The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times). 相似文献
The relativistic Sunyaev–Zel'dovich (SZ) effect offers a method, independent of X-ray, for measuring the temperature of the intracluster medium (ICM) in the hottest systems. Here, using N -body/hydrodynamic simulations of three galaxy clusters, we compare the two quantities for a non-radiative ICM, and for one that is subject both to radiative cooling and to strong energy feedback from galaxies. Our study has yielded two interesting results. First, in all cases, the SZ temperature is hotter than the X-ray temperature and is within 10 per cent of the virial temperature of the cluster. Secondly, the mean SZ temperature is less affected by cooling and feedback than the X-ray temperature. Both these results can be explained by the SZ temperature being less sensitive to the distribution of cool gas associated with cluster substructure. A comparison of the SZ and X-ray temperatures (measured for a sample of hot clusters) would therefore yield interesting constraints on the thermodynamic structure of the intracluster gas. 相似文献
Regional governance to address climate change is being constituted in New Zealand through domestic policy measures and international discourses. We examine climate change responses in two regions: Marlborough and Waikato. Informants expressed a desire for more transparent government policy; that planning for climate change makes good business sense for farmers and other businesses; that technology is sought to increase productivity and decrease environmental impact; and research networks build capacity for local action, linking sectors and organisations. Often conflicting, these responses to climate change were informed by a mix of discourses shaping New Zealand, including participatory democracy, the knowledge economy and sustainable development. 相似文献
AbstractThe Okavango River system flows through Angola, Namibia and Botswana. It is in near-natural condition and supports globally iconic wetlands and wildlife. The basin’s people are poor and development is inevitable: the next decade is critical. The river could become an example of responsible planning that resolutely addresses the three pillars of sustainable development. Recognizing this, the Member States completed a transboundary diagnostic analysis (TDA) in 2010 funded by the three governments and the Global Environment Facility. A central feature of the TDA was a basin-wide environmental flow assessment using the DRIFT (Downstream Response to Imposed Flow Transformation) holistic approach. This produced scenarios of increasing water resource use that spelled out the costs and benefits in terms of the health of the river ecosystem, associated social structures and local and national economies. The results were used to help create a transboundary strategic action programme, which the Member States are now beginning to act on. This article describes the DRIFT application, the findings and how these could be used to help achieve sustainable development.
Editor D. Koutsoyiannis; Guest editor M. AcremanCitation King, J., Beuster, H., Brown, C., and Joubert, A., 2014. Pro-active management: the role of environmental flows in transboundary cooperative planning for the Okavango River system. Hydrological Sciences Journal, 59 (3–4), 786–800. 相似文献
Halogens show a range from moderate (F) to highly (Cl, Br, I) volatile and incompatible behavior, which makes them excellent tracers for volatile transport processes in the Earth’s mantle. Experimentally determined fluorine and chlorine partitioning data between mantle minerals and silicate melt enable us to estimate Mid Ocean Ridge Basalt (MORB) and Ocean Island Basalt (OIB) source region concentrations for these elements. This study investigates the effect of varying small amounts of water on the fluorine and chlorine partitioning behavior at 1280?°C and 0.3 GPa between olivine and silicate melt in the Fe-free CMAS+F–Cl–Br–I–H2O model system. Results show that, within the uncertainty of the analyses, water has no effect on the chlorine partitioning behavior for bulk water contents ranging from 0.03 (2) wt% H2O (DClol/melt = 1.6?±?0.9 × 10?4) to 0.33 (6) wt% H2O (DClol/melt = 2.2?±?1.1 × 10?4). Consequently, with the effect of pressure being negligible in the uppermost mantle (Joachim et al. Chem Geol 416:65–78, 2015), temperature is the only parameter that needs to be considered for the determination of chlorine partition coefficients between olivine and melt at least in the simplified iron-free CMAS+F–Cl–Br–I–H2O system. In contrast, the fluorine partition coefficient increases linearly in this range and may be described at 1280?°C and 0.3 GPa with (R2?=?0.99): \(D_{F}^{\text{ol/melt}}\ =\ 3.6\pm 0.4\ \times \ {{10}^{-3}}\ \times \ {{X}_{{{\text{H}}_{\text{2}}}\text{O}}}\left( \text{wt }\!\!\%\!\!\text{ } \right)\ +\ 6\ \pm \ 0.4\times \,{{10}^{-4}}\). The observed fluorine partitioning behavior supports the theory suggested by Crépisson et al. (Earth Planet Sci Lett 390:287–295, 2014) that fluorine and water are incorporated as clumped OH/F defects in the olivine structure. Results of this study further suggest that fluorine concentration estimates in OIB source regions are at least 10% lower than previously expected (Joachim et al. Chem Geol 416:65–78, 2015), implying that consideration of the effect of water on the fluorine partitioning behavior between Earth’s mantle minerals and silicate melt is vital for a correct estimation of fluorine abundances in OIB source regions. Estimates for MORB source fluorine concentrations as well as chlorine abundances in both mantle source regions are within uncertainty not affected by the presence of water. 相似文献
