Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.     

Ultra-rapid landscape response and sediment yield following glacier retreat, Icy Bay, southern Alaska

The páramo is a neotropical alpine ecosystem that covers more than 75,000 km² of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g^− 1 at saturation, down to 1.24 g g^− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources.     

Specific effects of background electrolytes on the kinetics of step propagation during calcite growth

The mechanisms by which background electrolytes modify the kinetics of non-equivalent step propagation during calcite growth were investigated using Atomic Force Microscopy (AFM), at constant driving force and solution stoichiometry. Our results suggest that the acute step spreading rate is controlled by kink-site nucleation and, ultimately, by the dehydration of surface sites, while the velocity of obtuse step advancement is mainly determined by hydration of calcium ions in solution. According to our results, kink nucleation at acute steps could be promoted by carbonate-assisted calcium attachment. The different sensitivity of obtuse and acute step propagation kinetics to cation and surface hydration could be the origin of the reversed geometries of calcite growth hillocks (i.e., rate of obtuse step spreading < rate of acute step spreading) observed in concentrated (ionic strength, IS = 0.1) KCl and CsCl solutions. At low IS (0.02), ion-specific effects seem to be mainly associated with changes in the solvation environment of calcium ions in solution. With increasing electrolyte concentration, the stabilization of surface water by weakly paired salts appears to become increasingly important in determining step spreading rate. At high ionic strength (IS = 0.1), overall calcite growth rates increased with increasing hydration of calcium in solution (i.e., decreasing ion pairing of background electrolytes for sodium-bearing salts) and with decreasing hydration of the carbonate surface site (i.e., increasing ion pairing for chloride-bearing salts). Changes in growth hillock morphology were observed in the presence of Li⁺, F⁻ and , and can be interpreted as the result of the stabilization of polar surfaces due to increased ion hydration. These results increase our ability to predict crystal reactivity in natural fluids which contain significant amounts of solutes.     

Dredging-induced nutrient release from sediments to the water column in a southeastern saltmarsh tidal creek

Dredging is a large-scale anthropogenic disturbance agent in coastal and estuarine habitats that can profoundly affect water quality. We examined the impact of a small-scale dredging operation in a salt marsh in South Carolina by comparing nutrient levels (NH(4)(+), NO(x), PO(4)(-)) and total suspended solid concentrations before and during dredging activities. Nutrient enrichment was evaluated within the context of tidal, seasonal, and inter-annual variability by using long-term water chemistry data provided by the North Inlet-Winyah Bay National Estuarine Research Reserve. The conditions of the dredging permit (i.e., its relatively small scale), the season chosen for the work (fall-winter), the nature of the sediments dredged (coarse-grained), and the amount of natural variability in the estuary's water chemistry (even on a daily time-scale) all minimized the impact of the dredging activities. Results of this study will add to the limited body of empirical data that should be considered in evaluating future dredging permit applications related to shallow estuarine waterways.     

Mesofossil flora from the Late Cretaceous of New Zealand

This study presents the first report of mesofossils of flowers, fruits and seeds found in the Cretaceous of New Zealand. The specimens were recovered from the Late Cretaceous (Maastrichtian, ca. 70 Ma) at Kai Point Mine, South Island in a sequence of floodplain sediments sampled just below the Barclay Coal Seam. Angiosperm flowers, fruits and seeds occur in the sample. The most common form is an actinomorphic flower with two whorls of three tepals. Anther bases are preserved and the ovary develops into a drupe, all features that are consistent with placement in the Lauraceae. Reproductive structures including seeds of conifers are also described, with some allied to the Podocarpaceae. This contrasts with interpretations of the flora based on macrofossils that indicate abundant Araucariaceae and highlights the different perspectives that mesofossil floras give to any assemblage. The results of the present study support a Late Cretaceous flora at this site mainly dominated by conifers with affinities to Podocarpaceae but also including lauraceous angiosperms.     

