Long-term changes in salt marsh extent affected by channel deepening in a modified estuary

The aim of this study is to quantify the long-term (54 years) rates of marsh extension and retreat at two sites in the Westerschelde Estuary, SW Netherlands. Nine sets of aerial photographs were obtained for each of the two salt marsh sites, Zuidgors and Waarde, taken at various times between 1944 and 1998. The seaward edges of the marshes were digitised from rectified images after the photographs had been scanned and georegistered to the Dutch National Grid. Comparison of the extents of the marshes at these nine time points revealed that the areas of both marshes had fluctuated during these 54 years with periods of both extension and retreat of the seaward marsh edges. These periods of extension and retreat appeared to be approximately synchronised until the 1990s, with mean changes in position of marsh front ranging from −7.92 to 6.04 m a⁻¹.The rate of landward retreat and seaward extension of the marsh front is shown to be related to an increase in the tidal prism brought about by dredging operations to maintain or increase the depth of the main navigable channel of the estuary. The consequent greater frequency with which the high tides reach the edge of the fringing marshes increases the risk of erosion. Strong westerly winds may also be a factor in increasing erosion. No relationship between the volume of shipping traffic using the estuary and marsh erosion was found.     

Fluxes to sediments underlying the Rainbow hydrothermal plume at 36°14′N on the Mid-Atlantic Ridge

A geochemical investigation has been conducted of a suite of four sediment cores collected from directly beneath the hydrothermal plume at distances of 2 to 25 km from the Rainbow hydrothermal field. As well as a large biogenic component (>80% CaCO₃) these sediments record clear enrichments of the elements Fe, Cu, Mn, V, P, and As from hydrothermal plume fallout but only minor detrital background material. Systematic variations in the abundances of “hydrothermal” elements are observed at increasing distance from the vent site, consistent with chemical evolution of the dispersing plume. Further, pronounced Ni and Cr enrichments at specific levels within each of the two cores collected from closest to the vent site are indicative of discrete episodes of additional input of ultrabasic material at these two near-field locations. Radiocarbon dating reveals mean Holocene accumulation rates for all four cores of 2.7 to 3.7 cm.kyr⁻¹, with surface mixed layers 7 to 10+ cm thick, from which a history of deposition from the Rainbow hydrothermal plume can be deduced. Deposition from the plume supplies elements to the underlying sediments that are either directly hydrothermally sourced (e.g., Fe, Mn, Cu) or scavenged from seawater via the hydrothermal plume (e.g., V, P, As). Holocene fluxes into to the cores’ surface mixed layers are presented which, typically, are an order of magnitude greater than “background” authigenic fluxes from the open North Atlantic. One core, collected closest to the vent site, indicates that both the concentration and flux of hydrothermally derived material increased significantly at some point between 8 and 12 ¹⁴C kyr ago; the preferred explanation is that this variation reflects the initiation/intensification of hydrothermal venting at the Rainbow hydrothermal field at this time—perhaps linked to some specific tectonic event in this fault-controlled hydrothermal setting.     

Novel Well Completions in Small Diameter Coreholes Created Using Portable Rock Drills

Difficult access conditions have limited techniques for groundwater system characterization and monitoring in bedrock exposed landscapes. This condition is common in the mining industry and resulted in the development of lightweight portable drills. This paper describes how these drills were used at a contaminated site to understand the groundwater flow system by adapting piezometer designs, ensuring effective seals to obtain reliable hydraulic head, hydrochemistry, and contaminant concentrations. Two drilling machines were evaluated: the Shaw Portable Core Drill? fits in a backpack and can advance continuously cored rock holes, nominal 51 millimeters (mm) diameter, to depths up to approximately 15 meters (m); and the larger Winkie Drill? requires a two or more people to mobilize and can advance continuously cored holes, nominal 48 mm diameter, to depths of approximately 45 m. The resulting small diameter coreholes were accommodated in the design of each well using a seal created by injecting grout into a semipermeable fabric sleeve. This “fabric sleeve” serves as a means to contain the grout and ensures that the entire annulus above the screen is sealed without loss of grout into the formation, allowing the well to perform as a piezometer. To develop and demonstrate this methodology for groundwater monitoring in bedrock, the two drills were used in drainages located along the slopes of an elevated sandstone outcrop near Los Angeles, California. Unique insights into the groundwater flow system of this bedrock environment, which would otherwise be unattainable, were achieved. This methodology overcomes the accessibility limitations of conventional drilling methods that prevent installation of wells in remote and rugged mountainous terrains.     

