Oxygen and carbon isotope composition of structural carbonate in weathering apatites from laterites, southern Brazil and western Senegal

The oxygen (δ¹⁸O_c) and carbon (δ¹³C_c) isotope compositions of the structural carbonate group (CO₃) in apatites from lateritic profiles were investigated. The weathering profiles, located in southern Brazil and in western Senegal, are developed on three different types of apatite-rich parent rock: carbonatite, metamorphosed marine phosphorite and sedimentary marine phosphorite. The parent rock apatites are of magmatic, hydrothermal, metamorphic and sedimentary origins. The in situ formation of apatite of weathering origin in the profiles is well documented petrographically and geochemically.The overall range of measured δ¹⁸O_c and δ¹³C_c values of apatites of weathering origin (22 to 27 SMOW for δ¹⁸O_c and −15 to −10 PDB for δ¹³C_c) is much smaller than the range of measured and/or published isotope compositions of parent rock apatites (4–35 for δ¹⁸O_c and −11 to +1 for δ¹³C_c). In any profile, the apatites of weathering origin can exhibit lower, similar or higher δ¹⁸O_c values than parent rock apatites. In contrast, their δ¹³C_c values are systematically and significantly lower than those of the parent rock apatites. Apatites formed as a result of weathering in laterites can therefore be readily distinguished from apatites of other origin on the basis of their isotope composition.Assuming that apatite CO₃ fractionates O in a way similar to calcite CO₃, the structural carbonate group of the apatites of weathering origin appears to form in approximate isotopic equilibrium with the weathering solutions. The very low δ¹³C_c values exhibited by these apatites indicate that the dominant sources of dissolved CO₂ in the soil water are organic. The isotope composition of structural carbonate in apatite of weathering origin in lateritic profiles may provide useful information for paleoenvironmental studies.     

Spatial error correction and cointegration in nonstationary panel data: regional house prices in Israel

We “spatialize” residual-based panel cointegration tests for nonstationary spatial panel data in terms of a spatial error correction model (SpECM). Local panel cointegration arises when the data are cointegrated within spatial units but not between them. Spatial panel cointegration arises when the data are cointegrated through spatial lags between spatial units but not within them. Global panel cointegration arises when the data are cointegrated both within and between spatial units. Spatial error correction arises when error correction occurs within and between spatial units. We use nonstationary spatial panel data on the housing market in Israel to illustrate the methodology. We show that regional house prices in Israel are globally cointegrated in the long run and there is evidence of spatial error correction in the short run.     

The contribution of lateritization processes to the formation of the kaolin deposits from eastern Amazon

The eastern region of the Amazon is home to the most important kaolin bauxite producing district in Brazil, referred to as the Paragominas-Capim kaolin bauxite district, which has a reserve of at least 1.0 billion tons of high-quality kaolin used in the paper coating industry. The kaolin deposits are closely related to sedimentary rocks of the Parnaíba basin and their lateritic cover. Two large deposits are already being mined: IRCC (Ipixuna) and PPSA (Paragominas). The geology of the IRCC mine is comprised of the kaolin-bearing lower unit (truncated mature laterite succession derived from the Ipixuna/Itapecuru formation) and the upper unit (immature lateritized Barreiras formation). The lower kaolin unit is characterized by a sandy facies at the bottom and a soft (ore) with flint facies at the top. It is formed by kaolinite, quartz, some iron oxi-hydroxides, mica and several accessories and heavy minerals. The <2 μm kaolinite crystallites only correspond to 41.3–58.3% of the soft kaolin, and large booklets of 15–300 μm are common. The degree of structure order of kaolinite decreases towards the flint kaolin. The chemical composition of the soft kaolin is similar to the theoretical chemical composition of kaolinite, with low iron content, and can be well correlated to most kaolin deposits in the region. The distribution pattern of chemical elements from sandy to flint kaolin (lower unit) suggests a lateritic evolution and erosive truncation. This is quite distinct from the upper unit, which has a mineralogical and chemical pathway relating it to a complete immature lateritic profile. The geological evolution of the IRCC kaolin is similar to that of other deposits in the eastern Amazon region, being comprised of: parent rocks formed in an estuarine marine and fluvio-laccustrine environment during the early Cretaceous; establishment of mature lateritization with the formation of kaolin in the Eocene; marine transgression and regression – (Pirabas and Barreiras formation) with kaolin profile erosion and forward movement of deferruginization and flintization during the Miocene after partial mangrove covering; and immature lateritization – partial kaolin ferruginization during the Pleistocene.     

