Primary petrology,mineralogy and age of the Letšeng-la-Terae kimberlite (Lesotho,Southern Africa) and parental magmas of Group-I kimberlites

The Let?eng-la-Terae kimberlite (Lesotho), famous for its large high-value diamonds, has five distinct phases that are mined in a Main and a Satellite pipe. These diatreme phases are heavily altered but parts of a directly adjacent kimberlite blow are exceptionally fresh. The blow groundmass consists of preserved primary olivine with Fo_86?88, chromite, magnesio-ulvöspinel and magnetite, perovskite, monticellite, occasional Sr-rich carbonate, phlogopite, apatite, calcite and serpentine. The bulk composition of the groundmass, extracted by micro-drilling, yields 24–26 wt% SiO₂, 20–21 wt% MgO, 16–19 wt% CaO and 1.9–2.1 wt% K₂O, the latter being retained in phlogopite. Without a proper mineral host, groundmass Na₂O is only 0.09–0.16 wt%. However, Na-rich K-richterite observed in orthopyroxene coronae allows to reconstruct a parent melt Na₂O content of 3.5–5 wt%, an amount similar to that of highly undersaturated primitive ocean island basanites. The groundmass contains 10–12 wt% CO₂, H₂O is estimated to 4–5 wt%, but volatiles and alkalis were considerably reduced by degassing. Mg# of 77.9 and 530 ppm Ni are in equilibrium with olivine phenocrysts, characterize the parent melt and are not due to olivine fractionation. ⁸⁷Sr/⁸⁶Sr_(i)?=?0.703602–0.703656, ¹⁴³Nd/¹⁴⁴Nd_(i)?=?0.512660 and ¹⁷⁶Hf/¹⁷⁷Hf_(i)?=?0.282677–0.282679 indicate that the Let?eng kimberlite originates from the convective upper mantle. U–Pb dating of groundmass perovskite reveals an emplacement age of 85.5?±?0.3 (2σ) Ma, which is significantly younger than previously proposed for the Let?eng kimberlite.     

Uranium and arsenic dynamics in volcano-sedimentary basins – An exemplary study in North-Central Mexico

Uranium and As in deep groundwater of the volcano-sedimentary Villa de Reyes Graben around the city of San Luis Potosí in semi-arid North-Central Mexico (mean U: 7.6 μg L⁻¹, max. 138 μg L⁻¹; mean As: 11.4 μg L⁻¹, max. 25.8 μg L⁻¹) partly exhibit concentrations in excess of the WHO guideline values and thus endanger the quality of the most important drinking water source. To unravel the mechanisms for their enrichment in groundwater, the potential trace element sources, volcanic rocks and basin fill sediments, were characterized. A total of 131 solid and liquid samples were analyzed for major and trace element composition. The As/U hydrogeochemical signatures, their behavior during rock alteration and evidence from other major and trace element distributions, especially rare earth elements, strongly argue for dissolution of acid volcanic glass to be the dominating process of U and As release into groundwater. This natural baseline quality representing water–acid volcanic rock interaction is modified by additional trace element (preferentially As) mobilization from the sedimentary basin fill, representing a secondary source, in the course of decarbonatization of playa lake sediments and desorption from Fe-(hydr)oxide coated clastic material. The common behavior of both elements during magmatic differentiation and growing drift apart in sedimentary environments are important findings of this work. Comparison with recent findings in a similar environment suggests a common primary trace element source identification but significant differences in the evolution of As and U distribution. Geological and climatic similarity to numerous volcano-sedimentary basins makes the findings useful for water management purposes and transferable to other semi-arid regions facing challenges of geogenically impacted drinking water quality.     

Preservation of chemical residue-melt equilibria in natural anatexite: the effects of deformation and rapid cooling

A combined petrologic, textural and chemical approach is used to interpret the relationship between chemical exchange and deformation during partial melting of a granodioritic gneiss in the contact aureole of the Bergell Pluton (Central Alps). In contrast to most regional metamorphic anatexites, chemical equilibrium between residue and segregated melt was attained and preserved by several elements, as shown by their present distribution. Equilibrium involved both the major and the trace elements hosted in the rock-forming minerals and the light rare earth elements (LREE), hosted primarily in allanite. Equilibrium with respect to LREEs was achieved because allanite had a reactive behaviour during water-present melting, in contrast to the refractive behaviour of xenotime, which mostly controls the distribution of the HREE's. The attainment and preservation of equilibrium between leucosome and residue requires peculiar boundary conditions. We propose that the achievement of equilibrium between melt and residue was promoted by deformation, operating via a mechanism of melt present granular flow (i.e. dissolution-accommodated grain-boundary sliding active during partial melting). Microstructural observations indicate that melt-present granular flow was the dominating deformation mechanism in these anatexites. The preservation of residue-melt equilibrium is inferred to result from rapid cooling under contact metamorphic conditions and from the lack of deformation below the solidus.     

