Revised 14C dating of ice wedge growth in interior Alaska (USA) to MIS 2 reveals cold paleoclimate and carbon recycling in ancient permafrost terrain

Establishing firm radiocarbon chronologies for Quaternary permafrost sequences remains a challenge because of the persistence of old carbon in younger deposits. To investigate carbon dynamics and establish ice wedge formation ages in Interior Alaska, we dated a late Pleistocene ice wedge, formerly assigned to Marine Isotope Stage (MIS) 3, and host sediments near Fairbanks, Alaska, with 24 radiocarbon analyses on wood, particulate organic carbon (POC), air-bubble CO₂, and dissolved organic carbon (DOC). Our new CO₂ and DOC ages are up to 11,170 yr younger than ice wedge POC ages, indicating that POC is detrital in origin. We conclude an ice wedge formation age between 28 and 22 cal ka BP during cold stadial conditions of MIS 2 and solar insolation minimum, possibly associated with Heinrich event 2 or the last glacial maximum. A DOC age for an ice lens in a thaw unconformity above the ice wedge returned a maximum age of 21,470 ± 200 cal yr BP. Our variable ¹⁴C data indicate recycling of older carbon in ancient permafrost terrain, resulting in radiocarbon ages significantly older than the period of ice-wedge activity. Release of ancient carbon with climatic warming will therefore affect the global ¹⁴C budget.     

Provenance of chalk tesserae from Brading Roman Villa, Isle of Wight, UK

Thin section petrographical analysis of chalk tesserae at Brading Roman Villa, Isle of Wight, England, identifies a range of planktonic foraminifera and the calcareous algal cyst Pithonella that identify the Late Cenomanian Rotalipora cushmani Biozone (BGS Foraminiferal Biozones 4iii to 7). The local chalk crop to the north of the villa includes rocks of R. cushmani Biozone age, and indicates a likely local, rather than long distance, source for the tesserae. Microfossils provide a powerful tool for identifying the provenance of artefacts in Roman Britain.     

Hydroxyl stretching in phyllosilicates at high pressures and temperatures: an infrared spectroscopic study

The hydroxyl stretching frequencies of four phyllosilicates have been measured at high pressures and temperatures using an externally heated diamond-anvil cell and synchrotron infrared spectroscopy. Spectra were measured up to 26, 31, 21 and 8 GPa at room temperature for samples of talc, pyrophyllite, muscovite and 10-Å phase, respectively. Spectra were also measured in the range 273–500 K at ambient pressure for all samples and at 8–9 GPa for talc and pyrophyllite. The frequency of the Mg₃OH band in talc increases with pressure due to the absence of hydrogen bonding. The different orientation of the hydroxyl group in pyrophyllite and muscovite leads to hydrogen bonding and a decrease in the frequency of the Al₂OH band with pressure. 10-Å phase is approximately equivalent to talc with the addition of interlayer H₂O. In a spectrum of a sample synthesised for 143 h, two hydroxyl stretching bands are clearly resolved on compression. One is the same as the Mg₃OH band in talc, indicating the presence of intra-layer hydroxyl in a talc-like environment with no hydrogen bonding. The other, which separates from the talc-like band at 1 GPa, is associated with intra-layer hydroxyl that is hydrogen bonded to interlayer H₂O. There are equivalent bands in high-pressure spectra of a sample of deuterated 10-Å phase, synthesised for 400 h. This sample shows a greater extent of hydrogen bonding at ambient pressure than the 143 h sample. For all of the phases studied, increasing temperature leads to a decrease in frequency for every hydroxyl stretching vibration, both at low and high pressures. The shifts in frequency with temperature are an order of magnitude greater than the shifts with pressure when normalised to previously measured structural parameters.     

Cues,Not an Endogenous Rhythm,Control the Dusk Peak in Water-Column Entry by Benthic Copepods

Individuals of some benthic species swim out of or away from the sediment surface into the water column, i.e., they emerge. Individuals of both emergent and nonemergent benthic species can be entrained by near-bottom flows. Both emergence and entrainment are of interest, e.g., for their roles in benthopelagic coupling, but the controlling factors are poorly understood. Our experiments with benthic copepods from contrasting environments showed that a factor (or factors) associated with the onset of darkness, rather than an endogenous rhythm, controls their dusk emergence. In addition, we argue that entrainment and emergence can interact in at least two ways: (1) Light-induced changes in oxygenation of the sediment pore water may affect the entrainment flux of benthic copepods and (2) if large numbers of individuals are entrained in the time leading up to sunset, few will remain in the sediment to be part of the dusk peak in emergence.     