Saturated permeability measurements on pumice and welded-tuffaceous materials

Fluid flows in consolidated porous media of volcanic origin are being investigated to support such diverse efforts as the modeling of thermal/outgassing phenomena at Mount St. Helens and the hydrological modeling of tuffaceous rocks in support of the Department of Energy’s (DOE) Nevada Nuclear Waste Storage Investigations Project An experimental apparatus was designed and built to allow water-saturated permeabilities as low as 10⁻¹⁸ m² to be measured on cores of diameter 5 cm and length 10 cm under steady-state flow conditions. This same apparatus can also be utilized in a transient (pressure-decay) mode in order to measure permeabilities several orders of magnitude lower than the steady-state limit. Tests were conducted on samples of pumice, fractured welded tuff, and welded tuff, representing a permeability range of seven orders of magnitude Pumice was found to have a permeability of ∼3×10⁻¹² m², sufficiently high to allow the complete Darcy-to-Ergun regime to be investigated Welded (unfractured) tuff was tested in the transient mode, yielding a permeability of ∼5×10⁻¹⁹ m². Two, long-time-scale, steady-flow experiments were conducted on a core of welded tuff containing a single, through-going fracture. For the first experiment, the core was an integral cylinder containing a naturally occurring fracture. For the second experiment, the core was separated into two pieces along the existing fracture plane, then rejoined. Effects of essentially constant, as well as rapidly varied, circumferential stress were studied in both tests. Results showed core permeability to decay to 2×10⁻¹⁸ m² in both cases, independent of the initial fracture state (closed versus open). With a naturally occurring fracture, core permeability decreased by a factor of 2 over a 200-h test period. With an initially open fracture, core permeability decreased by a factor of 4 under the influence of a comparable 200-h load-time history, after 700 h of testing, core permeability was reduced by an order of magnitude from its initial level. Final effective hydraulic fracture aperture was calculated to be 10⁻⁶ m, corresponding to a calculated effective fracture permeability of 10⁻¹³ m² Fracture flow was thus estimated to account for 80% of the total flow rate through this core under final test conditions.     

Patterned fen development in northern Scotland: Hypothesis testing and comparison with ombrotrophic blanket peats

Patterned fens are part of the diverse Holocene peatland landscape of the Flow Country, northern Scotland. Their present vegetation and morphology allies them with boreal systems in Scandinavia and North America. However, previous work has shown that their mode of formation is rather different and has suggested a developmental model in which the poor fens have formed only recently and have arisen as a result of local hydrological change. These ideas are tested here by morphological, stratigraphical and macrofossil studies on three additional patterned fens covering a wider geographical and ecological range. Two sites corroborate the hypotheses of the earlier study, and one site which refutes the earlier findings can be shown to be dependent on different topographic controls. A comparison of two patterned fens with an ombrotrophic mire site in the same area shows that hydroseral processes dominate the early development of individual components of the mire complex. The time of initiation of patterned fens coincides with increasing surface wetness on the ombrotrophic mire. This may be due to climatic change and/or the coalescence of the constituent parts of the present integrated blanket mire system. The hydrological changes arising from this led to the emergence of the springs that currently supply the patterned fens with their water and elevated nutrient levels. The study supports the idea that landscape-scale research and conservation are essential for the understanding and hydrological integrity of blanket mire landscapes such as the Flow Country.     

On the use and abuse of Newton's second law for variable mass problems

We clarify some misunderstandings currently found in the literature that arise from improper application of Newton's second law to variable mass problems. In the particular case of isotropic mass loss, for example, several authors introduce a force that actually does not exist.Facultad de Ciencias Astronómicas y Geofisicas de la Universidad Nacional de La PlataOn a Fellowship from the Comisión de Investigaciones Cientificas de la Provincia de Buenos Aires.Member of the Carrera del Investigador Cientifico del Consejo Nacional de Investigaciones Cientificas y Técnicas de la República Argentina.     

