Heterogeneous distribution of H2O in the Martian interior: Implications for the abundance of H2O in depleted and enriched mantle sources

We conducted a petrologic study of apatite within 12 Martian meteorites, including 11 shergottites and one basaltic regolith breccia. These data were combined with previously published data to gain a better understanding of the abundance and distribution of volatiles in the Martian interior. Apatites in individual Martian meteorites span a wide range of compositions, indicating they did not form by equilibrium crystallization. In fact, the intrasample variation in apatite is best described by either fractional crystallization or crustal contamination with a Cl‐rich crustal component. We determined that most Martian meteorites investigated here have been affected by crustal contamination and hence cannot be used to estimate volatile abundances of the Martian mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite source has 36–73 ppm H₂O and the depleted source has 14–23 ppm H₂O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the Martian mantle. We also estimated the H₂O, Cl, and F content of the Martian crust using known crust‐mantle distributions for incompatible lithophile elements. We determined that the bulk Martian crust has ~1410 ppm H₂O, 450 ppm Cl, and 106 ppm F, and Cl and H₂O are preferentially distributed toward the Martian surface. The estimate of crustal H₂O results in a global equivalent surface layer (GEL) of ~229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface.     

Central Mediterranean tephrochronology between 313 and 366 ka: New insights from the Fucino palaeolake sediment succession

Thirty-two tephra layers were identified in the time-interval 313–366 ka (Marine Isotope Stages 9–10) of the Quaternary lacustrine succession of the Fucino Basin, central Italy. Twenty-seven of these tephra layers yielded suitable geochemical material to explore their volcanic origins. Investigations also included the acquisition of geochemical data of some relevant, chronologically compatible proximal units from Italian volcanoes. The record contains tephra from some well-known eruptions and eruptive sequences of Roman and Roccamonfina volcanoes, such as the Magliano Romano Plinian Fall, the Orvieto–Bagnoregio Ignimbrite, the Lower White Trachytic Tuff and the Brown Leucitic Tuff. In addition, the record documents eruptions currently undescribed in proximal (i.e. near-vent) sections, suggesting a more complex history of the major eruptions of the Colli Albani, Sabatini, Vulsini and Roccamonfina volcanoes between 313 and 366 ka. Six of the investigated tephra layers were directly dated by single-crystal-fusion ⁴⁰Ar/³⁹Ar dating, providing the basis for a Bayesian age–depth model and a reassessment of the chronologies for both already known and dated eruptive units and for so far undated eruptions. The results provide a significant contribution for improving knowledge on the peri-Tyrrhenian explosive activity as well as for extending the Mediterranean tephrostratigraphical framework, which was previously based on limited proximal and distal archives for that time interval.     

Local Extremes in the Lidar‐Derived Snow Cover of Alpine Glaciers

Snow deposition and redistribution are major drivers of snow cover dynamics in mountainous terrain and contribute to the mass balance of alpine glaciers. The quantitative understanding of inhomogeneous snow distribution in mountains has recently benefited from advances in measuring technologies, such as airborne laser scanning (ALS). This contribution further advances the quantitative understanding of snow distribution by analysing the areas of maximum surface elevation changes in a mountain catchment with large and small glaciers. Using multi‐annual ALS observations, we found extreme surface elevation changes on rather thin borders along the glacier margins. While snow depth distribution patterns in less extreme terrain have presented high inter‐annual persistence, there is little persistence of those extreme glacier accumulations between winters. We therefore interpret the lack of persistence as the result of a predominance of gravity‐driven redistribution, which has an inherently higher random component because it does not occur with all conditions in all winters. In highly crevassed zones, the lidar‐derived surface elevation changes are caused by a complex interaction of ice flux divergence, the propagation of crevasses and snow accumulation. In general, the relative contribution of gravitational mass transport to glacier snow cover volume was found to decrease for glaciers larger than 5 km² in the investigated region. We therefore suggest that extreme accumulations caused by gravitational snow transport play a significant role in the glacier mass balance of small to medium‐size glaciers and that they may be successfully parameterized by simple mass redistribution algorithms, which have been presented in the literature.     

Occurrence and turnover of DMSP and DMS in deep waters of the Ross Sea,Antarctica

