Effects of air pollution on precipitation in Kraków (Cracow), Poland in the years 1971–2005

Daily precipitation data from the period 1971–2005 from four stations in and around Kraków (Cracow), Poland (one urban and three rural ones) were analysed in order to find out whether the 80% decrease in air pollution after 1989 had an impact on the atmospheric precipitation amount and spatial distribution. The analyses were performed for the whole 35-year series and in two 17-year sub-periods: 1972–1988 (high air pollution) and 1989–2005 (low air pollution). No decreasing or increasing trend in the precipitation totals at the particular stations studied in the period 1971–2005 has been observed. The precipitation totals from 1972–1988 differ significantly from the ones of 1989–2005 only in case of Igo?omia (one of the rural stations) in winter and at the urban station in autumn. The spatial pattern of precipitation did not change after 1989. The changes in air pollution affected the spatial pattern of days with precipitation mainly in spring and autumn for daily totals above 5 mm.     

Leaching of viruses and other microorganisms naturally occurring in pig slurry to tile drains on a well-structured loamy field in Denmark

The amount of animal manure used in modern agriculture is increasing due to the increase in global animal production. Pig slurry is known to contain zoonotic bacteria such as E. coli, Salmonella spp. and Campylobacter spp., and viruses such as hepatitis E virus and group A rotavirus. Coliform bacteria, present in manure, have previously been shown to leach into tile drains. This poses a potential threat to aquatic environments and may also influence the quality of drinking water. As knowledge is especially scarce about the fate of viruses when applied to fields in natural settings, this project sets out to investigate the leaching potential of six different microorganisms: E. coli and Enterococcus spp. (detected by colony assay), somatic coliphages (using plaque assays), and hepatitis E virus, porcine circovirus type 2, and group A rotavirus (by real-time polymerase chain reaction). All six microorganisms leached through the soil entering the tile drains situated at 1-m depth the first day following pig slurry application. The leaching pattern of group A rotavirus differed substantially from the pattern for somatic coliphages, which are otherwise used as indicators for virus contamination. Furthermore, group A rotavirus was detected in monitoring wells at 3.5-m depth up to 2 months after pig slurry application. The detection of viral genomic material in drainage water and shallow groundwater signifies a potential hazard to human health that needs to be investigated further, as water reservoirs used for recreational use and drinking water are potentially contaminated with zoonotic pathogens.     

Platinum-group Element Geochemistry of Magnetite from Porphyry-Cu-Mo Deposits and their Host Rocks (Siberia,Russia)

The concentrations of platinum-group elements (PGE) have been analyzed in primary magmatic magnetite samples from the Zhireken,Shakhtama and Aksug porphyry Cu-Mo deposits (Siberia,Russia) by laser abla...     

Two-stage contamination during crustal assimilation: isotopic evidence from volcanic rocks in eastern Nevada

Thousands of cubic kilometers of dominantly intermediate composition, metaluminous magma erupted at approximately 35 Ma in eastern Nevada. Two stages of crustal contamination are inferred from detailed study of the earliest vocanic rocks. Fine-grained mafic rocks and rocks with mixed textures, ranging from basalt to rhyolite, were contaminated with a crustal component rich in Nd but poor in Sr. Overlying plagioclaserich andesites and dacites have greater Sr and ⁸⁷Sr/⁸⁶Sr, but less Nd and lower _Nd and are interpreted to have been contaminated by a crustal component with the opposite elemental signature (i.e., poor in Nd but rich in Sr). The first contaminant represents a partial melt of the crust with plagioclase as a residual phase and the second contaminant is the residue of the partial melting event, or bulk crust. The net effect is bulk crustal assimilation, but in two bites. The separation of the crustal souree into two elementally distinct contaminants causes divergent trends with respect to the variation of ⁸⁷Sr/ ⁸⁶Sr versus _Nd that could be misinterpreted to indicate the existence of isotopically distinct crustal reservoirs. Comparison of the calculated contaminants to melting relationships in pelites is consistent with the two contammants representing melt and residue at about 30% melting. The model age of the bulk crust is approximately 2.2 Ga, consistent with an early Proterozoic crustal province inferred by other workers.     