Age constraints on the evolution of the Austroalpine basement to the south of the Tauern Window

The Austroalpine basement to the south of the Tauern Window once was part of the northern margin of Gondwana. It includes the “Altkristallin” and the phyllitic Thurntaler Complex. In the Altkristallin (AMU, MPU), suites of arc-related metamafic sequences occur together with calc-alkaline metagranite. SHRIMP U–Pb dating of zircon from calc-alkaline metagranite associated with an eclogitic amphibolite give an age of 470 ± 3 Ma interpreted as the age of protolith emplacement. In the Thurntaler Complex, metaporphyroids occur together with tholeiitic as well as alkaline within-plate basalt-type metabasite. The metaryholites of this association give a crystallization SHRIMP age of 477 ± 4 Ma, which suggests contemporaneity of arc-related and extensional settings in the Austroalpine basement units. The age data demonstrate widespread magmatic activity associated with the Early-Ordovician amalgamation at the end of the 550–470 Ma subduction–accretion–collision cycle. The Pb–Pb and U–Pb systematics of step-wise leached staurolite and kyanite from the peak-metamorphic assemblage of the Altkristallin indicate that (1) step-wise leaching of staurolite and kyanite yields the age of inclusions rather than the host; (2) zircon inclusions in staurolite suggest an Ordovician or older age for the precursor of the staurolite-schists; (3) the weighted average of the ²⁰⁶Pb/²³⁸U data of the various leaching steps yields a Variscan age for the inclusions (ilmenite, biotite, and andesine). Since these inclusions are part of the metamorphic mineral assemblage, this age provides a minimum estimate for staurolite growth, i.e., metamorphism. Thus, the Pb–Pb and U–Pb systematics of staurolite provide evidence for a Variscan metamorphism of the Austroalpine basement, e.g., MPU, AMU and Thurntaler Complex, to the south of the Tauern Window.     

Evolution of the Peak Hill high-sulfidation epithermal Au–Cu deposit,eastern Australia

The early Palaeozoic Macquarie Arc, southeastern Australia, hosts a variety of major late Ordovician to earliest Silurian subduction-related deposits (e.g., Cadia East, Ridgeway, Cadia Hill, Cowal and Northparkes). However, there is uncertainty about whether coeval high-sulfidation epithermal deposits, which occur in intra-oceanic metallogenic belts elsewhere in the West Pacific, (e.g., Lepanto and Chinkuashih), are also present in the Macquarie Arc. This has led to suggestions that their absence may be due to the poor preservation potential of deposits that form at relatively shallow crustal levels in ancient rocks. We present here an interpretation for evolution of the Peak Hill Au–Cu deposit based on the distribution of alteration facies, sulfur isotope data from several textural forms of pyrite and barite, and an assessment of the regional volcanic and sedimentary facies architecture. These data show that the Peak Hill deposit displays a distinct sub-vertical zoning with a pyrophyllite and vuggy-quartz core, that today extends about 350 m east–west and at least 550 m north–south, which grades out through paragonite+muscovite, kaolinite to a chlorite+epidote alteration zone at the margin. The alteration zoning reflects both lower temperatures and neutralisation of acid fluids with increasing distance from the core, which represents the conduit along which hot acidic hydrothermal fluids were channelled. Several temporally overlapping events of silicification, bladed-quartz-pyrite veining, brecciation and pyrite veining occurred during the last stages of hydrothermal alteration, although most appear to predate mineralisation. Au–Cu mineralisation was associated with late quartz-pyrite-barite veins, and the highest gold grades occur mainly in microcrystalline-quartz-altered rocks in the paragonite+muscovite alteration zone, generally within 50 m outward from the boundary of the pyrophyllite and vuggy-quartz core. Sulfur- and lead-isotope data, and the characteristic zoning of ore minerals and alteration assemblages support a magmatic source for the hydrothermal fluids. Similarities in many of the isotopic signatures between Peak Hill and deposits such as Northparkes support generation of the high-sulfidation mineralisation during the Late Ordovician to earliest Silurian (possibly ca. 440 Ma) metallogenic event. The Late Ordovician to Early Silurian volcanic and sedimentary facies associations at Peak Hill are consistent with alteration and mineralisation occurring in rocks deposited in a submarine setting.