Recharge,geochemical processes and water quality in karst aquifers: Central West Bank,Palestine

The Central West Bank aquifer (CWB) is one of the most important resources of fresh groundwater of Palestine. The geology of the area consists mainly of karstic and permeable limestones and dolomites interbedded with argillaceous beds of late Albian–Turonian age. Exploitation of the CWB aquifer, combined with lack of information required to understand the groundwater pattern, represents a challenge for reservoir management. The present work reports hydrogeochemistry, microbiology and environmental isotope data from spring water samples, which were utilized to understand recharge mechanisms, geochemical evolution and renewability of groundwater in CWB aquifer. Besides the major chemical compositions, ionic ratios were used to delineate mineral-solution reactions and weathering processes. Interpretation of chemical data suggests that the chemical evolution of groundwater is primarily controlled by (1) water–rock interactions, involving dissolution of carbonate minerals (calcite and dolomite), and (2) cation exchange processes. The measured equation of the local meteoric water line is δD?=?5.8 δ¹⁸O?+?9.9. Stable isotopes show that precipitation is the source of recharge to the groundwater system. The evaporation line has a linear increasing trend from south to north direction in the study area. All analyzed spring waters are suitable for irrigation, but not for drinking purposes. The results from this study can serve as a basis for decision-makers and stakeholders, with the intention to increase the understanding of sustainable management of the CWBs.     

Age of Sheep Creek Tephra (Pleistocene) in Central Alaska from Thermoluminescence Dating of Bracketing Loess

The age of the Sheep Creek tephra (SCt), a widespread marker ash bed in eastern Alaska and western Yukon Territory, has been ambiguous and controversial. We have obtained three reliable thermoluminescence age estimates from bracketing loess near Fairbanks that imply a deposition age of about 190,000 ± 20,000 yr for SCt. Three of six loess samples near and closely bracketing the SCt beds near Fairbanks yielded younger age estimates (∼117,000 and ∼135,000 yr), most likely (based on field aspects) because of reworking and contamination by translocated grains. The new, reliable age assignment of 190,000 yr confirms independent stratigraphic evidence of a pre-last interglaciation age, and stratigraphic evidence from one site (Upper Eva Creek) that SCt is older than the more-widespread 140,000-yr-old Old Crow tephra. The SCt age also has implications for regional correlations of glacial and nonglacial deposits. In particular, it supports the stratigraphic and geomorphic interpretation that the Delta Glaciation in the east-central Alaska Range and the Reid Glaciation in western Yukon Territory are older than the last interglaciation (isotope substage 5e).     

Analysis of the effect of trees on block propagation using a DEM model: implications for rockfall modelling

The objective of this research was to use numerical models based on mechanical approaches to improve the integration of the protective role of forests against rockfall into block propagation models. A model based on the discrete element method (DEM) was developed to take into account the complex mechanical processes involved during the impact of a block on a tree. This modelling approach requires the definition of many input parameters and cannot be directly integrated into block propagation models. A global sensitivity analysis identified the leading parameters of the block kinematics after impact (i.e. block energy reduction, trajectory changes, and rotational velocity): the impact velocity, the tree diameter, and the impact point horizontal location (i.e. eccentricity). Comparisons with the previous experimental and numerical studies of block impacts on trees demonstrated the applicability of the DEM model and showed some of the limitations of earlier approaches. Our sensitivity analysis highlights the significant influence of the impact velocity on the reduction of the block’s kinetic energy. Previous approaches usually also focus on parameters such as impact height, impact vertical incidence, and tree species, whose importance is only minor according to the present results. This suggests that the integration of forest effects into block propagation models could be both improved and simplified. The DEM model can also be used as an alternative to classical approaches for the integration of forest effects by directly coupling it with block propagation models. This direct coupling only requires the additional definition of the location and the diameter of each tree. Indeed, the input parameters related to the mechanical properties of the stem and the block/stem interaction in the DEM model can be set to average values because they are not leading parameters. The other input parameters are already defined or calculated in the block propagation model.     

Luminescence chronology of late pleistocene loess-paleosol and tephra sequences near Fairbanks, Alaska

Thermoluminescence (TL) and infrared-stimulated luminescence (IRSL) sediment-dating methods have been applied to paleosol- and tephra-bearing loess sequences younger than marine oxygen isotope stage (MIS) 7 at three important sites. TL ages indicate the development of significant paleosols ∼75,000 and ∼30,000 yr ago in the loess sequence at the Gold Hill site. Relatively minor soil development occurred ∼70,000 and ∼48,000 yr ago. Like the ∼75,000-yr-old soil, the 30,000-yr-old soil is apparently of global extent, and consistent in timing with inferred warm intervals elsewhere (e.g., Greenland, Europe, western and central China). At Birch Hill, replicate TL dating of primary loess combined with two earlier TL results from the same site, and with an earlier mean fission-track-glass-shard age of 140,000 ± 10,000 yr for the associated Old Crow tephra, yield a more precise numeric age of 142,300 ± 6600 yr for this Alaska/Yukon chronostratigraphic marker ash bed. Three of the TL ages at the Halfway House site are difficult to interpret, but combined with other evidence, they indicate: (1) the upper 5-6 m of loess from Halfway House is not part of the Gold Hill Loess (equivalent to pre-MIS 5 age) as long thought by T.L. Péwé, but rather is much younger; (2) the regionally significant variegated tephra, found in the Fairbanks and Klondike areas and previously thought to be older than MIS 5, has an age of 77,800 ± 4100 yr (late MIS 5).