The impact of El Ni?o on South American summer climate during different phases of the Pacific Decadal Oscillation

In austral summer, the observed El Ni?o (EN) events during warm Pacific Decadal Oscillation (PDO) phases (PDO(+)) exhibited large anomalous upper level wave patterns in response to larger Sea Surface Temperature (SST) anomalies in the Equatorial Pacific and Atlantic Oceans compared with SST anomalies in EN events during cold PDO phases (PDO(?)). The precipitation anomalies in PDO(+) EN are increased over Southeastern South America (SESA) associated with the intensification of the moisture flux convergence in this region. The PDO(?) EN events exhibit positive precipitation anomalies only over southern SESA, while negative anomalies were observed in the north. Downward motion and anomalous divergence over central eastern Brazil may have contributed to the weakening of the northwesterly moisture flux convergence associated with the South American Low Level Jet (SALLJ) over the subtropics. The extratropical cyclones showed higher frequency and lower central pressures in southern Brazil, Uruguay, northeastern Argentina, and Southwest Atlantic Ocean during the PDO(+) EN events compared with the PDO(?) EN events. Such increase in the frequency and intensity of cyclogenesis cases seems to be in accordance with the anomalous moisture flux convergence over the SESA and associated reduction in the Sea Level Pressure observed during PDO(+) EN events. In order to investigate the impact of a canonical El Ni?o event over South America under different PDO phases, two numerical experiments were done with an Atmospheric General Circulation Model. Global SST and ice sea fields average over years characterized by (a) PDO(+) and (b) PDO(?) were considered as climatologically fields, and a composite of anomalies of SST of all El Ni?o events observed in 1950?C1999 was added in the region 20oS?C20oN;120oW?C175oW of both ??climatologies.?? The differences in experiments suggest that a canonical EN may produce significant different anomalous atmospheric patterns associated with distinct PDO climatologies. The more significant differences are simulated over extreme northern and eastern Brazil. Additional numerical experiments isolating the observed variability of SST over several oceanic basins during different PDO phases will be conducted to study their particular role on the South American climate.     

Review of Modeling Approaches to Groundwater Flow in Deformed Carbonate Aquifers

We discuss techniques to represent groundwater flow in carbonate aquifers using the three existing modeling approaches: equivalent porous medium, conduit network, and discrete fracture network. Fractures in faulted stratigraphic successions are characterized by dominant sets of sub-vertical joints. Grid rotation is recommended using the equivalent porous medium to match higher hydraulic conductivity with the dominant orientation of the joints. Modeling carbonate faults with throws greater than approximately 100 m is more challenging. Such faults are characterized by combined conduit-barrier behavior. The barrier behavior can be modeled using the Horizontal Flow Barrier Package with a low-permeability vertical barrier inserted to represent the impediment of horizontal flow in faults characterized by sharp drops of the piezometric surface. Cavities can occur parallel to the strike of normal faults generating channels for the groundwater. In this case, flow models need to account for turbulence using a conduit network approach. Channels need to be embedded in an equivalent porous medium due to cavities a few centimeters large, which are present in carbonate aquifers even in areas characterized by low hydraulic gradients. Discrete fracture network modeling enables representation of individual rock discontinuities in three dimensions. This approach is used in non-heavily karstified aquifers at industrial sites and was recently combined with the equivalent porous medium to simulate diffusivity in the matrix. Following this review, we recommend that the future research combines three practiced modeling approaches: equivalent porous medium, discrete fracture network, and conduit network, in order to capture structural and flow aspects in the modeling of groundwater in carbonate rocks.     