Origin of Tertiary to Recent EM- and subduction-like chemical and isotopic signatures in Auca Mahuida region (37°–38°S) and other Patagonian plateau lavas

The alkaline volcanic rocks of the 1.8–0.9 Ma Auca Mahuida and post-mid-Pliocene Rio Colorado backarc volcanic fields east of the Andean Southern Volcanic Zone at ~37°–38°S have pronounced intraplate-like chemical signatures with some striking similarities to oceanic DM-EM1-like lavas of the south Atlantic Tristan da Cunha type. These backarc lavas are considered to have formed as a series of mantle batches typified by 4–7 % melting, with decompression melting initiating in a garnet-bearing mantle above a steepening subduction zone, and final equilibration occurring near the base of a ~65- to 70-km-thick lithosphere at temperatures of ~1,350–1,380 °C. Evolved Auca Mahuida mugearite to trachytic samples are best explained by crystal fractionation with limited mixing of partial melts of recently underplated basalts, in line with isotopic signatures that preclude significant radiogenic contamination in a preexisting refractory crust. Higher Ba/La and subtly higher La/Ta ratios than in nearby ~24–20 Ma primitive basalts or oceanic (OIB) lavas are attributed to the residual effects of slab fluids introduced during a shallow subduction episode recorded in the arc-like chemistry of the adjacent 7–4 Ma Chachahuén volcanic complex. Positive Sr, K and Ba spikes on mantle-normalized patterns of both primitive Auca Mahuida and ~24–20 Ma basalts, like those in EM-like OIB basalts, are attributed to mixing of continental lithosphere into the asthenosphere. In Patagonia, this mixing is suggested to have peaked as the South America continent accommodated to major late Oligocene plate convergence changes, as similar Sr, K and Ba spikes and DM-EM1 signatures are absent in ~50–30 Ma backarc lavas north of 51°S, and all of those south of 51°S. Introduction of an EM1-like component associated with lateral mantle flow of a Tristan da Cunha source is largely precluded by its Cretaceous age and distance to Patagonia.     

Carbonatite metasomatized peridotite xenoliths from southern Patagonia: implications for lithospheric processes and Neogene plateau magmatism

The mineral chemistry, major and trace element, and Sr–Nd isotopic composition of Cr-diopside, spinel peridotite xenoliths from the Estancia Lote 17 locality in southern Patagonia document a strong carbonatitic metasomatism of the backarc continental lithosphere. The Lote 17 peridotite xenolith suite consists of hydrous spinel lherzolite, wehrlite, and olivine websterite, and anhydrous harzburgite and lherzolite. Two-pyroxene thermometry indicates equilibration temperatures ranging from 870 to 1015 °C and the lack of plagioclase or garnet suggests the xenoliths originated from between ˜40 and 60 km depth. All of the xenoliths are LILE- and LREE-enriched, but have relatively low ⁸⁷Sr/⁸⁶Sr (0.70294 to 0.70342) and high ɛ_Nd (+3.0 to +6.6), indicating recent trace element enrichment (∼25 Ma, based on the low ⁸⁷Sr/⁸⁶Sr and high Rb concentrations of phlogopite separates) in the long-term, melt-depleted Patagonian lithosphere. Lote 17 peridotite xenoliths are divided into two basic groups. Group 1 xenoliths consist of fertile peridotites that contain hydrous phases (amphibole ± phlogopite ± apatite). Group 1 xenoliths are further subdivided into three groups (a, b, and c) based on distinctive textures and whole-rock chemistry. Group 1 xenolith mineralogy and chemistry are consistent with a complex metasomatic history involving variable extents of recent carbonatite metasomatism (high Ca/Al, Nb/La, Zr/Hf, low Ti/Eu) that has overprinted earlier metasomatic events. Group 2 xenoliths consist of infertile, anhydrous harzburgites and record cryptic metasomatism that is attributed to CO₂-rich fluids liberated from Group 1 carbonatite metasomatic reactions. Extremely variable incompatible trace element ratios and depleted Sr–Nd isotopic compositions of Lote 17 peridotite xenoliths indicate that the continental lithosphere was neither the primary source nor an enriched lithospheric contaminant for Neogene Patagonian plateau lavas. Neogene plateau magmatism associated with formation of asthenospheric slab windows may have triggered this occurrence of “intraplate-type” carbonatite metasomatism in an active continental backarc setting. Received: 26 January 2000 / Accepted: 1 March 2000     

