MgSO4 ION association in seawater

Examination of the consequences of the stoichiometric association constant $\text{K}{}^1{}_{\mathrm{<mtext>a</mtext>}}\text{= 41.7}$ for MgSO₄ in seawater as advocated by Johnson and Pytkowicz (1979) leads to a thermodynamic association constant K_a = 212.6, a value 32% greater than K_A = 160 derived from conductance data. Use of K_a = 160 leads to a $\text{K}{}^1{}_{\mathrm{<mtext>a</mtext>}}$ in essential agreement with the value of 10.2 reported by Kester and Pytkowicz (1969).     

STRUCTURAL ADJUSTMENTS IN THE SOUTHERN MANUFACTURING SECTOR

The diversity of manufacturing in the United States South has shown a substantial increase during the post-World War II period. The basis for this changing industrial structure is found in the expansion of food processing and apparel industries but particularly since 1967 in a variety of higher-pay and higher-technology industries. The traditional textile states remain the least diversified and the slowest to change.     

Hα coronagraph observations of a flare spray,March 1, 1969

An H solar prominence with the characteristics of a spray was ejected in association with a bright limb flare. Knots of material were observed to a distance of more than one solar radius above the west limb of the Sun. The optical event was followed by 80 MHz emission from a type IV source which was observed moving out through several solar radii.Coronagraph observations have been used to determine the trajectories and velocities of the knots in directions perpendicular to the line of sight. After some early deceleration velocities increase to 300–500 km/sec and slowly decline with variations depending on the initial direction of outflow. We suggest that the magnetic field over the spot group is deformed by the energy of the mass motions of material fragments, some of which then continue to move outward from the Sun.     

Monochromatic observations of a coronal loop

An isophotal map of a small coronal loop, obtained from a coronagraph observation through a solid Fabry-Perot interferometer, is used to estimate the variation of emission per unit volume and the pressure gradient at the top and sides of the loop. The magnitude of the magnetic field necessary to maintain the estimated pressure gradients is found to be ¦H ²¦ = 30 G².     

First observations of the Na exosphere of Mercury with the high-resolution spectrograph of the 3.5M Telescopio Nazionale Galileo

Analysis of three spectra of the exosphere of Mercury in the Na-D lines are presented. Spectra were secured with the high-resolution spectrograph (SARG) of the 3.5 M Telescopio Nazionale Galileo (TNG, located on the Roque de los Muchachos, Canaries) on the evenings of August 23 and 24, 2002. Spectra have resolution ; the slit length was 26.7”. The Na column abundances range from 4.3 to with the highest abundances being close to the illuminated limb. Our observations at true anomaly angles (TAA) from 171°to 174°show the traces of the emission lines to be strongly peaked at the illuminated limb, supportive of recent modeling that shows thermal desorption to be a strong factor in determining the distribution of Na about the planet.     

A late Lake Minong transgression in the Lake Superior basin as documented by sediments from Fenton Lake, Ontario

The evolution of the early Great Lakes was driven by changing ice sheet geometry, meltwater influx, variable climate, and isostatic rebound. Unfortunately none of these factors are fully understood. Sediment cores from Fenton Lake and other sites in the Lake Superior basin have been used to document constantly falling water levels in glacial Lake Minong between 9,000 and 10,600 cal (8.1–9.5 ka) BP. Over three meters of previously unrecovered sediment from Fenton Lake detail a more complex lake level history than formerly realized, and consists of an early regression, transgression, and final regression. The initial regression is documented by a transition from gray, clayey silt to black sapropelic silt. The transgression is recorded by an abrupt return to gray sand and silt, and dates between 9,000 and 9,500 cal (8.1–8.6 ka) BP. The transgression could be the result of increased discharge from Lake Agassiz overflow or the Laurentide Ice Sheet, and hydraulic damming at the Lake Minong outlet. Alternatively ice advance in northern Ontario may have blocked an unrecognized low level northern outlet to glacial Lake Ojibway, which switched Lake Minong overflow back to the Lake Huron basin and raised lake levels. Multiple sites in the Lake Huron and Michigan basins suggest increased meltwater discharges occurred around the time of the transgression in Lake Minong, suggesting a possible linkage. The final regression in Fenton Lake is documented by a return to black sapropelic silt, which coincides with varve cessation in the Superior basin when Lake Agassiz overflow and glacial meltwater was diverted to glacial Lake Ojibway in northern Ontario.     

North polar frontal clouds and dust storms on Mars during spring and summer

The complete archive of Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) Mars Daily Global Maps (MDGM) are used to study north polar clouds and dust storms that exhibit frontal structures during the spring and summer (L_s 0-180°). Results show that frontal events generally follow the edge of the polar cap during spring and mid/late summer with a gap in the distribution in early summer. The exact duration and timing of the gap vary from year to year. Ten to twenty percent of spring and summer time frontal events exhibit complex morphologies. Distinct temperature signatures are associated with features observed in images in many but not all cases. The general travel paths of the frontal events are eastward around the polar cap. Westward paths exist only at the edge of the polar cap in late spring/early summer. Occasionally, the paths curve toward or away from the polar cap in certain longitude sectors.     