The role of SST on the South American atmospheric circulation during January, February and March 2001

Precipitation deficits were observed over southeastern, northeastern and Central Brazil during the 2001 Austral Summer. They contributed to the worsening of the energy crisis that was occurring in the country. A low-level anomalous anticyclonic circulation observed over eastern Brazil enhanced the deviation of moisture transport that usually occurs from the Amazon Basin to southeastern Brazil and inhibited the occurrence of South Atlantic Convergence Zone events in that period. However, an anomalous low-level northerly moisture flux was observed over the La Plata Basin, and positive precipitation anomalies occurred over Bolivia, Paraguay, northeastern Argentina and southern Brazil. Using the ensemble technique, a numerical study was carried out to investigate the role of different sea surface temperature (SST) forcings observed over this anomalous South American atmospheric circulation. Reynolds SST monthly means were used as boundary conditions to study the influence of South Atlantic, South Indian, South Pacific and Equatorial Pacific oceans. The simulations were run from September 2000 to April 2001 using the Community Climate Model version 3.6 General Circulation Model. Ten integrations using different initial conditions were done to each experiment. Numerical experiments suggested that the combined influence of South Pacific and Equatorial Pacific oceans could be responsible for the drought observed over Central Brazil. These experiments simulated the low-level anticyclonic anomaly observed over eastern Brazil. However, both experiments have poorly reproduced the intensity of the anomalous low-level northerly moisture flux observed over the La Plata Basin. Therefore, the intensity of the simulated precipitation anomalies over the subtropical regions was much weaker than observed.     

Assessment of institutional capacity to adapt to climate change in transboundary river basins

Responses to climate change in transboundary river basins are believed to depend on national and sub-national capacities as well as the ability of co-riparian nations to communicate, coordinate, and cooperate across their international boundaries. We develop the first framework for assessing transboundary adaptive capacity. The framework considers six dimensions of transboundary river basins that influence planning and implementation of adaptation measures and represents those dimensions using twelve measurable indicators. These indicators are used to assess transboundary adaptive capacity of 42 basins in the Middle East, Mediterranean, and Sahel. We then conduct a cluster analysis of those basins to delineate a typology that includes six categories of basins: High Capacity, Mediated Cooperation, Good Neighbour, Dependent Instability, Self-Sufficient, and Low Capacity. We find large variation in adaptive capacity across the study area; basins in Western Europe generally have higher capacities to address the potential hazards of climate change. Our basin typology points to how climate change adaptation policy interventions would be best targeted across the different categories of basins.     

Estimation of background levels of contaminants

Samples from hazardous waste site investigations frequently come from two or more statistical populations. Assessment of background levels of contaminants can be a significant problem. This problem is being investigated at the U.S. Environmental Protection Agency's Environmental Monitoring Systems Laboratory in Las Vegas. This paper describes a statistical approach for assessing background levels from a dataset. The elevated values that may be associated with a plume or contaminated area of the site are separated from lower values that are assumed to represent background levels. It would be desirable to separate the two populations either spatially by Kriging the data or chronologically by a time series analysis, provided an adequate number of samples were properly collected in space and/or time. Unfortunately, quite often the data are too few in number or too improperly designed to support either spatial or time series analysis. Regulations typically call for nothing more than the mean and standard deviation of the background distribution. This paper provides a robust probabilistic approach for gaining this information from poorly collected data that are not suitable for above-mentioned alternative approaches. We assume that the site has some areas unaffected by the industrial activity, and that a subset of the given sample is from this clean part of the site. We can think of this multivariate data set as coming from two or more populations: the background population, and the contaminated populations (with varying degrees of contamination). Using robust M-estimators, we develop a procedure to classify the sample into component populations. We derive robust simultaneous confidence ellipsoids to establish background contamination levels. Some simulated as well as real examples from Superfund site investigations are included to illustrate these procedures. The method presented here is quite general and is suitable for many geological and biological applications.