Biochronology and biochron boundaries: A real dilemma or a false problem? An example based on the Pleistocene large mammalian faunas from Italy

Reconstructing the Neogene-Quaternary biostratigraphy in continental environments and recognising ‘boundaries’ between successive mammalian faunal complexes is a problematic task. The definition and application of biochronology has been often tainted by references to and inferences from biostratigraphy. Actually, the discontinuities in the continental sedimentary record, environmental conditions, taphonomic and sampling biases are responsible for the fact that the stratigraphical order of the lowest and highest occurrences of fossil remains (stratigraphic datum) does not necessarily reflect the temporal order of actual first/last appearances of taxa (palaeobiological events) in time. Nonetheless, the first/last appearance bioevents (recorded by lowest/highest occurrences of fossil remains in fossiliferous levels of different continental stratigraphical successions) have been the principal foundation for establishing the biochronological setting of continental mammal faunas. Therefore, from a theoretical point of view, ‘boundaries’ should be defined by the oldest and/or youngest ‘historical occurrence’ of one or more taxa. What about an operational approach?Some examples of the Italian faunas are presented, focusing on the transition from the Villafranchian to the Galerian and from the Galerian to the Aurelian Land-Mammal Ages. The results obtained indicate the difficulty of defining a stable scheme that can be applied for correlation by the international scientific community.     

Molecular analysis of petroleum derived compounds that adsorb onto gas hydrate surfaces

Field observations have shown that some streams of water, gas and crude oil do not form gas hydrate plugs during petroleum production even when operating within thermodynamic conditions for hydrate formation. Also, when studied under controlled laboratory conditions, some oils are found to form hydrate dispersed systems whereas others form plugs. Oils with low tendency to form hydrate plugs are believed to contain natural hydrate plug inhibiting components (NICs) that adsorb onto the hydrate surface, making them less water-wet and preventing the particles from agglomerating into large hydrate clusters. The molecular structure of the NICs is currently unknown. In this work, hydrate adsorbing components were extracted from crude oils using freon hydrates as an extraction phase. The fractions were found to be enriched in polar material, and more polar material is associated with hydrates generated in biodegraded crude oils than in non-biodegraded oils. Various fractionation schemes and analytical techniques have been applied in the search for molecular characterisation. The average molecular weights were found to be approximately 500 g/mole. GC–MS chromatograms show a large UCM (Unresolved Complex Mixture). Thus, GC–MS has a limited potential for identification of compounds. A commercial biosurfactant was used as a model compound in the search for similar structures in the extracts. The results from analysis of the hydrate adsorbing components suggest that the type and structure are more important for hydrate morphology than the amount of material adsorbed.     

Food Web Structure and Habitat Connectivity in Fish Estuarine Nurseries—Impact of River Flow

River flow variability is known to influence estuarine production, yet knowledge on its effect upon estuarine food webs dynamics is still scarce. Stable carbon and nitrogen isotopes were used to assess the effect of river flow in the connectivity and food web interactions between the two main fish nursery areas of the Tagus estuary. The aims of the present work were to investigate the seasonal variation in food web structure and the exchange rate of individuals of marine juvenile fish among estuarine nurseries, to compare the spring of a rainy year (2001) with that of an average year (2000), and to investigate the impact of the winter floods of 2001. A low level of connectivity was observed for the fish species that use these areas as nurseries. In low river flow conditions, two isotopically distinct food webs were established in each nursery area. These food webs were very sensitive to small variations in the freshwater input. Winter floods seem to disrupt the localized food webs that are established in low river flow periods, leading to the re-establishment of a wider food web. While in rainy years this wide food web is maintained until spring, in average years the food web undergoes fragmentation into two localized and isotopically distinctive food webs. The increase in frequency of droughts due to climate change should lower the connectivity of the estuarine fish nurseries food webs, causing habitat fragmentation and consequent loss in complexity and resilience.     

On the Centre Manifold of Collinear Points in the Planar Three-Body Problem

We study the existence of invariant tori in a neighbourhood of the collinear equilibrium points of the planar three-body problem. To this end some properties of the normal form of the Hamiltonian reduced to the 4D central manifold are proved. Using this normal form, we show that the nondegeneracy conditions of KAM theorem are satisfied for all positive masses, including the 2:1 resonance case. The evaluation of the conditions is done numerically.     

Coronal rotation dependence on the solar cycle phase

A study of the green corona rotation rate, during the period 1970–1974, confirms that the differential rotation degree varies systematically through a solar cycle and that the corona rotates in an almost rigid manner before sunspot minimum. During the first two years, 1970–1971, the differential rotation degree, characteristic of high solar activity periods is detected. While during the years of declining activity, 1972–1974, a drastic decrease of the differential rotation degree occurs and the green corona rotates almost rigidly, as the coronal holes observed in the same period. These conclusions are valid only for the rotation of coronal features with lifetime of at least one solar rotation.     

