High-resolution Surveys for Geohazards and Shallow Gas: NW Adriatic (Italy) and Iskenderun Bay (Turkey)

The need for quantifying and understanding the distribution of shallow gas is both of academic interest and of relevance to offshore facilities. The combination of seafloor mapping, subbottom profiling, and multi-channel seismic data can provide information on regions of possible shallow gas, where the gas impacts the acoustic properties of the host material and the seafloor. In this paper, we present two case studies – one academic and one industry – that evaluate the distribution of shallow gas in two field areas in the Mediterranean. In the first case study, geophysical data from Iskenderun Bay, southeastern Turkey, indicate the presence and distribution of shallow gas. Pockmarks on the seafloor are associated with acoustic wipeout in the shallow subbottom data. Although deeper seismic data do not show bright spots or other indicators of possible gas, instantaneous frequency analysis clearly shows laterally restricted anomalies indicating gas-rich zones. The interpretation of possible shallow gas resulted in moving a proposed drilling location to a nearby area characterized by fewer (but still present) shallow gas signatures. In the second case study, cores acquired in the Po Delta, Adriatic Sea, provide quantitative ground-truthing of shallow gas – as suggested by geophysical data – and provide minimum estimates of the percentage of gas in the subsurface. Cores targeted on anomalous subbottom data yielded up to 41,000 ppm methane; cores with anomalous gas content are associated with thick recent flood deposits which may effectively isolate reactive terrigenous organic matter from biologic and physical re-working.     

Life Cycle, Demography and Secondary Production of the Polychaete Hediste ­diversicolor in a Non-Polluted Estuary in the Bay of Biscay

Abstract. Population dynamics and secondary somatic production data of a population of the polychaete Hediste diversicolor (O. F. Müller) are reported. Monthly samples were taken in a small muddy-sand flat in the Gernika estuary (Basque Country, North Iberian Peninsula) from May 1991 to May 1992. In addition to H. diversicolor abundance, temporal variation of the infauna and sediment conditions were analysed. Size measurements were employed to estimate H. diversicolor biomass and several cohorts were differentiated based on the size distribution. Secondary production was estimated based on cohort summation of growth increments following individual cohorts through time. Results are compared with those of other H. diversicolor populations located along the whole latitudinal gradient of distribution of the species.     

Sulfur and carbon isotope geochemistry of coal and derived coal-combustion by-products: An example from an Eastern Kentucky mine and power plant

The isotopic compositions of S (δ³⁴S) and C (δ¹³C) were determined for the coal utilized by a power plant and for the fly ash produced as a by-product of the coal combustion in a 220-MW utility boiler. The coal samples analyzed represent different lithologies within a single mine, the coal supplied to the power plant, the pulverized feed coal, and the coal rejected by the pulverizer. The ash was collected at various stages of the ash-collection system in the plant. There is a notable enrichment in ³⁴S from the base to the top of the coal seam in the mine, with much of the variation due to an upwards enrichment in the δ³⁴S values of the pyrite. Variations in δ³⁴S and in the amount of pyritic S in the coal delivered to the plant show that there was a change of source of coal supplied to the plant, between week one and week two of monitoring, supporting a previous study based on metal and sulfide geochemistry for the same plant. The fly ash has a more enriched δ³⁴S than the pulverized coal and, in general, the δ³⁴S is more enriched in fly ashes collected at cooler points in the ash-collection system. This pattern of δ³⁴S suggests an increased isotopic fractionation due to temperature, with the fly ash becoming progressively depleted in ³⁴S and the flue gas S-containing components becoming progressively enriched in ³⁴S with increasing temperatures. Substantially less variation is seen in the C isotopes compared to S isotopes. There is little vertical variation in δ¹³C in the coal bed, with δ¹³C becoming slightly heavier towards the top of the coal seam. An 83–93% loss of solid phase C occurs during coal combustion in the transition from coal to ash owing to loss of CO₂. Despite the significant difference in total C content only a small enrichment of 0.44–0.67‰ in ¹³C in the ash relative to the coal is observed, demonstrating that redistribution of C isotopes in the boiler and convective passes prior to the arrival of the fly ash in the ash-collections system is minor.     

Accessibility to basic services in one of the most sparsely populated areas in Europe: the province of Teruel (Spain)

This paper analyses local differences in access to basic health services in the province of Teruel (Spain), one of the most sparsely populated areas in Europe. The demographic decline and the concentration of the remaining population in the main settlements has meant that there is a high degree of spatial fit of supply and demand and average aggregate accessibility is good. However, access costs are high for the scarce and aged population resident in the most remote villages and hamlets scattered over an extensive and tacitly ignored territory. In such circumstances the demands of the inhabitants for more attention from the public authorities, expressed through the 'Teruel Exists' movement, can be readily understood.     