A semianalytical approach for solving first-order perturbation equations of dissolution-timescale reactive infiltration instability problems in fluid-saturated rocks

This paper presents a semianalytical approach for solving first-order perturbation (FOP) equations, which are used to describe dissolution-timescale reactive infiltration instability (RII) problems in fluid-saturated rocks. The proposed approach contains two parts because the chemical dissolution reaction divides the whole problem domain into two subdomains. In the first part, the interface-condition substitution strategy is used to derive the analytical expressions of purely mathematical solutions for the FOP equations in the upstream subdomain, where the dissolution chemical reaction is ceased and the FOP equations are weakly coupled. In the second part, the finite element method (FEM) is used to derive the analytical expressions of numerical solutions for the FOP equations in the downstream subdomain, where the dissolution chemical reaction needs to be considered and the FOP equations are strongly coupled so that it is impossible to derive purely mathematical solutions for them. Particular attention is paid to the development of the element-by-element forward marching strategy, which is associated with the use of the FEM for solving this new kind of scientific problem. The related analytical results demonstrated that (1) both the dynamic characteristic of a reactive infiltration system and the dimensionless wavenumber can have pronounced influences on the distribution of the FOP dimensionless acid concentration within the entire domain of the dissolution-timescale RII problems in fluid-saturated rocks and (2) the FOP dimensionless acid concentration distribution exhibits two significantly different patterns in the upstream and downstream subdomains of the dissolution-timescale RII system.     

Fault zone hydrogeology in arid environments: The origin of cold springs in the Wadi Araba Basin,Egypt

The role of faults in controlling groundwater flow in the Sahara and most of the hyper-arid deserts is poorly understood due to scarcity of hydrological data. The Wadi Araba Basin (WAB), in the Eastern Sahara, is highly affected by folds and faults associated with Senonian tectonics and Paleogene rifting. Using the WAB as a test site, satellite imagery, aeromagnetic maps, field observations, isotopic and geochemical data were examined to unravel the structural control on groundwater flow dynamics in the Sahara. Analysis of satellite imagery indicated that springs occur along structurally controlled scarps. Isotopic data suggested that cold springs in the WAB showed a striking similarity with the Sinai Nubian aquifer system (NAS) water and the thermal springs along the Gulf of Suez (e.g., δ¹⁸O = −8.01‰ to −5.24‰ and δD = −53.09‰ to −31.12‰) demonstrating similar recharge sources. The findings advocated that cold springs in the WAB represent a natural discharge from a previously undefined aquifer in the Eastern Desert of Egypt rather than infiltrated precipitation over the plateaus surrounding the WAB or through hydrologic windows from deep crystalline basement flow. A complex role of the geological structures was inferred including: (1) channelling of the groundwater flow along low-angle faults, (2) compartmentalization of the groundwater flow upslope from high-angle faults, and (3) reduction of the depth to the main aquifer in a breached anticline setting, which resulted in cold spring discharge temperatures (13–22°C). Our findings emphasize on the complex role of faults and folds in controlling groundwater flow, which should be taken into consideration in future examination of aquifer response to climate variability in the Sahara and similar deserts worldwide.     

Using GIS-based distributed soil loss modeling and morphometric analysis to prioritize watershed for soil conservation in Bago river basin of Lower Myanmar

Bago River is an important river in Myanmar. Although shorter than other rivers, it has its own river system, and people along the river rely heavily on it for their daily lives. The upper part of the watershed has changed rapidly from closed forest to open forest land in the 1990s. Since the recent degradation of the forest environment, annual flooding has become worse during the rainy season in Bago City. This paper aims at determining soil conservation prioritization of watershed based on soil loss due to erosion and morphometric analysis in the Bago Watershed by integrating remote sensing and geographic information system (GIS) techniques. In this study, soil erosion of the Bago watershed was determined using the Universal Soil Loss Equation. Such factormaps as rainfall, soil erodibility, slope length gradient, and crop management were compiled as input parameters for the modeling; and the soil loss from 26 sub-watersheds were estimated. Then, the soil erosion maps of the Bago watershed for 2005 were developed. The resulting Soil Loss Tolerance Map could be utilized in developing watershed management planning, forestry management planning, etc.