High-resolution quantitative imaging of plagioclase composition using accumulated backscattered electron images: new constraints on oscillatory zoning

Oscillatory zoning in plagioclase is investigated at small scale (⢪ µm) using accumulated backscattered electron (BSE) images as high-resolution imaging method. Combined with electron microprobe quantitative analysis, gray-value profiles across these images can be calibrated for An-content with a resolution of 0.5 mol% An. Applied to oscillatory-zoned crystals, this new application of BSE imaging allows better characterization of zoning patterns along a profile and quantification of wavelength, amplitude, and shape of the oscillations. We also obtain high-resolution information on the morphology of growth zones boundaries. This approach allows us to better classify the different types of "oscillations" and concentric zoning. Dissolution is more frequent than usually recognized. Major resorption surfaces crosscut several growth zones. Irregular 5-10-µm saw-tooth zones are delimited by faint wavy dissolution surfaces and must be distinguished from small-scale oscillations (Б-3 µm) with straight boundaries. This suggests at least two mechanisms for the formation of these zoning patterns: faint oscillations are probably caused by local kinetic control whereas wavy dissolution surfaces involve magma chamber dynamics.     

Subcritical compaction and yielding of granular quartz sand

Cylindrical samples of water-saturated, initially loose, St. Peter quartz sand were consolidated using triaxial deformation apparatus at room temperature, constant fluid pressure (12.5 MPa), and elevated confining pressures (up to 262.5 MPa). The samples were deformed along four loading paths: (1) hydrostatic stressing tests in which confining pressure was monotonically increased; (2) hydrostatic stress cycling similar to (1) except that effective pressure was periodically decreased to initial conditions; (3) triaxial deformation at constant effective pressure in which differential stress was applied after raising effective pressure to an elevated level; and (4) triaxial stress cycling similar to (3) except that the axial differential stress was periodically decreased to zero. Hydrostatic stressing at a constant rate results in a complex nonlinear consolidation response. At low pressures, large strains occur without significant acoustic emission (AE) activity. With increased pressure, the stress versus strain curve becomes quasi-linear with a corresponding nonlinear increase in AE rates. At elevated pressures, macroscopic yielding is marked by the onset of large strains, high AE rates, and significant grain failure. Stress cycling experiments show that measurable inelastic strain occurs at all stages of hydrostatic loading. The reload portions of stress cycles are characterized by a poro-elastic response and lower AE rates than during constant rate hydrostatic stressing. As the stress nears and exceeds the level that was applied during previous loading cycles, strain and AE rates increase in a manner consistent with yielding. Triaxial stressing cycles achieve greater consolidation and AE rates than hydrostatic loading at similar mean stress levels. By comparing our results with previously published studies, we construct a three-component model to describe elastic and inelastic compaction of granular sand. This model involves acoustically silent grain rearrangement that contributes significant inelastic strain at low pressures, poro-elastic (Hertzian) deformation at all pressures, and inelastic strain related to granular cracking and particle failure which increases in significance at greater pressures.     

Methane and CO2 sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures

Sorption and desorption behaviour of methane, carbon dioxide, and mixtures of the two gases has been studied on a set of well-characterised coals from the Argonne Premium Coal Programme. The coal samples cover a maturity range from 0.25% to 1.68% vitrinite reflectance. The maceral compositions were dominated by vitrinite (85% to 91%). Inertinite contents ranged from 8% to 11% and liptinite contents around 1% with one exception (Illinois coal, 5%). All sorption experiments were performed on powdered (−100 mesh), dry coal samples.Single component sorption/desorption measurements were carried out at 22 °C up to final pressures around 51 bar (5.1 MPa) for CO₂ (subcritical state) and 110 bar (11 MPa) for methane.The ratios of the final sorption capacities for pure CO₂ and methane (in molar units) on the five coal samples vary between 1.15 and 3.16. The lowest ratio (1.15) was found for the North Dakota Beulah-Zap lignite (VR_r=0.25%) and the highest ratios (2.7 and 3.16) were encountered for the low-rank coals (VR_r 0.32% and 0.48%) while the ratio decreases to 1.6–1.7 for the highest rank coals in this series.Desorption isotherms for CH₄ and CO₂ were measured immediately after the corresponding sorption isotherms. They generally lie above the sorption isotherms. The degree of hysteresis, i.e. deviation of sorption and desorption isotherms, varies and shows no dependence on coal rank.Adsorption tests with CH₄/CO₂ mixtures were conducted to study the degree of preferential sorption of these two gases on coals of different rank. These experiments were performed on dry coals at 45 °C and pressures up to 180 bar (18 MPa). For the highest rank samples of this sequence preferential sorption behaviour was “as expected”, i.e. preferential adsorption of CO₂ and preferential desorption of CH₄ were observed. For the low rank samples, however, preferential adsorption of CH₄ was found in the low pressure range and preferential desorption of CO₂ over the entire pressure range.Follow-up tests for single gas CO₂ sorption measurements consistently showed a significant increase in sorption capacity for re-runs on the same sample. This phenomenon could be due to extraction of volatile coal components by CO₂ in the first experiment. Reproducibility tests with methane and CO₂ using fresh sample material in each experiment did not show this effect.     