Isotopic evidence on the diagenetic evolution of coastal sabkha reservoirs from the Solimões Basin, northern Brazil

The isotopic composition of diagenetic carbonates, sulfates, illites and associated diagenetic constituents of the Carboniferous Juruá sandstones, Solimões Basin, largest hydrocarbon reservoirs of northern Brazil, was analyzed in conjunction with petrographic characterization and chemical composition. Eolian Juruá sandstones, deposited in a coastal sabkha of a wide cratonic sag, are the best reservoirs, but diagenetic processes introduced strong and complex heterogeneities, which affect hydrocarbon production. Dolomite and anhydrite cementation, together with compaction, exerts the main control on the quality of the reservoirs. Early dolomite cements precipitated under strong evaporation, while late dolomites are related to thermal decarboxylation. Late anhydrite cements are related to the interbedded evaporites and possibly to the oxidation of dissolved sulfide. Authigenic illite K–Ar ages are related to the voluminous Triassic basic magmatism (around 200 Ma), and to the Jurassic–Cretaceous tectonism (around 150 Ma), which may have also affected the late anhydrite and dolomite–ankerite cementation. This isotopic study revealed the major conditions of the diagenetic processes that strongly affected the Juruá reservoirs, which are essential for the development of models that will optimize the production, as well as decrease the risks in the exploration for new Juruá reservoirs.     

Las Matras Block, Central Argentina (37°S-67°W): the Southernmost Cuyania Terrane and its Relationship with the Famatinian Orogeny

The Las Matras Block in Central Argentina constitutes the southernmost part of the Cuyania terrane, which was accreted to the southwestern margin of Gondwana during the Early to Mid Ordovician Famatinian orogeny. The Grenville-aged rocks of the Las Matras Block are represented by the tonalitic to trondhjemitic Las Matras pluton. A new U-Pb conventional zircon age of 1244±42 Ma confirms previous Sm-Nd and Rb-Sr isochron ages of this pluton. Mineral composition data are consistent with the tonalitic-trondhjemitic character of the pluton, and constrain its emplacement level to 1.9 to 2.6 kb. This shallow level of emplacement and the undeformed character of the pluton are distinctive features of this southernmost basement. A regional comparison indicates that the igneous-metamorphic evolution of the Grenville-aged basement rocks of the Cuyania terrane occurred over a period of more than 200 million years, with ages older than 1200 Ma up to those close to 1000 Ma. The shallowest crustal level is found in Las Matras, suggesting a southward shallowing of the exposed level of basement. The deformation and metamorphism associated with the collisional Famatinian orogeny affect both the Cuyania terrane and the adjacent western margin of Gondwana, and the Gondwana margin was also the locus of the related arc magmatism, but the compressive effects of the collision decrease in intensity toward the south. The Famatinian metamorphism and magmatism continue even further south into the Patagonia region, but the southern continuity of the Cuyania terrane into this region remains uncertain.     

Deglacial and postglacial climate history in east-central Isla Grande de Chiloé, southern Chile (43°S)

Palynologic and stratigraphic data from Laguna Tahui (42°50′S, 73°30′W) indicate cool-temperate and humid conditions there between 14,000 and 10,000 ¹⁴C yr B.P., followed by warmer and drier-than-present conditions between 10,000 and 7000 ¹⁴C yr B.P., and subsequent cooling and rise in precipitation over the last 5800 ¹⁴C yr. The thermophilous Valdivian trees Eucryphia cordifolia and Caldcluvia paniculata reached their maximum abundance during the early Holocene warm-dry phase (10,000-7000 ¹⁴C yr B.P.), followed by a rise in lake levels and reexpansion of North Patagonian conifers starting at 7000 and 5800 ¹⁴C yr B.P., respectively. Variations in the stratigraphic and geographic distribution of temperate rainforests in southern Chile suggest multimillennial trends in temperature and westerly activity, which are spatially and temporally coherent with paleoclimate records from neighboring regions. Climate variability at millennial and submillennial time scales may account for the establishment and persistence of fine-scale mosaics of Valdivian and North Patagonian rainforest species in low- to mid-elevation communities since ∼5800 ¹⁴C yr B.P.     

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.     

Water resources for agriculture in a changing climate: international case studies

This integrated study examines the implications of changes in crop water demand and water availability for the reliability of irrigation, taking into account changes in competing municipal and industrial demands, and explores the effectiveness of adaptation options in maintaining reliability. It reports on methods of linking climate change scenarios with hydrologic, agricultural, and planning models to study water availability for agriculture under changing climate conditions, to estimate changes in ecosystem services, and to evaluate adaptation strategies for the water resources and agriculture sectors. The models are applied to major agricultural regions in Argentina, Brazil, China, Hungary, Romania, and the US, using projections of climate change, agricultural production, population, technology, and GDP growth.For most of the relatively water-rich areas studied, there appears to be sufficient water for agriculture given the climate change scenarios tested. Northeastern China suffers from the greatest lack of water availability for agriculture and ecosystem services both in the present and in the climate change projections. Projected runoff in the Danube Basin does not change substantially, although climate change causes shifts in environmental stresses within the region. Northern Argentina's occasional problems in water supply for agriculture under the current climate may be exacerbated and may require investments to relieve future tributary stress. In Southeastern Brazil, future water supply for agriculture appears to be plentiful. Water supply in most of the US Cornbelt is projected to increase in most climate change scenarios, but there is concern for tractability in the spring and water-logging in the summer.Adaptation tests imply that only the Brazil case study area can readily accommodate an expansion of irrigated land under climate change, while the other three areas would suffer decreases in system reliability if irrigation areas were to be expanded. Cultivars are available for agricultural adaptation to the projected changes, but their demand for water may be higher than currently adapted varieties. Thus, even in these relatively water-rich areas, changes in water demand due to climate change effects on agriculture and increased demand from urban growth will require timely improvements in crop cultivars, irrigation and drainage technology, and water management.