Geophysical investigation of the Colônia structure,Brazil

The origin of the nearly circular Colônia structure, located at the southwestern edge of the city of São Paulo, Brazil, has been the subject of a long‐standing debate, ever since the 1960s when the structure was first investigated by geophysical methods. The structure still raises interest for geological research, as its sedimentary infill holds important paleoclimatic information about the evolution of the tropical rainforest, as well as the interplay between the South American summer monsoon, the Intertropical Convergence Zone, and the southern Westerly wind belt—for possibly as long as several million years. In addition, the search for evidence to conclusively establish the origin of this structure continues, and the answer most likely lies in the lower portions of the basin's sedimentary infill, which also holds a significant potential for underground water resources. Here, we present the results from recent seismic (reflection and HVSR), gravimetric, and geoelectrical surveys. They have provided a reliable image of the sedimentary infill, and the maximum depth to basement within the structure has been constrained consistently by the different methods to approximately ?400 m. The geophysical data have also allowed to map the lateral contact between the crystalline basement rocks and the sedimentary infill, which indicates a diameter of approximately 2.8 km for the sedimentary basin, with 3.6 km being the diameter of the outermost limit of the structure. A total of six seismic stratigraphic boundaries were identified within the sedimentary infill, providing a framework for the planning of a deep drilling campaign and subsequent sampling program aimed at geological and paleoclimatology studies.     

Laboratory simulation of interplanetary ultraviolet radiation (broad spectrum) and its effects on Deinococcus radiodurans

The radiation-resistant bacterium Deinococcus radiodurans was exposed to a simulated interplanetary UV radiation at the Brazilian Synchrotron Light Laboratory (LNLS). Bacterial samples were irradiated on different substrates to investigate the influence of surface relief on cell survival. The effects of cell multi-layers were also investigated. The ratio of viable microorganisms remained virtually the same (average 2%) for integrated doses from 1.2 to 12 kJ m⁻², corresponding to 16 h of irradiation at most. The asymptotic profiles of the curves, clearly connected to a shielding effect provided by multi-layering cells on a cavitary substrate (carbon tape), means that the inactivation rate may not change significantly along extended periods of exposure to radiation. Such high survival rates reinforce the possibility of an interplanetary transfer of viable microbes.     

The first description and confirmation of the Vista Alegre impact structure in the Paraná flood basalts of southern Brazil

Abstract– The Vista Alegre structure, centered at 25°57′S and 52°41′W, has been recently proposed as a meteorite impact structure. The 9.5 km‐diameter structure is located in the Paraná state of southern Brazil, within the Paraná Basin, which contains one of the largest and most extensive flood basalt provinces on Earth. The Paraná flood basalts belong to the Serra Geral Formation and are temporally related to the opening of the South Atlantic Ocean, having been dated at about 133–132 Ma. Tholeiitic basalts dominate the western portion of Paraná state, with some minor rhyodacites. Morphologically, Vista Alegre has a prominent circular outline, in the form of an incomplete ring of escarpments, and an inner depression. The presence of a central uplift is not obvious, but it is inferred by the occurrence of deformed sandstone blocks near the center of the structure. These sandstones are possibly related to the Triassic Pirambóia Formation and/or to the Cretaceous Botucatu Formation. These units are normally at stratigraphic depths of about 700–800 m below the present surface in this portion of the Paraná Basin. The structure appears to be in an advanced erosion stage and its interior is occupied by a soil cover several meters thick, extensively used for agriculture. As a result there are limited outcrops in the interior of the structure, all of polymict breccias, some of them melt‐bearing. We report the extensive occurrence of shatter cones, in the form of fine‐grained rock clasts within the polymict breccias. The shatter cone‐bearing breccias occur at different locations within the structure, separated by several kilometers. The nested shatter cones range in size from about 0.5 to 20 cm for individual cones, and up to half a meter for complete assemblages. The shatter cones formed in fine‐grained Parana flood basalt and might be the first examples of shatter cones in such a rock type. In addition, planar deformation features (PDFs) were found in quartz grains within sedimentary rock clasts of the polymict breccia. These findings confirm the impact origin of the Vista Alegre structure.     

