Carry-over effects of the membrane interface probe

The membrane interface probe (MIP) is widely used to characterize the subsurface distribution of volatile organic compounds (VOCs). One problem that arises during MIP application is that disproportionately high MIP signals are obtained after passing source zones which contain mobile or residual phases. This serious problem occurs because of a carry-over effect, in particular caused by compound-specific retention times in the conventional unheated transfer line, commonly used during such an investigation. The objective of this study was to perform a qualitative methodical field evaluation of the carry-over effect of a conventional MIP system with a conventional unheated transfer line. This was achieved by coupling a mobile mass spectrometer to the MIP device. Results obtained were then further compared with those achieved using a laser induced fluorescence (LIF) system. Because of this coupling, time- and depth-dependent signals for different substances became known. Field evaluation data obtained showed complex superpositions of compounds with MIP system results. As a result of this superposition, MIP signals from the saturated zone beneath the source zone (zone with free and/or residual phase) are blurred and are therefore not representative of particular depths. However, utilizing multidirectional probing alongside conventional MIP probing (forwards and backwards), it was possible to detect the upper and lower phase boundary of the source zone. These MIP results correlated excellently with the LIF results. An important conclusion that can be drawn from the field investigation is that coupling a mobile mass spectrometer to the MIP system enables advanced MIP signal interpretation to be successfully achieved.     

Shake‐table tests of a three‐story reinforced concrete frame with masonry infill walls

This paper presents the shake‐table tests of a 2/3‐scale, three‐story, two‐bay, reinforced concrete frame infilled with unreinforced masonry walls. The specimen is representative of the construction practice in California in the 1920s. The reinforced concrete frame had nonductile reinforcement details and it was infilled with solid masonry walls in one bay and infill walls with window openings in the other bay. The structure was subjected to a sequence of dynamic tests including white‐noise base excitations and 14 scaled historical earthquake ground motion records of increasing intensity. The performance of the structure was satisfactory considering the seismic loads it was subjected to. The paper summarizes the design of the specimen and the major findings from the shake‐table tests, including the dynamic response, the load resistance, the evolution of damage, and the final failure mechanism. Copyright © 2011 John Wiley & Sons, Ltd.     

Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.     

Environmental Radioxenon Levels in Europe: a Comprehensive Overview

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.     

Rock slope instability assessment using spatially distributed structural orientation data in Darjeeling Himalaya (India)

We discuss a geographic information system (GIS)‐based methodology for rock slope instability assessment based on geometrical relationships between topographic slopes and structural discontinuities in rocks. The methodology involves (a) regionalization of point observations of orientations (azimuth and dip) of structural discontinuities in rocks in order to generate a digital structural model (DStM), (b) testing the kinematical possibility of specific modes of rock slope failures by integrating DStMs and digital elevation model (DEM)‐derived slope and aspect data and (c) computation of stability scenarios with respect to identified rock slope failure modes. We tested the methodology in an area of 90 km² in Darjeeling Himalaya (India) and in a small portion (9 km²) within this area with higher density of field structural orientation data. The results of the study show better classification of rock slope instability in the smaller area with respect to known occurrences of deep‐seated rockslides than with respect to shallow translational rockslides, implying that structural control is more important for deep‐seated rockslides than for shallow translational rockslides. Results of scenario‐based analysis show that, in rock slopes classified to be unstable, stress‐induced rock slope instability tends to increase with increasing level of water saturation. The study demonstrates the usefulness of spatially distributed data of orientations of structural discontinuities in rocks for medium‐ to small‐scale classification of rock slope instability in mountainous terrains. Copyright © 2010 John Wiley & Sons, Ltd.     

