Long term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions

Isotopic analysis of nitrate and sulfate minerals from the nitrate ore fields of the Atacama Desert in northern Chile has shown anomalous ¹⁷O enrichments in both minerals. Δ¹⁷O values of 14-21 ‰ in nitrate and 0.4 to 4 ‰ in sulfate are the most positive found in terrestrial minerals to date. Modeling of atmospheric processes indicates that the Δ¹⁷O signatures are the result of photochemical reactions in the troposphere and stratosphere. We conclude that the bulk of the nitrate, sulfate and other soluble salts in some parts of the Atacama Desert must be the result of atmospheric deposition of particles produced by gas to particle conversion, with minor but varying amounts from sea spray and local terrestrial sources. Flux calculations indicate that the major salt deposits could have accumulated from atmospheric deposition in a period of 200,000 to 2.0 M years during hyper-arid conditions similar to those currently found in the Atacama Desert. Correlations between Δ¹⁷O and δ¹⁸O in nitrate salts from the Atacama Desert and Mojave Desert, California, indicate varying fractions of microbial and photochemical end-member sources. The photochemical nitrate isotope signature is well preserved in the driest surficial environments that are almost lifeless, whereas the microbial nitrate isotope signature becomes dominant rapidly with increasing moisture, biologic activity, and nitrogen cycling. These isotopic signatures have important implications for paleoclimate, astrobiology, and N cycling studies.     

Velocity field in the spiral-wave pattern observed in rotating shallow-water experiments

The paper presents the first quantitative results of a laboratory study of the velocity field in a two-arm spiral-wave pattern generated in a steady-state fashion by a hydrodynamical instability in a differentially rotating, thin layer of liquid. The liquid layer has a free surface, and the rotational profile includes an interval where the velocity drops abruptly, as in the gaseous disks of spiral galaxies. The properties of anticyclonic vortices observed between the arms of this pattern at the corotation radius are considered.     

Feeding habits of harp and hooded seals in drift ice waters along the east coast of Greenland in summer and winter

Results of analyses of stomach and intestinal contents from hooded ( Cystophora cristata ) and harp ( Phoca groenlandica ) seals captured in the pack ice belt of the Greenland Sea in summer (July-August) in 2000 and winter (February-March) in 2001 revealed that the diet of both species were comprised of relatively few prey taxa. Pelagic amphipods of the genus Parathemisto , the squid Gonatus fabricii , polar cod ( Boreogadus saida ) and capelin ( Mallotus villosus ) constituted 63-99% of the observed diet biomass in both seal species, irrespective of sampling period, but their relative contribution to the diet varied both with species and sampling period/area. For hooded seals, G. fabricii and capelin were the dominant food items in winter 2001, but the summer 2000 diet comprised a mixture of this squid and polar cod. Parathemisto was most important for the harp seals during summer 2000; in winter 2001 the contribution from krill and capelin were comparable to that of Parathemisto . Multivariate analyses revealed differences in the intestinal contents of hooded and harp seals in areas where the two species' occurrence spatially overlapped. Different foraging depths of the two species may have contributed to the observed differences in diets.     

Rainfall thresholds for landsliding in the Himalayas of Nepal

Landsliding of the hillslope regolith is an important source of sediment to the fluvial network in the unglaciated portions of the Himalayas of Nepal. These landslides can produce abrupt increases of up to three orders of magnitude in the fluvial sediment load in less than a day. An analysis of 3 years of daily sediment load and daily rainfall data defines a relationship between monsoonal rainfall and the triggering of landslides in the Annapurna region of Nepal. Two distinct rainfall thresholds, a seasonal accumulation and a daily total, must be overcome before landslides are initiated. To explore the geomorphological controls on these thresholds, we develop a slope stability model, driven by daily rainfall data, which accounts for changes in regolith moisture. The pattern of rainfall thresholds predicted by the model is similar to the field data, including the decrease in the daily rainfall threshold as the seasonal rainfall accumulation increases. Results from the model suggest that, for a given hillslope, regolith thickness determines the seasonal rainfall necessary for failure, whereas slope angle controls the daily rainfall required for failure.     

Apparent and real bias in numerical transfer functions in palaeolimnology

We present an evaluation of the procedure by which model prediction bias is examined in palaeolimnological transfer function inference models. We argue that most of the prediction biases commonly reported in the literature are, in fact, fallacious, and are the artificial consequence of the inappropriate manner in which residuals are traditionally examined. We show that the extent of the specious model bias is entirely predictable from first principles and is essentially determined by the strength of the predictive model. We suggest that the analysis of residuals should always be examined as a function of the model's predictions and we discuss the implications of the old and new approaches.