Can We Determine Electric Fields and Poynting Fluxes from Vector Magnetograms and Doppler Measurements?

The availability of vector-magnetogram sequences with sufficient accuracy and cadence to estimate the temporal derivative of the magnetic field allows us to use Faraday’s law to find an approximate solution for the electric field in the photosphere, using a Poloidal–Toroidal Decomposition (PTD) of the magnetic field and its partial time derivative. Without additional information, however, the electric field found from this technique is under-determined – Faraday’s law provides no information about the electric field that can be derived from the gradient of a scalar potential. Here, we show how additional information in the form of line-of-sight Doppler-flow measurements, and motions transverse to the line-of-sight determined with ad-hoc methods such as local correlation tracking, can be combined with the PTD solutions to provide much more accurate solutions for the solar electric field, and therefore the Poynting flux of electromagnetic energy in the solar photosphere. Reliable, accurate maps of the Poynting flux are essential for quantitative studies of the buildup of magnetic energy before flares and coronal mass ejections.     

Spatial and temporal dynamics of nitrogen exchange in an upwelling reach of a groundwater-fed river and potential response to perturbations changing rainfall patterns under UK climate change scenarios

We report the complex spatial and temporal dynamics of hyporheic exchange flows (HEFs) and nitrogen exchange in an upwelling reach of a 200 m groundwater-fed river. We show how research combining hydrological measurement, geophysics and isotopes, together with nutrient speciation techniques provides insight on nitrogen pathways and transformations that could not have been captured otherwise, including a zone of vertical preferential discharge of nitrate from deeper groundwater, and a zone of rapid denitrification linking the floodplain with the riverbed. Nitrate attenuation in the reach is dominated by denitrification but is spatially highly variable. This variability is driven by groundwater flow pathways and landscape setting, which influences hyporheic flow, residence time and nitrate removal. We observed the spatial connectivity of the river to the riparian zone is important because zones of horizontal preferential discharge supply organic matter from the floodplain and create anoxic riverbed conditions with overlapping zones of nitrification potential and denitrification activity that peaked 10–20 cm below the riverbed. Our data also show that temporal variability in water pathways in the reach is driven by changes in stage of the order of tens of centimetres and by strength of water flux, which may influence the depth of delivery of dissolved organic carbon. The temporal variability is sensitive to changes to river flows under UK climate projections that anticipate a 14%–15% increase in regional median winter rainfall and a 14%–19% reduction in summer rainfall. Superimposed on seasonal projections is more intensive storm activity that will likely lead to a more dynamic and inherently complex (hydrologically and biogeochemically) hyporheic zone. We recorded direct evidence of suppression of upwelling groundwater (flow reversal) during rainfall events. Such flow reversal may fuel riverbed sediments whereby delivery of organic carbon to depth, and higher denitrification rates in HEFs might act in concert to make nitrate removal in the riverbed more efficient.     

Using micro-catchment experiments for multi-local scale modelling of nature-based solutions

The Q-natural flood management project has co-developed with the Environment Agency 18 monitored micro-catchments (~1 km²) in Cumbria, UK installing calibrated flumes aimed at quantifying the potential shift in observed flows resulting from a range of nature-based-solutions installed by local organizations. The small-scale reduces the influence of variability characterizing larger catchments that would otherwise mask any such shifts, which we attempt to relate to a shift in model parameters. This paper demonstrates an approach to applying donor-parameter-shifts obtained from modelling two of the paired micro-catchments to a much larger scale, in order to understand the potential for improved distributed modelling of nature-based solutions in the form of additional tree-planting. The models include a rainfall-runoff model, Dynamic Topmodel, and a 2D hydrodynamic model, JFlow, permitting analysis of changes in hillslope processes and channel hydrodynamics resulting from a range of distributed measures designed to emulate natural hydrological processes that evaporate, store or infiltrate flows. We report on attempts to detect shift in hydrological response using one of the paired-micro-catchment moorland versus forestry sites in Lorton using Dynamic Topmodel. A donor-parameter-shift approach is used in a hypothetical experiment to represent new woodland in a much larger catchment, although testing all combinations of spatial planting strategies, responses to multiple-extremes, failure-modes and changes to synchronization becomes intractable to support good decision making. We argue that the problem can be re-framed to use donor-parameter-shifts at multi-local-scale catchments above communities known to be at risk, commensurate with most of the evidence of NbS impacts being effective at the small scale (ca. 10 km²). This might lead to more effective modelling to help catchment managers prioritize those communities-at-risk where there is more evidence that NbS might be effective.