) is applied and different weighting factors are allowed to account for dissimilar importance of the considered variables. The ICFs are indexed by a parameter β to assign different cost characteristics to different variables. The overall assessment is based on the comparison of costs computed for the candidate sites assuming many configurations of weights and β values. Our exercise uses a simulated numerical bathymetry to avoid a site-specific evaluation at the initial stage of the KM3NeT project. Hence, no recommendations as to the real locations of the neutrino telescope in the Mediterranean Sea are addressed. Our approach is found to serve well in the process of comparing costs between different candidate sites.     

On the influence of DC railway noise on variation data from Belsk and Lviv geomagnetic observatories

Geomagnetic variation data from the observatories in Belsk (BEL, Poland) and Lviv (LVV, Ukraine) significantly suffer from disturbances caused by direct current (DC) electric railways. The aim of this study is to quantify the impact of these disturbances on quantities derived from such data, as the K index of magnetic activity and the induction arrow used in the geomagnetic deep sounding method to indicate lateral contrasts of electric conductivity in the solid earth. Therefore, undisturbed data have been reconstructed by means of a frequency-domain transfer function that relates the horizontal magnetic field components of the observatory to the ones synchronously recorded at a noise-free reference station. The comparison of the K index derived from original and reconstructed data shows an increase of quiet time segments by 29% for LVV and by 14% for BEL due to our noise removal procedure. Furthermore, the distribution of the corrected K indices agrees well with the one from the Niemegk observatory in Germany.     

Local ice caps in Finderup Land,North Greenland,survived the Holocene Thermal Maximum

Local glaciers and ice caps (GICs) comprise only ~5.4% of the total ice volume, but account for ~14–20% of the current ice loss in Greenland. The glacial history of GICs is not well constrained, however, and little is known about how they reacted to Holocene climate changes. Specifically, in North Greenland, there is limited knowledge about past GIC fluctuations and whether they survived the Holocene Thermal Maximum (HTM, ~8 to 5 ka). In this study, we use proglacial lake records to constrain the ice‐marginal fluctuations of three local ice caps in North Greenland including Flade Isblink, the largest ice cap in Greenland. Additionally, we have radiocarbon dated reworked marine molluscs in Little Ice Age (LIA) moraines adjacent to the Flade Isblink, which reveal when the ice cap was smaller than present. We found that outlet glaciers from Flade Isblink retreated inland of their present extent from ~9.4 to 0.2 cal. ka BP. The proglacial lake records, however, demonstrate that the lakes continued to receive glacial meltwater throughout the entire Holocene. This implies that GICs in Finderup Land survived the HTM. Our results are consistent with other observations from North Greenland but differ from locations in southern Greenland where all records show that the local ice caps at low and intermediate elevations disappeared completely during the HTM. We explain the north–south gradient in glacier response as a result of sensitivity to increased temperature and precipitation. While the increased temperatures during the HTM led to a complete melting of GICs in southern Greenland, GICs remained in North Greenland probably because the melting was counterbalanced by increased precipitation due to a reduction in Arctic sea‐ice extent and/or increased poleward moisture transport.