Diachronous isotopic and sedimentary responses to topographic change as indicators of mid‐Eocene hydrologic reorganization in the western United States

Early Cenozoic terrestrial deposits in the western United States represent well‐preserved archives of climatic and tectonic processes that together shaped the Earth's surface during the demise of a large continental plateau. This study examines a Cenozoic terrestrial sedimentary sequence in the central part of the Cordilleran orogen (Montana) using sedimentologic and geochemical techniques. At ～49 Ma, we observe rapid major shifts in oxygen, carbon and strontium isotope records that are too large to directly reflect changes in meteoric water composition due to simple orographic rainout. The transition to low‐δ¹⁸O values in pedogenic carbonate in concert with changes in the composition of clastic material at ～49 Ma points to the input of evolved meteoric water to the hydrological cycle due to a change in the source of waters reaching Cordilleran intermontane regions in southwestern Montana. This drainage reorganization coincides with the initiation of magmatism and extension to the west in what is now Montana and Idaho. The sedimentological record shows evidence that depositional gradients increased in the study area ～46 Ma, ～3 Myr after the drainage reorganization occurred. This interval is most likely the time it took for extensional deformation to propagate to the study area itself. Evidence of freshening events in Laramide Basins to the southeast suggests that this drainage reorganization diverted waters to progressively fill these basins and highlights the impact of post‐plateau extension‐related landscape reorganization on river networks and lake dynamics. This study also emphasizes the importance of using multiple tools in deciphering topographic history through the study of terrestrial basin deposits, in that interpretation based on any single method employed would have compromised our ability to successfully identify the regional evolution of topography and drainage networks.     

Seismic damage analysis including inelastic shear–flexure interaction

The paper focusses on seismic damage analysis of reinforced concrete (R/C) members, accounting for shear–flexure interaction in the inelastic range. A finite element of the beam-column type recently proposed by the writers for the seismic analysis of R/C structures is first briefly described. The analytical model consists of two distributed flexibility sub-elements which interact throughout the analysis to simulate inelastic flexural and shear response. The finite element accounts for shear strength degradation with inelastic curvature demand, as well as coupling between inelastic flexural and shear deformations after flexural yielding. Based on this model, a seismic damage index is proposed taking into account both inelastic flexural and shear deformations, as well as their interaction. The finite element and the seismic damage index are used to analyse the response of R/C columns tested under cyclic loading and failing either in shear or in flexure. It is shown that the analytical model and damage index can predict and describe well the hysteretic response of R/C columns with different types of failure.     

What Can be Expected from the GRACE-FO Laser Ranging Interferometer for Earth Science Applications?

The primary objective of the gravity recovery and climate experiment follow-on (GRACE-FO) satellite mission, due for launch in August 2017, is to continue the GRACE time series of global monthly gravity field models. For this, evolved versions of the GRACE microwave instrument, GPS receiver, and accelerometer will be used. A secondary objective is to demonstrate the effectiveness of a laser ranging interferometer (LRI) in improving the satellite-to-satellite tracking measurement performance. In order to investigate the expected enhancement for Earth science applications, we have performed a full-scale simulation over the nominal mission lifetime of 5 years using a realistic orbit scenario and error assumptions both for instrument and background model errors. Unfiltered differences between the synthetic input and the finally recovered time-variable monthly gravity models show notable improvements with the LRI, on a global scale, of the order of 23 %. The gain is realized for wavelengths smaller than 240 km in case of Gaussian filtering but decreases to just a few percent when anisotropic filtering is applied. This is also confirmed for some typical regional Earth science applications which show randomly distributed patterns of small improvements but also degradations when using DDK4-filtered LRI-based models. Analysis of applied error models indicates that accelerometer noise followed by ocean tide and non-tidal mass variation errors are the main contributors to the overall GRACE-FO gravity model error. Improvements in these fields are therefore necessary, besides optimized constellations, to make use of the increased LRI accuracy and to significantly improve gravity field models from next-generation gravity missions.     

Transport of salt and freshwater in the Atlantic Subpolar Gyre

Transport of salt in the Irminger Current, the northern branch of the Atlantic Subpolar Gyre coupling the eastern and western subpolar North Atlantic, plays an important role for climate variability across a wide range of time scales. High-resolution ocean modeling and observations indicate that salinities in the eastern subpolar North Atlantic decrease with enhanced circulation of the North Atlantic subpolar gyre (SPG). This has led to the perception that a stronger SPG also transports less salt westward. In this study, we analyze a regional ocean model and a comprehensive global coupled climate model, and show that a stronger SPG transports more salt in the Irminger Current irrespective of lower salinities in its source region. The additional salt converges in the Labrador Sea and the Irminger Basin by eddy transports, increases surface salinity in the western SPG, and favors more intense deep convection. This is part of a positive feedback mechanism with potentially large implications for climate variability and predictability.