High concentrations of the phytoplankton metabolite dimethylsulfoniopropionate (DMSP) and its degradation product dimethylsulfide (DMS) are associated with blooms of Phaeocystis antarctica in the Ross Sea, Antarctica. Episodic and rapid vertical export of Phaeocystis biomass to deep water has been reported for the Ross Sea, therefore we examined the distribution and microbial consumption rates of DMSP and DMS throughout the sub-euphotic water column. Total DMSP (dissolved+particulate; DMSPt) was present at 0.5–22 nM at depths between 70 and 690 m during both the early bloom (November) and the late bloom (January). Sub-euphotic peaks of DMSP were sometimes associated with mid-water temperature maxima, and elevated DMSP below 70 m was found mainly in water masses characterized as Modified Circumpolar Deep Water or Antarctic Shelf Water. Overall, 50–94% of the integrated water-column DMSPt was found below the euphotic zone. At one station during the early bloom, local maxima of DMSPt (14 nM) and DMS (20 nM) were observed between 113 and 240 m and these maxima corresponded with high chlorophyll a concentrations, P. antarctica cell numbers, and Fv/Fm (the quantum yield of photosystem II). During the late bloom, a sub-euphotic maximum of DMSPt (15.8 nM) at 250 m cooccurred with peaks of chlorophyll a concentration, DMSP lyase activity, bacterial production and dissolved DMSP consumption rates. DMSP turnover contributed ～12% of the bacterial carbon demand between 200 and 400 m. DMS concentrations peaked at 286 m but the maximum concentration (0.42 nM) was far lower than observed during the early bloom, probably because of relatively rapid biological consumption of DMS (1–3 turnovers per day) which, in turn, contributed to elevated dissolved dimethylsulfoxide (DMSO) concentrations. Relatively stable DMSPt distributions at some sites suggest that rapid sinking of Phaeocystis biomass is probably not the major mechanism responsible for mesopelagic DMSP accumulations. Rather, subduction of near-surface water masses, lateral advective transport or trapping of slowly sinking P. antarctica biomass in intermediate water masses are more likely mechanisms. We found that a culture of P. antarctica maintained cellular integrity during 34 days of darkness, therefore the presence of intact cells (and DMSP) at depth can be explained even under a slow sinking/advection scenario. Whatever the mechanism, the large pools of DMSP and DMS below the euphotic zone suggest that export exerts a control on potential DMS emission from the surface waters of the Ross Sea.     

Volume transport in the Soya Strait during 2006–2008

Time-series data of the vertical structure of the Soya Warm Current (SWC) were obtained by a bottom-mounted acoustic Doppler current profiler (ADCP) in the middle of the Soya Strait from September 2006 to July 2008. The site of the ADCP measurement was within the coverage of the ocean-radar measurement around the strait. The volume transport of the SWC through the strait is estimated on the basis of both the vertical structure observed by the ADCP and the horizontal structure observed by the radars for the first time. The annual transport estimates are 0.62–0.67 Sv (1 Sv = 10⁶ m³s⁻¹). They are somewhat smaller than the difference between the previous estimates of the inflow and outflow through other straits in the Sea of Japan, and smaller than those obtained in the region downstream of the strait during 2004–05 (0.94–1.04 Sv). The difference in the two periods may be attributed to interannual variability of the SWC and/or the different measurement locations.     

Past,present and future nutrient loads of the North Sea: Causes and consequences

Comprehensive, aggregate nutrient budgets were established for two compartments of the North Sea, the shallow coastal and deeper open regions, and for three different periods, representing pre-eutrophication (∼1950), eutrophication (∼1990) and contemporary (∼2000) phases. The aim was to quantify the major budget components, to identify their sources of variability, to specify the anthropogenic components, and to draw implications for past and future policy. For all three periods, open North Sea budgets were dominated (75%) by fluxes from and to the North-East Atlantic; sediment exchange was of secondary importance (18%). For the coastal North Sea, fluxes during the eutrophication period were dominated by sediment exchange (49% of all inputs), followed by exchange with the open sea (21%), and anthropogenic inputs (19%). Between 1950 and 1990, N-loading of coastal waters increased by a factor of 1.62 and P-loading by 1.45. These loads declined after 1990. Interannual variability in Atlantic inflow was found to correspond to a variability of 11% in nutrient load to the open North Sea. Area-specific external loads of both the open and coastal North Sea were below Vollenweider-type critical loads when expressed relative to depth and flushing. External area-specific load of the coastal North Sea has declined since 1990 from 1.8 to about 1.4 g P m⁻² y⁻¹ in 2000, which is close to the estimate of 1.3 for 1950. N-load declined less, leading to an increase in N/P ratio.     

Modern and historical tropical cyclone and tsunami deposits at the coast of Myanmar: Implications for their identification and preservation in the geological record