Automatic 1D inversion of multifrequency airborne electromagnetic data with artificial neural networks: discussion and a case study

Artificial neural networks were used to implement an automatic inversion of frequency‐domain airborne electromagnetic (AEM) data that do not require a priori information about the survey area. Two classes of model, i.e. homogeneous half‐space models and horizontally layered half‐space models with two layers, are used in this 1D inversion, and for each data point the selection of the class of 1D model is performed prior to the inversion, also using an artificial neural network. The proposed inversion method was tested in a survey area situated in Austria, northwest of Vienna in the Bohemian Massif. The results of the inversion were compared with the geological setting, logging results, and seismic and gravimetric measurements. This comparison shows a good correlation between the AEM models and the known geological and geophysical data.     

Genetic implications of pyrite chemistry from the Palaeoproterozoic Olary Domain and overlying Neoproterozoic Adelaidean sequences, northeastern South Australia

Sulphide mineralisation associated with rocks from the Palaeoproterozoic Olary Domain (OD) and overlying Neoproterozoic Adelaidean sequences has undergone a complex history of metamorphism and remobilisation. In this study, new trace element and sulphur isotopic analyses of pyrites from a large number of deposits and paragenetic generations are combined with an existing data set to build up a sequence of mineralising events linked to the tectonometamorphic evolution of the region. The typically high Co/Ni ratios (>10) indicate that early strata-bound pyrite precipitated from a volcanic-related fluid, which had fluctuating activities of the two metals during the early stages of the evolution of the Willyama basin. This period of mineralisation was followed by a diagenetic concentration of sulphide mineralisation at the horizon known as the Bimba Formation, which occurred as a result of the differing redox conditions between the upper and lower sequences in the Willyama Supergroup. During the Mesoproterozoic (1600 to 1500 Ma) Olarian Orogeny, metamorphic remobilisation of strata-bound pyrite resulted in an epigenetic signature; the trace element concentrations of this generation were controlled primarily by the proximity of mineralisation to the mafic intrusive bodies found throughout the terrane. Further reworking of existing sulphides during the Delamerian Orogeny and associated granitoid-intrusive rocks led to the formation of a new generation of epigenetic pyrite that occurs in quartz veins in the Adelaidean sequences and veins that crosscut Olarian fabrics in the Olary Domain. δ³⁴S results range from 16‰ to 11‰, but most data fall between 2‰ and 4‰. This association is suggestive of an initial uniform deep-seated crustal reservoir of sulphur, which has been repeatedly tapped throughout the metallogenic history of the region. The isotopic outliers can be explained by the input of biogenic sulphur or sulphur derived from oxidised, possibly evaporitic, sediments, respectively. Previous workers have invoked the Kupferschiefer and the Zambian Copperbelt as analogues to mineralisation processes in the Olary Domain. This study shows that δ³⁴S and trace element data are suggestive of some affinities with the aforementioned analogues, but a more likely link can be made between epigenetic remobilisation in the Olary region and the iron oxide copper gold (IOCG) style of mineralisation found at the nearby Olympic Dam deposit.     

Petrographic and oxygen-isotopic study of refractory forsterites from R-chondrite Dar al Gani 013 (R3.5-6), unequilibrated ordinary and carbonaceous chondrites

We have conducted petrographic, chemical and in-situ oxygen isotopic studies of refractory forsterites from unequilibrated ordinary and carbonaceous chondrites as well as an unequilibrated R-chondrite. Refractory forsterites occur in all types of unequilibrated chondrites and all have very similar chemical composition with low FeO and high refractory lithophile element (RLE) contents. Refractory forsterites are typically enriched in ¹⁶O relative to ‘normal’ olivine independent of the bulk O-isotope ratios of the parent meteorites. Analyses of refractory forsterites spread along a Δ¹⁷O mixing line with Δ¹⁷O ranging from +2 to −10‰. Due to similarities in oxygen isotopes and chemical compositions, we conclude that refractory forsterites of various types of chondrites come from a single common reservoir. Implications of this hypothesis for the chemical and O-isotope evolution of silicates in the early solar nebular are discussed.     

