Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO2 uptake at regional and global scales

The goal of this study was to highlight the occurrence of an additional proton-promoted weathering pathway of carbonate rocks in agricultural areas where N-fertilizers are extensively spread, and to estimate its consequences on riverine alkalinity and uptake of CO₂ by weathering. We surveyed 25 small streams in the calcareous molassic Gascogne area located in the Garonne river basin (south-western France) that drain cultivated or forested catchments for their major element compositions during different hydrologic periods. Among these catchments, the Hay and the Montoussé, two experimental catchments, were monitored on a weekly basis. Studies in the literature from other small carbonate catchments in Europe were dissected in the same way. In areas of intensive agriculture, the molar ratio (Ca + Mg)/HCO₃ in surface waters is significantly higher (0.7 on average) than in areas of low anthropogenic pressure (0.5). This corresponds to a decrease in riverine alkalinity, which can reach 80% during storm events. This relative loss of alkalinity correlates well with the content in surface waters. In cultivated areas, the contribution of atmospheric/soil CO₂ to the total riverine alkalinity (CO_{2 ATM-SOIL}/HCO₃) is less than 50% (expected value for carbonate basins), and it decreases when the nitrate concentration increases. This loss of alkalinity can be attributed to the substitution of carbonic acid (natural weathering pathway) by protons produced by nitrification of N-fertilizers (anthropogenic weathering pathway) occurring in soils during carbonate dissolution. As a consequence of these processes, the alkalinity over the last 30 years shows a decreasing trend in the Save river (one of the main Garonne river tributaries, draining an agricultural catchment), while the nitrate and calcium plus magnesium contents are increasing.We estimated that the contribution of atmospheric/soil CO₂ to riverine alkalinity decreased by about 7-17% on average for all the studied catchments. Using these values, the deficit of CO₂ uptake can be estimated as up to 0.22-0.53 and 12-29 Tg¹ yr⁻¹ CO₂ on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO₂ flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO₂ for the atmosphere. This anthropogenic CO₂ source is not negligible since it could reach 6-15% of CO₂ uptake by natural silicate weathering and could consequently partly counterbalance this natural CO₂ sink.     

From economic integration to socioeconomic inclusion: day labor worker centers as social intermediaries

Day labor worker centers have emerged as an important mode of regulatory action in the informal economy of major US cities. Research suggests that these organizations are beneficial in improving employment outcomes experienced by migrant workers engaged in this labor market sector. Yet, the extent to which these organizations impact the social integration of this working population remains relatively undeveloped in the literature. Using data from the National Day Labor Survey, we examine the impact of day labor worker centers on the level of social inclusion experienced by migrant day laborers. We find that worker centers have a modest, but statistically significant, impact on the levels of social integration experienced by this working population and that this varies from city to city. Ultimately we argue that the social intermediary role of these organizations may offer a type of counter mobilization necessary to promote the socioeconomic integration of this working population, but that issues of capacity remain.     

Phytoplankton dynamics and cyanobacterial dominance in Murchison Bay of Lake Victoria (Uganda) in relation to environmental conditions

Murchison Bay is a shallow embayment in the north-western part of Lake Victoria, strongly influenced by urban pollution from the Ugandan capital Kampala. Two stations, representing the semi-enclosed innermost part of the bay and the wider outer part of the bay, were sampled in the period from April 2003 to March 2004, in order to assess the phytoplankton community and the nutrient status in the bay. Murchison Bay was highly eutrophic with average concentrations (n=25) of total phosphorous >90 μg L⁻¹ and total nitrogen >1100 μg L⁻¹ in the inner part of the bay. The phytoplankton community was dominated by a variety of cyanobacterial species and diatoms. Cyanobacteria were dominant in the whole bay, whereas diatoms were more abundant in the outer part of the bay. Moreover, the proportion of N-fixing species like Anabaena sp. was higher in the outer part of the bay, whereas species like Microcystis sp. were more abundant in the inner part of the bay. The phytoplankton community, especially in the outer part of the bay, may be influenced by light limitation. Low NO₃-N concentrations in the bay may also indicate a possible N-limitation, thus favouring growth of N-fixing cyanobacteria. The open bay is, however, a complex system, and additional environmental factors and loss processes most likely affect the phytoplankton community.     