The catastrophic storm surge of tropical cyclone Nargis in May 2008 demonstrated Myanmar's exposure to coastal flooding. The investigation of sediments left by tropical cyclone Nargis and its predecessors is an important contribution to prepare for the impact of future tropical cyclones and tsunamis in the region, because they may extend the database for long-term hazard assessment beyond the relatively short instrumental and historical record. This study, for the first time, presents deposits of modern and historical tropical cyclones and tsunamis from the coast of Myanmar. The aim is to establish regional sedimentary characteristics that may help to identify and discriminate cyclones and tsunamis in the geological record, and to document post-depositional changes due to tropical weathering in the first years after deposition. These findings if used to interpret older deposits will extend the existing instrumental record of flooding events in Myanmar. Evaluating deposits that can be related to specific events, such as the 2006 tropical cyclone Mala and the 2004 Indian Ocean tsunami, indicates similar sedimentary characteristics for both types of sediments. Landward thinning and fining trends, littoral sediment sources and sharp lower contacts allow for the differentiation from underlying deposits, while discrimination between tropical cyclone and tsunami origin is challenging based on the applied methods. The modern analogues also demonstrate a rather low preservation potential of the sand sheets due to carbonate dissolution, formation of organic top soils, and coastal erosion. However, in coastal depressions sand sheets of sufficient thickness (>10 cm) may be preserved where the shoreline is prograding or stable. In the most seaward swale of a beach-ridge plain at the Rakhine coast, two sand sheets have been identified in addition to the deposits of 2006 tropical cyclone Mala. Based on a combination of optically stimulated luminescence, radiocarbon and ¹³⁷Cs dating, the younger sand layer is related to 1982 tropical cyclone Gwa, while the older sand layer is most probably the result of an event that took place prior to 1950. Comparison with historical records indicates that the archive is only sensitive to tropical cyclones of category 4 (or higher) with landfall directly in or a few tens of kilometres north of the study area. While the presented tropical cyclone records are restricted to the last 100 years, optically stimulated luminescence ages of the beach ridges indicate that the swales landward of the one investigated in this study might provide tropical cyclone information for at least the past 700 years.     

Variable Tl,Pb, and Cd concentrations and isotope compositions of enstatite and ordinary chondrites—Evidence for volatile element mobilization and decay of extinct 205Pb

New Tl, Pb, and Cd concentration and Tl, Pb isotope data are presented for enstatite as well as L- and LL-type ordinary chondrites, with additional Cd stable isotope results for the former. All three chondrite suites have Tl and Cd contents that vary by more than 1–2 orders of magnitude but Pb concentrations are more uniform, as a result of terrestrial Pb contamination. Model calculations based on Pb isotope compositions indicate that for more than half of the samples, more than 50% of the measured Pb contents are due to addition of modern terrestrial Pb. In part, this is responsible for the relatively young and imprecise Pb-Pb ages determined for EH, L, and LL chondrites, which are hence only of limited chronological utility. In contrast, four particularly pristine EL chondrites define a precise Pb-Pb cooling age of 4559 ± 6 Ma. The enstatite chondrites (ECs) have highly variable ε^114/110Cd of between about +3 and +70 due to stable isotope fractionation from thermal and shock metamorphism. Furthermore, nearly all enstatite meteorites display ε²⁰⁵Tl values from −3.3 to +0.8, while a single anomalous sample is highly fractionated in both Tl and Cd isotopes. The majority of the ECs thereby define a correlation of ε²⁰⁵Tl with ε^114/110Cd, which suggests that at least some of the Tl isotope variability reflects stable isotope fractionation rather than radiogenic ingrowth of ²⁰⁵Tl from ²⁰⁵Pb decay. Considering L chondrites, most ε²⁰⁵Tl values range between −4 and +1, while two outliers with ε²⁰⁵Tl ≤ −10 are indicative of stable isotope fractionation. Considering only those L chondrites which are least likely to feature Pb contamination or stable Tl isotope effects, the results are in accord with the former presence of live ²⁰⁵Pb on the parent body, with an initial ²⁰⁵Pb/²⁰⁴Pb = (1.5 ± 1.4) × 10⁻⁴, which suggests late equilibration of the Pb-Tl system 26–113 Ma after carbonaceous chondrites (CCs). The LL chondrites display highly variable ε²⁰⁵Tl values from −12.5 to +14.9, also indicative of stable isotope effects. However, the data for three pristine LL3/LL4 chondrites display an excellent correlation between ε²⁰⁵Tl and ²⁰⁴Pb/²⁰³Tl. This defines an initial ²⁰⁵Pb/²⁰⁴Pb of (1.4 ± 0.3) × 10⁻⁴, equivalent to a ²⁰⁵Pb-²⁰⁵Tl cooling age of 55 + 12/−24 Ma (31–67 Ma) after CCs.     

Diversity and burglary: Do community differences matter?

Diversity within a population has been linked to levels of both social cohesion and crime. Neighborhood crimes are the result of a complex set of factors, one of which is weak community cohesion. This article seeks to explore the impacts of diversity on burglary crime in a range of neighborhoods, using Leeds, UK as a case study. We propose a new approach to quantifying the correlates of burglary in urban areas through the use of diversity metrics. This approach is useful in unveiling the relationship between burglary and diversity in urban communities. Specifically, we employ stepwise multiple regression models to quantify the relationships between a number of neighborhood diversity variables and burglary crime rates. The results of the analyses show that the variables that represent diversity were more significant when regressed against burglary crime rates than standard socio‐demographic data traditionally used in crime studies, which do not generally use diversity variables. The findings of this study highlight the importance of neighborhood cohesion in the crime system, and the key place for diversity statistics in quantifying the relationships between neighborhood diversities and burglary. The study highlights the importance of policy planning aimed at encouraging community building in promoting neighborhood safety.