Distribution of dissolved molybdenum,uranium and vanadium in baltic sea waters

This study presents dissolved molybdenum, uranium and vanadium profiles from eight stations in the main Baltic subregions. The elements were analysed by a new analytical procedure based on total-reflection X-ray fluorescence (TXRF). Mo and U reveal a strong, positive correlation with salinity (with r = 0.95 and 0.93, respectively). The estimated end-member concentrations (for S = 35 × 10^?3) are consistent with North Atlantic Ocean water values, indicating conservative mixing with Baltic river waters as the dominating process. In contrast, dissolved V shows relatively low levels, with mean surface and deep layer values of 2.7 and 1.7 nmol kg^?1, respectively. Compared with recently investigated Atlantic Ocean waters (normalized to S = 35 × 10^?3), Baltic waters are deplated in dissolved V by more than 60%. The removal is attributed to scavenging processes by terrigenous and/or biogenic material during the course of mixing. However, the data did not indicate that precipitation or other removal processes were significant in the anaerobic waters.     

A new telluric KCl probe using Filloux's AgAgCl electrode

The measurement of the telluric field's long-time variations requires stable instruments in the period range above 1 day. Obviously, most problems arise from drifting voltages between the telluric probes. Good results have been achieved using a three chamber Hempfling KCl probe together with Filloux's AgAgCl electrode. However, a one chamber probe of 0.6 m length and 0.06 m diameter filled with saturated KCl solution may be sufficient for some applications and additionally allows permanent control of the electrolyte's salt concentration. In a field test the telluric field at a single site was simultaneously observed using one and three chamber probes separated by 25 and 55 m resp. For periods shorter than 1 hour the noise level of the electrodes was found to be less than 1 (mV)²/Hz whereas in the period range between 1 hour and 1 day it increases to 100 (mV)²/Hz. Consequently, surveys investigating long periods of the telluric field can be carried out using small electrode separations of a few tens of meters. Furthermore, the stability of this probe negates the need to interrupt the time series for servicing of the probe. However, the one chamber probe is somewhat inferior to the three chamber probe with regard to temperature dependence at long periods.     

The use of maximum entropy to increase the informational content of hydrological networks by additional gauges

ABSTRACT

The optimization and extension of existing gauging networks are a challenging task, which can be done under consideration of many different aspects. One possibility is to maximize the obtained information on regional hydrological characteristics by new gauges compared to existing ones. For this, information theory approaches are most suitable. Here, the principle of maximum entropy is applied to calculate the probability of non-similarity of catchments to determine locations of new gauges according to the catchment characteristics that are most relevant for the hydrological conditions. The realization in an interactive application, provided online, makes use easy for practitioners and scientists. Goodness-of-fit measures are applied to investigate the explanatory power of the model and the contribution of each characteristic to the model, which gives information on the most influential properties of the catchment. The relevance of the proposed approach is proven by comparing hydrological signatures between similar and non-similar catchment.     

Temporal analysis of thermal bioclimate conditions between Kolkata (India) and its three neighbouring suburban sites

Theoretical and Applied Climatology - The study of human biometeorological conditions is becoming increasingly important in climate perception for the improvement of public health system. The...     

A methodology for the evaluation of the human-bioclimatic performance of open spaces

The purpose of this paper is to present a simple methodology to improve the evaluation of the human-biometeorological benefits of open spaces. It is based on two groups of new indices using as basis the well-known PET index. This simple methodology along with the accompanying indices allows a qualitative and quantitative evaluation of the climatic behavior of the selected sites. The proposed methodology was applied in a human-biometeorology research in the city of Athens, Greece. The results of this study are in line with the results of other related studies indicating the considerable influence of the sky view factor (SVF), the existence of the vegetation and the building material on human-biometeorological conditions. The proposed methodology may provide new insights in the decision-making process related to urban open spaces’ best configuration.

     

Calculation of electromagnetic sensitivities in the time domain

The speed of calculating sensitivities for 3-D conductivity structures for time- domain electromagnetic methods is significantly improved by applying the reciprocity theorem directly in the time domain. The sensitivities are obtained by convolving the electric field in the subsurface due to a transmitter at the surface with the electric field impulse response due to another transmitter, which replaces the original receiver. The acceleration compared to the classical perturbation method is approximately P/R , where P is the number of model parameters and R is the number of receiver positions. If the sensitivity has to be calculated very close to the receiver, approximate sensitivities can be obtained using an integral condition. Comparisons with the classical perturbation approach show that the method gives accurate results. Examples using transmitter–receiver configurations from a long-offset transient electromagnetics survey demonstrate the usefulness of sensitivities for the evaluation of resolution properties.