Estimation of net accumulation rate at a Patagonian glacier by ice core analyses using snow algae

Snow algae in a 45.97-m-long ice core from the Tyndall Glacier (50°59′05″S, 73°31′12″W, 1756 m a.s.l.) in the Southern Patagonian Icefield were examined for potential use in ice core dating and estimation of the net accumulation rate. The core was subjected to visual stratigraphic observation and bulk density measurements in the field, and later to analyses of snow algal biomass, water isotopes (¹⁸O, D), and major dissolved ions. The ice core contained many algal cells that belonged to two species of snow algae growing in the snow near the surface: Chloromonas sp. and an unknown green algal species. Algal biomass and major dissolved ions (Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻) exhibited rapid decreases in the upper 3 m, probably owing to melt water elution and/or decomposition of algal cells. However, seasonal cycles were still found for the snow algal biomass, ¹⁸O, D-excess, and major ions, although the amplitudes of the cycles decreased with depth. Supposing that the layers with almost no snow algae were the winter layers without the melt water essential to algal growth, we estimated that the net accumulation rate at this location was 12.9 m a^− 1 from winter 1998 to winter 1999, and 5.1 m from the beginning of winter to December 1999. These estimates are similar to the values estimated from the peaks of ¹⁸O (17.8 m a^− 1 from summer 1998 to summer 1999 and 11.0 m from summer to December 1999) and those of D-excess (14.7 m a^− 1 from fall 1998 to fall 1999 and 8.6 m a^− 1 from fall to December 1999). These values are much higher than those obtained by past ice core studies in Patagonia, but are of the same order of magnitude as those predicted from various observations at ablation areas of Patagonian glaciers.     

Synthetic secular theories of the planetary orbits: Regular and chaotic behavior

Modern computer technology allows dynamical astronomers to investigate the long term stability of real systems as thoroughly as ever. However, the process is not straightforward and new problems need to be solved. This work deals with only one such problem: the construction-from the numerical integration- of a secular perturbation theory that is able to describe the dynamical behavior of the system. The discussion refers to the outer planets and is based on the knowledge acquired by the author during her participation in project LONGSTOP. A digital filter is used in order to reduce the output and eliminate short periodic terms. Filtering uncovers long term variations in the semimajor axes. From the filtered output a secular perturbation theory is constructed in the assumption that the solution is regular, as secular perturbation theories can only be constructed for regular solutions. If we succeed, this means that the solution is indeed regular for the computed span of time; if not-and this can be established in a rigorous way-it has to be concluded a posteriori that the solution is not regular. The LONGSTOP 1A and 1B integrations show well that as the timespan of the integration increases it is possible to detect the non-regular behavior of the solution. This happens in the eccentricity of Saturn at the 10^–4 level.     

Solar Microflares Observed by SphinX and RHESSI

In 2009, the Russian Complex Orbital Observations Near-Earth of Activity of the Sun (CORONAS-Photon) spacecraft was launched, carrying the Polish Solar PHotometer In X-rays (SphinX). The SphinX was most sensitive in the spectral range 1.2?–?15 keV, thus an excellent opportunity appeared for comparison with the low-energy end of Ramaty High Energy Solar Spectroscopic Imager (RHESSI) spectra. Common spectral measurements with these instruments cover the range where most of the flare energy is accumulated. We have chosen four consecutive small solar events observed on 4 July 2009 at 13:43 UT, 13:48 UT, 13:52 UT, and 13:55 UT (RHESSI flare peak times) and used them to compare the data and results from the two instruments. Moreover, we included Geostationary Operational Environmental Satellite (GOES) records in our analysis. In practice, the range of comparison performed for SphinX and RHESSI is limited roughly to 3?–?6 keV. RHESSI fluxes measured with a use of one, four, and nine detectors in the 3?–?4 keV energy band agree with SphinX measurements. However, we observed that SphinX spectral irradiances are three times higher than those of RHESSI in the 4?–?6 keV energy band. This effect contributes to the difference in obtained emission measures, but the derived temperatures of plasma components are similar. RHESSI spectra were fitted using a model with two thermal components. We have found that the RHESSI hot component is in agreement with GOES, and the RHESSI hotter component fits the SphinX flaring component well. Moreover, we calculated the so-called thermodynamic measure and the total thermal energy content in the four microflares that we studied. The results obtained show that SphinX is a very sensitive complementary observatory for RHESSI and GOES.     

Lensing, reddening and extinction effects of Mg ii absorbers from z= 0.4 to 2

Using a sample of almost 7000 strong Mg  ii absorbers with   W ₀ > 1 Å  and  0.4 < z < 2.2  detected in the SDSS DR4 data set, we investigate the gravitational lensing and dust extinction effects they induce on background quasars. After carefully quantifying several selection biases, we isolate the reddening effects as a function of redshift and absorber rest equivalent width, W ₀. We find the amount of dust to increase with cosmic time as  τ( z ) ∝ (1 + z )^−1.1±0.4  , following the evolution of cosmic star density or integrated star formation rate. We measure the reddening effects over a factor of 30 in E ( B − V ) and we find that  τ∝ ( W ₀)^1.9±0.1  , providing us with an important scaling for theoretical modelling of metal absorbers. We also measure the dust-to-metal ratio and find it similar to that of the Milky Way. In contrast to previous studies, we do not detect any gravitational magnification by Mg  ii systems. We measure the upper limit  μ < 1.10  and discuss the origin of the discrepancy. Finally, we estimate the fraction of absorbers missed due to extinction effects and show that it rises from 1 to 50 per cent in the range  1 < W ₀ < 6 Å  . We parametrize this effect and provide a correction for recovering the intrinsic  ∂ N /∂ W ₀  distribution.