Parameterizing turbulent exchange over sea ice: the ice station weddell results

A 4-month deployment on Ice Station Weddell (ISW) in the western Weddell Sea yielded over 2000 h of nearly continuous surface-level meteorological data, including eddy-covariance measurements of the turbulent surface fluxes of momentum, and sensible and latent heat. Those data lead to a new parameterization for the roughness length for wind speed, z₀, for snow-covered sea ice that combines three regimes: an aerodynamically smooth regime, a high-wind saltation regime, and an intermediate regime between these two extremes where the macroscale or `permanent' roughness of the snow and ice determines z₀. Roughness lengths for temperature, z_T, computed from this data set corroborate the theoretical model that Andreas published in 1987. Roughness lengths for humidity,z_Q, do not support this model as conclusively but are all, on average, within an order of magnitude of its predictions. Only rarely arez_Tand z_Q equal to z₀. These parameterizations have implications for models that treat the atmosphere-ice-ocean system.     

Approximation formulas for the microphysical properties of saline droplets

Microphysical theory has proven essential for explaining sea spray's role in transferring heat and moisture across the air–sea interface. But large-scale models of air–sea interaction, among other applications, cannot afford full microphysical modules for computing spray droplet evolution and, thus, how rapidly these droplets exchange heat and moisture with their environment. Fortunately, because the temperature and radius of saline droplets evolve almost exponentially when properly scaled, it is possible to approximate a droplet's evolution with just four microphysical endpoints: its equilibrium temperature, T_eq; the e-folding time to reach that temperature, τ_T; its equilibrium radius, r_eq; and the e-folding time to reach that radius, τ_r.Starting with microphysical theory, this paper derives quick approximation formulas for these microphysical quantities. These approximations are capable of treating saline droplets with initial radii between 0.5 and 500 μm that evolve under the following ambient conditions: initial droplet temperatures and air temperatures between 0 and 40 °C, ambient relative humidities between 75% and 99.5%, and initial droplet salinities between 1 and 40 psu.Estimating T_eq, τ_T, and τ_r requires only one-step calculations; finding r_eq is done recursively using Newton's method. The approximations for T_eq and τ_T are quite good when compared to similar quantities derived from a full microphysical model; T_eq is accurate to within 0.02 °C, and τ_T is typically accurate to within 5%. The estimate for equilibrium radius r_eq is also usually within 5% of the radius simulated with the full microphysical model. Finally, the estimate of radius e-folding time τ_r is accurate to within about 10% for typical oceanic conditions.     

Survey and monitoring of landslide displacements by means of L-band satellite SAR interferometry

This paper illustrates the capabilities of L-band satellite SAR interferometry for the investigation of landslide displacements. SAR data acquired by the L-band JERS satellite over the Italian and Swiss Alps have been analyzed together with C-band ERS-1/2 SAR data and in situ information. The use of L-band SAR data with a wavelength larger than the usual C-band, generally considered for ground motion measurements, reduces some of the limitations of differential SAR interferometry, in particular, signal decorrelation induced by vegetation cover and rapid displacements. The sites of the Alta Val Badia region in South Tyrol (Italy), Ruinon in Lombardia (Italy), Saas Grund in Valais (Switzerland) and Campo Vallemaggia in Ticino (Switzerland), representing a comprehensive set of different mass wasting phenomena in various environments, are considered. The landslides in the Alta Val Badia region are good examples for presenting the improved performance of L-band in comparison to C-band for vegetated areas, in particular concerning open forest. The landslides of Ruinon, Saas Grund, and Campo Vallemaggia demonstrate the strength of L-band in observing moderately fast displacements in comparison to C-band. This work, performed with historical SAR data from a satellite which operated until 1998, demonstrates the capabilities of future planned L-band SAR missions, like ALOS and TerraSAR-L, for landslide studies.     

Summer Floods in Central Europe – Climate Change Track?

In Central Europe, river flooding has been recently recognized as a major hazard, in particular after the 1997 Odra /Oder flood, the 2001 Vistula flood, and the most destructive 2002 deluge on the Labe/Elbe. Major recent floods in central Europe are put in perspective and their common elements are identified. Having observed that flood risk and vulnerability are likely to have grown in many areas, one is curious to understand the reasons for growth. These can be sought in socio-economic domain (humans encroaching into floodplain areas), terrestrial systems (land-cover changes – urbanization, deforestation, reduction of wetlands, river regulation), and climate system. The atmospheric capacity to absorb moisture, its potential water content, and thus potential for intense precipitation, are likely to increase in a warmer climate. The changes in intense precipitation and high flows are examined, based on observations and projections. Study of projected changes in intense precipitation, using climate models, for several areas of central Europe, and in particular, for drainage basins of the upper Labe/Elbe, Odra/Oder, and Vistula is reported. Significant changes have been identified between future projections and the reference period, of relevance to flood hazard in areas, which have experienced severe recent floodings.