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.     

Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.     

High‐precision U–Pb age and duration of the latest Devonian (Famennian) Hangenberg event,and its implications

Precise U–Pb zircon dates from three volcanic ash beds that bracket the Hangenberg Shale in the Holy Cross Mountains, Poland, constrain the age and duration of one of the most significant palaeobiological events of the Palaeozoic Era, the Hangenberg Event. It is linked to a terminal Devonian global shift from greenhouse to icehouse climate conditions, a global transgression, and widespread black shale deposition. Our results constrain the Hangenberg Event to between 358.97 ± 0.11 Ma and 358.89 ± 0.20 Ma, with a calculated duration of 0.05 +0.14/?0.05 Ma. A third, underlying ash bed yielded a distinctly older age of 359.97 ± 0.46 Ma. The duration of ~50–100 ka. for the event is comparable to those of Quaternary glaciations, and is consistent with both a glacio‐eustatic origin for the eustatic fluctuations and changes in ocean chemistry that led to this major reorganization of the biosphere.     

Importance of geological information for assessing drain flow in a Danish till landscape

There has, in recent years, been an increasing interest in developing nutrient load mitigation measures focussing on tile drains. To plan the location of such tile drain measures, it is important to know where in the landscape drain flow is generated and to understand the key factors governing drain flow dynamics. In the present study, we test two approaches to assess spatial patterns in drain flow generation and thereby assess the importance of including geological information. The approaches are the widely used topographical wetness index (TWI), based solely on elevation data, and hydrological models that include the subsurface geology. We set‐up an ensemble of 20 hydrological models based on 20 stochastically generated geological models to predict drain flow dynamics in the clay till Norsminde catchment in Denmark and test the results against TWI. We find that the hydrological models predict observed daily drain flow reasonably well. High drain flow volumes were found in stream valleys and in wetlands and lower drain flow volumes in the more hilly parts of the catchment. In spite of the apparent connection to the landscape, there was no statistically significant correlation between TWI and drain flow at grid scale (100 × 100 m). TWI was therefore not found to be a sufficient index on its own to assess where drain flow is generated, especially in the highlands of the catchment. The geology below 3 m was found to have a large impact on the drain flow, and correlations between sand percentage in the subsurface geology and drain flow volume were found to be statistically significant. Geological uncertainty therefore give rise to uncertainty on simulated drain flow, and this uncertainty was found to be high at the model grid scale but decreasing with increasing scale.     

The Greenland ice sheet through the last glacial-interglacial cycle

The evolution of the Greenland ice sheet during the last 150,000 years, in response to a climate history derived from a Greenland ice-margin oxygen-18 record, is simulated by means of a three-dimensional, time-dependent ice-sheet model. The calculations indicate that the ice sheet displayed considerable thinning and ice-margin retreat during the last interglacial (the Eemian) and during a warm interstadial c. 100,000 yr B.P., resulting in a splitting up of the ice sheet into a central-northern and a southern part. However, the ice sheet in Central Greenland survived the warm stages with almost unchanged surface elevations as compared with the present.     

A new,valid measure of climate change understanding: associations with risk perception

The relationship between climate change understanding and other variables, including risk perception, beliefs, and worldviews, is an important consideration as we work to increase public attention to climate change. Despite significant effort to develop rigorous mechanisms for measuring affective variables, measurement of climate change understanding is often relegated to unvalidated questions or question sets. To remedy this situation, we constructed and analyzed a climate change concept inventory using a suite of validity and reliability steps, including Rasch analysis. The resultant 21-item test has a high degree of validity and reliability for measuring understanding about basic climate change processes. Inventory scores along with other variables were included in a model of climate change risk perception, providing both concurrent validity for the test and new insight into the importance of understanding, worldview, and values on risk perception. We find that environmental beliefs and cultural cognition worldview play a larger role in predicting an individual’s risk perception than knowledge. Implications for addressing climate change are considered.