Multispectral thermal infrared mapping of the 1 October 1988 Kupaianaha flow field,Kilauea volcano,Hawaii

Multispectral thermal infrared radiance measurements of the Kupaianaha flow field were acquired with the NASA airborne Thermal Infrared Multispectral Scanner (TIMS) on the morning of 1 October 1988. The TIMS data were used to map both the temperature and emissivity of the surface of the flow field. The temperature map depicted the underground storage and transport of lava. The presence of molten lava in a tube or tumulus resulted in surface temperatures that were at least 10° C above ambient. The temperature map also clearly defined the boundaries of hydrothermal plumes which resulted from the entry of lava into the ocean. The emissivity map revealed the boundaries between individual flow units within the Kupaianaha field. In general, the emissivity of the flows varied systematically with age but the relationship between age and emissivity was not unique. Distinct spectral anomalies, indicative of silica-rich surface materials, were mapped near fumaroles and ocean entry sites. This apparent enrichment in silica may have resulted from an acid-induced leaching of cations from the surfaces of glassy flows. Such incipient alteration may have been the cause for virtually all of the emissivity variations observed on the flow field, the spectral anomalies representing areas where the acid attack was most intense.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.     

Organic geochemistry of silicified wood,Petrified Forest National Park,Arizona

Lignin derivatives have been isolated for the first time from carbonaceous sections of the silicified (~90% SiO₂) conifer Araucarioxylon arizonicum. The products released by sequential high vacuum pyrolysis and identified by combined gas chromatography-mass spectrometry (GC-MS) include a wide variety of alkyl-substituted, phenolic and condensed aromatic compounds.Brauns spruce lignin was pyrolized and analyzed by GC-MS as a comparison for the fossil wood data. The primary pyrolyzates at the 300°C step were CO₂, H₂O, ethanol and propanol. The main product at 450°C was 4-methyl-2-methoxyphenol (methyl guaiacol), but at 600°C the pyrolyzates were similar both in product composition and in relative abundance to those from silicified wood. The results suggest that the fossil wood experienced a mild thermal event during which the ether bonds were ruptured and loss of oxygen occurred along with the rearrangement of the original wood into a highly stable polymer.     

A review of the ocean science and technology partnership between US and Korea

In 2001, the National Oceanic and Atmospheric Administration (NOAA) and the Ministry of Maritime Affairs and Fisheries Integrated Coastal and Ocean Resources Scientific and Technical Arrangement was signed to pursue scientific and technical cooperation in integrated coastal and ocean resources management in the mutual interest of the participants. Over the last 6 years, the cooperation has been very beneficial, particularly for advancing marine science and management programs in Korea, such as Deep Sea Aquaculture, Sea Grant College Program, Marine Protected Areas, and Ocean Observations. The benefits to NOAA from the cooperation include Deep-ocean Assessment and Reporting of Tsunamis (DART) buoys, ocean and coastal observations, GEOSS program, and Global Program of Action. Also the cooperation has spillover effects on other ocean science and technological arrangement between US and Korea. This article reviews purpose, obstacles, and achievement of the cooperation and suggests recommendations for the future steps.     

On the optimal siting of cubic kilometre scale neutrino telescope infrastructure on the deep-sea floor

The aim of this paper is to propose an approach for optimal siting of the KM3NeT neutrino telescope on the sea floor. The method is based on Geographic Information System (GIS) spatial analyses and cost assessment. GIS techniques initially aim to derive depth and slope characteristics of the sea floor, and estimate the distance from shore. Subsequently, GIS methods are used to pre-select sites meeting the KM3NeT infrastructure criteria. Finally, the candidate locations are evaluated in terms of cost estimation. A convex combination of instantaneous cost functions (ICFs) is applied and different weighting factors are allowed to account for dissimilar importance of the considered variables. The ICFs are indexed by a parameter β to assign different cost characteristics to different variables. The overall assessment is based on the comparison of costs computed for the candidate sites assuming many configurations of weights and β values. Our exercise uses a simulated numerical bathymetry to avoid a site-specific evaluation at the initial stage of the KM3NeT project. Hence, no recommendations as to the real locations of the neutrino telescope in the Mediterranean Sea are addressed. Our approach is found to serve well in the process of comparing costs between different candidate sites.     

Seasonal fluctuations in the deep central equatorial Atlantic Ocean: a data–model comparison

Low-frequency current fluctuations in the deep central equatorial Atlantic are analyzed using current meter measurements recorded from November 1992 to November 1994. Current meters were located at about 14°W of longitude and 1° of latitude on both sides of the equator between 1,700 m depth and the ocean bottom. At all sampling depths, the velocity fluctuations are dominantly zonal and symmetrical with respect to the equator. At 1,700 and 2,000 m, the flow is dominated by annual period fluctuations, at 3,000 m, the velocity field amplitude presents a minimum, and at 3,750 and 3,950 m, the flow is modulated by annual and semiannual period variability. The annual signal exhibits an apparent upward phase propagation. When considering the phase and the amplitude of the seasonal fluctuations, the data compare well with the outputs of a realistic numerical simulation of the Atlantic Ocean. Together with a previous analysis of the model simulations, this supports the idea that the observed annual fluctuations are due to wind-forced vertically propagating Kelvin and Rossby waves. Data and model do not provide deciding evidences of the presence of semiannual equatorial waves deeper than 3,500 m depth in the central equatorial Atlantic Ocean.     

Dating of marine aragonite by electron spin resonance

Marine aragonite, in the form of corals and/or shells, provides useful markers of geological and archaeological events. It is, therefore, important to have simple and accurate methods of dating these materials. Electron spin resonance (ESR) has previously been shown to be a reliable method for establishing the age of aragonitic coral samples in the time period approximately 100 ka B.P. The primary purpose of the present work is to discuss the problems encountered in extending this method to considerably older samples, up to 600 ka BP in age. In this time period there are questions about the stability of the ESR signal. The samples investigated are aragonitic corals from reef terraces of Barbados, West Indies, all of which have previously been dated by the methods, and by U-series disequilibrium, for samples below the limit of this method. There is generally good agreement for samples up to about 300 ka in age; older samples, even unrecrystallized, appear younger when dated by ESR than by . The source of this discrepancy is not clear. The explanation of thermal fading is not adequate. However, it appears likely that in most cases ESR will be able to be used to date materials up to this age. Further investigation is needed to determine tests that will distinguish datable samples from non-datable ones.