Water balance,nutrient and carbon export from a heath forest catchment in central Amazonia,Brazil

Carbon storage values in the Amazon basin have been studied through different approaches in the last decades in order to clarify whether the rainforest ecosystem is likely to act as a sink or source for carbon in the near future. This water balance, dissolved organic carbon (DOC) and nutrient export study were carried out in a micro‐scale heath forest (Campina) catchment in central Amazonia, Brazil. For a 1‐year study period (18 March 2007 until 19 March 2008), rainfall amounted to 3054 mm; of which, 1532 mm was evaporated by the forest (4.1 mm day^?1). Rainfall interception loss amounted to 15.6% of gross rainfall. Surface runoff amounted to 485 mm, whereas another 1071 mm was discharged as regional groundwater outflow. Accumulated DOC exports in surface runoff amounted to 15.3 g m^?2 year^?1, whereas the total carbon exported was 55.9 g m^?2. This is much higher than that observed for a nearby tall rainforest catchment in central Amazonia (DOC export < 20 g m^?2). As Campina heath forest areas cover a significant proportion of the Amazon Basin, these differences in ecosystem hydrological carbon exports should be taken into account in future studies assessing the carbon budget for the Amazon Basin. Macro‐nutrient exports were low, but those of calcium and potassium were higher than those observed for tall rainforest in the Amazon, which may be caused by a lower retention capacity of the heath forest ecosystem. Copyright © 2015 John Wiley & Sons, Ltd.     

Melting and cataclastic features in shatter cones in basalt from the Vista Alegre impact structure,Brazil

Shatter cones are one of the most widely recognized pieces of evidence for meteorite impact events on Earth, but the process responsible for their formation is still debated. Evidence of melting on shatter cone surfaces has been rarely reported in the literature from terrestrial impact craters but has been recently observed in impact experiments. Although several models for shatter cones formation have been proposed, so far, no one can explain all the observed features. Shatter cones' from the Vista Alegre impact structure, Brazil, formed in fine‐grained basalt of the Jurassic‐Cretaceous Serra Geral Formation (Paraná large igneous province). A continuous quenched melt film, consisting of a crystalline phase, mica, and amorphous material, decorates the striated surface. Ultracataclasites, containing subrounded pyroxene clasts in an ultrafine‐grained matrix, occur subparallel to the striated surface. Several techniques were applied to characterize the crystalline phase in the melt, including Raman spectroscopy and transmission electron microscopy. Results are not consistent with any known mineral, but they do suggest a possible rare or new type of clinopyroxene. This peculiar evidence of melting and cataclasis in relation with shatter cone surfaces is interpreted as the result of tensile fracturing at the tip of a fast propagating shock‐induced rupture, which led to the formation of shatter cones at the tail of the shock front, likely during the early stage of the impact events.     

Earthquake deformation in the northwestern Sierras Pampeanas of Argentina based on seismic waveform modelling

We investigate the seismic properties of modern crustal seismicity in the northwestern Sierras Pampeanas of the Andean retroarc region of Argentina. We modelled the complete regional seismic broadband waveforms of two crustal earthquakes that occurred in the Sierra de Velasco on 28 May 2002 and in the Sierra de Ambato on 7 September 2004. For each earthquake we obtained the seismic moment tensor inversion (SMTI) and tested for its focal depth. Our results indicate mainly thrust focal mechanism solutions of magnitudes M_w 5.8 and 6.2 and focal depths of 10 and 8 km, respectively. These results represent the larger seismicity and shallower focal depths in the last 100 years in this region. The SMTI 2002 and 2004 solutions are consistent with previous determinations for crustal seismicity in this region that also used seismic waveform modelling. Taken together, the results for crustal seismicity of magnitudes ≥5.0 in the last 30 years are consistent with an average P-axis horizontally oriented by an azimuth of 125° and T-axis orientation of azimuth 241° and plunge 58°. This modern crustal seismicity and the historical earthquakes are associated with two active reverse faulting systems of opposite vergences bounding the eastern margin of the Sierra de Velasco in the south and the southwestern margin of the Sierra de Ambato in the north. Strain recorded by focal mechanisms of the larger seismicity is very consistent over this region and is in good agreement with neotectonic activity during the last 11,000 years by Costa (2008) and Casa et al. (in press); this shows that the dominant deformation in this part of the Sierras Pampeanas is mainly controlled by contraction. Seismic deformation related to propagation of thrusts and long-lived shear zones of this area permit to disregard previous proposals, which suggested an extensional or sinistral regime for the geomorphic evolution since Pleistocene.     