Since the 1960s, an early explosive activity in the Mont-Dore Massif is associated with a major pyroclastic rhyolitic eruption (5–7 km3) known as the “Grande Nappe” (GN). This event, linked to the formation of a 6-km-diameter cryptic caldera named “Haute Dordogne”, was before our investigation dated by 40Ar/39Ar at 3.07 ± 0.04 Ma. Our new single-crystal laser fusion 40Ar/39Ar dates obtained on two outcrops of the GN (Rochefort-Montagne and Ludières) questioned several hypotheses made concerning this “landmark” event of the Mont-Dore Massif history. We demonstrate that: (1) the GN rhyolitic eruption has occurred much later than previously estimated (i.e. 2.77 ± 0.02–0.07 Ma full external uncertainties); (2) the correlation made between the Vendeix rhyolitic complexes (intra-caldera position) dated back to 2.74 ± 0.04 Ma and the GN is proposed; (3) xenocryst contamination could be very high (i.e. 70% for the Rochefort-Montagne GN outcrop) and explains the noticeable older age obtained previously; (4) a link between the GN eruption and the formation of a caldera is questionable; the hypothesis of a northward-oriented blast channeled eastward toward the paleo-Allier River is thus proposed. 相似文献
Heating heavy oil reservoirs is a common method for reducing the high viscosity of heavy oil and thus increasing the recovery factor. Monitoring of these viscosity changes in the reservoir is essential for delineating the heated region and controlling production. In this study, we present an approach for estimating viscosity changes in a heavy oil reservoir. The approach consists of three steps: measuring seismic wave attenuation between reflections from above and below the reservoir, constructing time‐lapse Q and Q?1 factor maps, and interpreting these maps using Kelvin–Voigt and Maxwell viscoelastic models. We use a 4D relative spectrum method to measure changes in attenuation. The method is tested with synthetic seismic data that are noise free and data with additive Gaussian noise to show the robustness and the accuracy of the estimates of the Q‐factor. The results of the application of the method to a field data set exhibit alignment of high attenuation zones along the steam‐injection wells, and indicate that temperature dependent viscosity changes in the heavy oil reservoir can be explained by the Kelvin–Voigt model. 相似文献
Increasing research has suggested that biosolids generated from municipal wastewater treatment can be a major sink for many pharmaceuticals and personal care products (PPCPs) and their land application potentially introduces these contaminants into the terrestrial and aquatic environments. In this study, methods were developed for the analysis of 14 PPCPs in biosolids and soils using pressurized liquid extraction, solid phase extraction and liquid chromatography‐tandem mass spectrometry. Recoveries were over 50% for all analytes except diphenhydramine (?30%) in soils. Soil properties or type of biosolids showed minor effects on method recoveries. Estimated method limits of quantification (LOQ) range from 0.1–15 ng g–1 for soil and 0.3–27 ng g–1 for biosolids. A field study utilizing the methods revealed that other than carbamazepine‐10,11‐epoxide, all targeted compounds were detected in biosolids. Diphenhydramine, fluoxetine, triclosan and triclocarban were detected up to the μg g–1 range with the highest concentration of 23 μg g–1 for triclocarban. Seven of the PCCPs found in biosolids were also detected in agricultural soils amended with these biosolids and several (carbamazepine, diphenhydramine, and triclocarban) appeared to be persistent in soils. Triclocarban was also found most abundant in soils with the highest average concentration of 0.2 μg g–1 while the rest of compounds were in the lower ng g–1 range. Generally, the concentrations found on the fields were 2–3 degrees of magnitude lower than in the biosolids, which is likely to be due to dilution, degradation and leaching processes. 相似文献
We investigated the distribution of naturally occurring geochemical tracers (222Rn, 223Ra, 224Ra, 226Ra, CH4, δ18O, and δ2H) in the water column and adjacent groundwater of Mangueira Lagoon as proxies of groundwater discharge. Mangueira Lagoon is a large (90 km long), shallow (4–5 m deep), fresh, and non-tidal coastal lagoon in southern Brazil surrounded by extensively irrigated rice plantations and numerous irrigation canals. We hypothesized that the annual, intense irrigation for rice agriculture creates extreme conditions that seasonally change groundwater discharge patterns in the adjacent lagoon. We further supposed that dredging of irrigation canals alters groundwater fluxes.
While the activities of 222Rn in shallow groundwater were 2–3 orders of magnitude higher than in surface water, CH4 and radium isotopes were only 1 order of magnitude higher. Therefore, 222Rn appears to be the preferred groundwater tracer in this system. Radon concentrations and conductivities were dramatically higher near the pump house of rice irrigation canals, consistent with a groundwater source. Modeling of radon inventories accounting for total inputs (groundwater advection, diffusion from sediments, and decay of 226Ra) and losses (atmospheric evasion, horizontal mixing and decay) indicated that groundwater advection rates in the irrigation canals (25 cm/d) are over 2 orders of magnitude higher than along the shoreline (0.1 cm/d). Nearly 75% of the total area of the canals is found in the southern half of the lagoon, where groundwater inputs seem to be higher as also indicated by methane and stable isotope trends. In spite of the relatively small area of the canals, we estimate that they contribute nearly 70% of the total (57,000 m3/d) groundwater input into the entire Mangueira Lagoon. We suggest that the dredging of these canals cut through aquitards which previously restricted upward advection from the underlying permeable strata. The irrigation channels may therefore represent an important but previously overlooked source of nutrients and other dissolved chemicals derived from agricultural practices into the lagoon. 相似文献