Propagation of coastal‐trapped waves under an ice cover in Hudson Bay*

Abstract

Three arrays of current‐meter moorings were deployed under landfast sea ice in southeast Hudson Bay for eight weeks in spring 1986. Spectral analysis shows low‐frequency signals with periods of 3 to 11 days. These signals are interpreted as being due to coastal‐trapped waves propagating cyclonically in Hudson Bay; their theoretical dispersion relations and corresponding modal structures are presented for winter stratification and are compared with observations. At a period of 3 days both the modified external Kelvin wave and higher mode continental shelf waves may be important in describing the observed low‐frequency variability, whereas at a period of 10 days the Kelvin wave appears to be the dominant mode. The generation mechanisms for these coastal trapped waves are also investigated. Two sources have been studied: the longshore atmospheric pressure gradient and the average atmospheric pressure over the ice cover in Hudson Bay. Coherence and phase analyses performed with time series of longshore current and atmospheric forcing data reveal that both the average atmospheric pressure and the longshore atmospheric pressure gradient are important in explaining the observed low‐frequency variability, without indicating which one is the most important.     

Characterization of seafloor pockmark seepage of hydrocarbons employing fractal: A case study from the western continental margin of India

Here we apply quantitative technique to describe the seafloor seepages based on the multi-beam backscatter and bathymetric investigations to characterize the pockmark morphology. The variable seafloor backscatter strength for coarser seafloor sediments are related to the diagenesis derived from biodegraded seepages. In this regard, box counting method is used to estimate ‘fractal dimension’ for backscatter imagery data of 398 blocks. These blocks are further sub-grouped into six classes depending on the spread of pockmark related seepages. The study area lies 102 km west off Marmagao along the central west coast of India which contains pre-dominantly (70%) gas-charged sediments. Comparison between the estimated self-similar fractals reveals that there is approximately 97% correlation between the box (D_box) and information (D_info) dimensions. Box dimension–derived fractal dimension values, suggest that the seepages are more along the fault trace in deeper waters, in comparison to sparsely distributed shallow water seepages. Besides, this poor seepage is confined within the smooth to moderately rough seafloor. It is established that the high backscatter strength along the upper slope of the pockmark region having higher fractal dimensions reflects multifractal behavior of seepage distribution. Entire area indicates patchy seepage patterns as supported by estimated fractal values showing intermittent fluctuations, which emphasizes non-linear behavior. Estimated self organizing criticality (SOC) parameters for six representative blocks reveal that the nature of pockmark, fault trace, sediment nature coupled with slumping of pockmark’s wall, sediment movement due to bottom currents are controlling the dynamic balance in the area seepage system. Further, our study emphasizing the multifractal behavior of seepage blocks, clearly depicts the drift in the seepage pattern.     

Geophysical surveys of the sediments of Loch Ness,Scotland: implications for the deglaciation of the Moray Firth Ice Stream,British–Irish Ice Sheet

We present results from three geophysical campaigns using high‐resolution sub‐bottom profiling to image sediments deposited in Loch Ness, Scotland. Sonar profiles show distinct packages of sediment, providing insight into the loch's deglacial history. A recessional moraine complex in the north of the loch indicates initial punctuated retreat. Subsequent retreat was rapid before stabilisation at Foyers Rise formed a large stillstand moraine. Here, the calving margin produced significant volumes of laminated sediments in a proglacial fjord‐like environment. Subsequent to this, ice retreated rapidly to the southern end of the loch, where it again deposited a sequence of proglacial laminated sediments. Sediment sequences were then disturbed by the deposition of a thick gravel layer and a large turbidite deposit as a result of a jökulhlaup from the Spean/Roy ice‐dammed lake. These sediments are overlain by a Holocene sheet drape. Data indicate: (i) a former tributary of the Moray Firth Ice Stream migrated back into Loch Ness as a major outlet glacier with a calving margin in a fjord‐like setting; (ii) there was significant sediment supply to the terminus of this outlet glacier in Loch Ness; and (iii) that jökulhlaups are important for sediment supply into proglacial fjord/lake environments and may compose >20% of proglacial sedimentary sequences. Copyright © 2011 John Wiley & Sons, Ltd.