Fluoride-Selective Electrode as a Tool to Evaluate the Degradation of PFAS in Groundwater: A Bench-Scale Investigation

Fluoride (F⁻) concentration in groundwater can be used as an independent measure of the degradation of per- and polyfluoroalkyl substances (PFAS) at contaminated sites. This study assessed the impact of the groundwater matrix, oxidizing reagents, quenching agent, and sample handling procedures (filtration) on determinations of F⁻. F⁻ was quantified using a fluoride-selective electrode (FSE) using matrix spike recovery (acceptable range 75 to 125%) and electrode slope performance (ideal range −54 to −60 mV). For the unaltered aqueous matrices considered (ultrapure water, ultrapure water with sodium chloride, and simulated groundwater), matrix spike recoveries were greater than 93% and acceptable electrode slopes (−59.5 ± 0.2 mV) were obtained. Matrix spike recoveries and electrode slopes when persulfate or permanganate was added were 87 and 93%, and −58.4 ± 1.3 and −47.3 ± 2.2 mV, respectively. Therefore, quantifying F⁻ in matrices containing permanganate should involve use of either a matrix-matched calibration curve or the method of standard additions due to the low electrode slope. The addition of ascorbic acid as a quenching agent resulted in a decrease in matrix spike recoveries to <74% and suggests alternate quenching procedures should be used if an FSE is employed to measure F⁻. Removal of sediments by filtration prior to the addition of the fluoride spike led to improved matrix spike recoveries (>96%), which were otherwise underestimated using the FSE in the presence of sediments. While the FSE may be a quick and portable tool, its significant limitations need to be fully understood before it can be used to quantify the production of F⁻ resulting from the potential degradation of PFAS at field sites.     

An improved geomagnetic data selection algorithm for global geomagnetic field modelling

A spherical harmonic degrees 60, global internal field model is described (called BGS/G/L/0706). This model includes a degree 15 core and piecewise-linear secular variation model and is derived from quiet-time Ørsted and Champ satellite data sampled between 2001.0 and 2005.0. For the satellite data selection, a wide range of geomagnetic index and other data selection filters have been used to best isolate suitably quiet magnetospheric and ionospheric conditions. Only a relatively simple, degree one spherical harmonic, external field model is then required. It is found that a new 'Vector Magnetic Disturbance' index ( VMD ), the existing longitude sector A indices, the auroral zone index IE , and the polar cap index PC are better than Kp and Dst at rejecting rapidly varying external field signals at low, middle, auroral and polar latitudes. The model quality is further enhanced by filling spatial and temporal gaps in the quiet data selection with a second selection containing slightly more disturbed data. It is shown that VMD provides a better parametrization than Dst of the large-scale, rapidly changing, external field. The lithospheric field model between degrees 16 and 50 is robust and displays good coherence with other recently published models for this epoch. BGS/G/L/0706 also shows crustal anomalies consistent with other studies, although agreement is poorer in the southern polar cap. Intermodel coherency reduces above about degree 40, most likely due to incompletely filtered signals from polar ionospheric currents and auroral field aligned currents. The absence of the PC index for the southern hemisphere for 2003 onwards is a particular concern.     

Late Holocene Mediterranean coastal change along the Tiber Delta and Roman occupation of the Laurentine shore, central Italy

A line of Roman villas once dominated the Mediterranean coastline to the south of the Tiber river mouth near Ostia in central Italy. The Roman remains, which were constructed within a series of dune ridges, now lie up to 900 m from the current shoreline as a result of the continued evolution of the Tiber delta in response to postglacial sea level rise, sediment inputs from the Tiber river catchment and tectonic uplift. Infrared stimulated luminescence (IRSL) ages of potassium-rich feldspars extracted from dune sands are in good agreement with the independent age control provided by the Roman structures and allow us to hypothesise an increase in aggradation rates of five times since the end of the period of Roman occupation compared with the earlier Holocene.     

The path of NLK whistler-mode signals received at Wellington

VLF whistler-mode signals transmitted from NLK in Seattle and received at Wellington, New Zealand, were found to travel mainly along magnetic field lines near Wellington (L ~ 2.3) rather than those near Seattle (L ~ 3.0). This is found to be explicable in terms of the expected attenuation for the subionospheric part of the path together with the guiding to be expected from likely duct enhancements.