High-pressure displacive phase transition of a natural Mg-rich pigeonite

A high-pressure single-crystal X-ray diffraction study has been carried out on a P2₁/c natural Mg-rich pigeonite sample with composition ca. Wo₆En₇₆Fs₁₈ using a diamond anvil-cell. The unit-cell parameters were determined at 14 different pressures to 7.14 GPa. The sudden disappearance of the b-type reflections (h + k = odd) and a strong discontinuity (about 2.8%) in the unit-cell volume indicated a first-order P2₁/c–C2/c phase transition between 4.66 and 4.88 GPa. The P(V) data of the P2₁/c phase were fitted to 4.66 GPa by a third-order Birch–Murnaghan equation of state (BM3 EoS), whereas the limited number of experimental data collected within the C2/c phase between 4.88 and 7.14 GPa were fitted using the same equation of state but with K′ constrained to the value obtained for the P2₁/c fitting. The equation of state coefficients are V ₀ = 424.66(6) ų, K _T0 = 104(2) GPa and K′ = 8(1) for the P2₁/c phase, and V ₀ = 423.6(1) ų, K _T0 = 112.4(8) GPa, and K′ fixed to 8(1) for the C2/c phase. The axial moduli for a, b, and c for the P2₁/c phase were obtained using also a BM3-EoS, while for the C2/c phase only a linear calculation could be performed, and therefore the same approach was applied for comparison also to the P2₁/c phase. In general the C2/c phase exhibits axial compressibilities (β _c > β _a >> β _b) lower than those of the P2₁/c phase (β _b > β _c ≈ β _a; similar to those found in previous studies in clinopyroxenes and orthopyroxenes). The lower compressibility of the C2/c phase compared with that of the P2₁/c could be ascribed to the greater stiffness along the b direction. A previously published relationship between P _c and M2 average cation radius (i.r.) has been updated using all the literature data on P2₁/c clinopyroxene containing large cations at M2 site and our new data. The following weighted regression was obtained: P _c (GPa) = 26(4) ? 28(5) ×  i.r (Å), R ² = 0.97. This improved equation can be used to predict the critical pressure of natural P2₁/c clinopyroxene samples just knowing the composition at M2 site.     

Pollution effects of the Tuy River on the central Venezuelan coast: Anthropogenic organic compounds and heavy metals in Tivela mactroidea

Bivalve samples were collected at seven sampling stations located between the town of Machurucuto and the Bay of Higuerote, Venezuela, covering approximately 70 km of coastline. Samples were collected both east and west of the Tuy River mouth, which has a plume known to move in a north-westerly direction. Petroleum hydrocarbons, both aliphatic (n-alkanes and UCM) and polyaromatic (PAHs), were detected and quantified in the samples. These hydrocarbons were found to be primarily derived from fossil fuels. Halogenated organics consisted mostly of polychlorinated biphenyls (PCBs) and some chlorinated pesticides, primarily of the DDT group. Heavy metals such as Pb, Cu, Ni, Zn, Cr and Cd were analysed in the samples. The results clearly show the influence of the Tuy River plume on the water quality of the coastal zone, particularly that located west of the river mouth. One sampling station, located just east of the river mouth, also showed significant influence from the river plume.     

The Platanar-Aguas Zarcas volcanic centers,Costa Rica: spatial-temporal association of Quaternary calc-alkaline and alkaline volcanism

The Platanar volcanic center is dominated by a calc-alkaline, basalt-andesite-dacite-rhyolite magma series with unusual LREE enrichment. Adjacent and overlapping the calc-alkaline rocks are the most alkaline basalts found along the volcanic front of Central America. These basalts are mafic, LIL- and LREE-enriched transitional to alkaline basalts. Several are found on the north flank of Platanar in the Aguas Zarcas region, where there are nine cinder cones and a few isolated flows. However, they are also found in isolated lava outcrops at least as far south as Porvenir volcano along the volcanic front. The addition of mafic alkaline magmas with high La/Yb and low Ba/La into the Platanar magma chamber or chambers may contribute to the LREE-enriched character of the Platanar basaltic andesites and andesites. At Platanar the field and geochemical evidence suggest mixing between calc-alkaline and alkaline magmas, a process that has probably occurred throughout the development of the Cordillera Central of Costa Rica. The presence of negative Ce anomalies in several of the calc-alkaline lavas also make the Platanar complex very unusual compared to the rest of the Central American volcanic front. In the center of the Platanar complex is the Chocosuela caldera, an apparent remnant of an avalanche caldera created by the collapse in the Middle Pleistocene of an ancestral stratovolcano toward the NNW in a directed blast-type eruption. Rhyolite is present as pumice lapilli in pyroclastic flow deposits outside the caldera rim. Whole lapilli analyses span the daciterhyolite range. The previous eruption of high silica tephra as pyroclastic flows, the current long dormant period and the repeated occurrence of earthquake swarms on the flanks of the Platanar complex make it a candidate for volcanic hazard mapping, detailed geological mapping and emergency planning.