Mining lakes as groundwater‐dominated hydrological systems: assessment of the water balance of Mining Lake Plessa 117 (Lusatia,Germany) using stable isotopes

In the present study, the stable isotopes δ¹⁸O and δ²H were used for assessment of the water balance in a heterogeneously structured catchment area in the Lusatian Lignite Mining District, in particular, for estimation of the annual groundwater inflow and outflow (I_GW and O_GW) of Mining Lake Plessa 117. The application of stable isotopes was possible since the water exchange in the catchment area had reached steady‐state conditions after the abandonment of mining activities in 1968 and the filling of the voids and aquifers by re‐rising groundwater in the years thereafter. Diverging slopes of the Evaporation Line and the Global Meteoric Water Line manifested as evaporation from the lake catchment area. The calculated isotope water balance was compared with the commonly used surface water balance, which is unable to differentiate between I_GW and O_GW, and with a local groundwater model. The groundwater model calculated an I_GW of about 811 000 m³ yr^?1 and an O_GW close to zero, whereas the isotope water balance showed fluxes of about 914 000 and 140 000 m³ yr^?1, respectively. Considering the contribution of the groundwater inflow to the total annual input into the lake (ΔI_T) and the mean residence time (τ), where the groundwater model and the isotope water balance calculated 42 and 47% for ΔI_T and 4·3 and 3·9 years for τ, respectively, it was shown that both water balance calculation methods led to comparable results despite the differences in I_GW and O_GW. Copyright © 2008 John Wiley & Sons, Ltd.     

Characteristics of oceanic impact‐induced large water waves—Re‐evaluation of the tsunami hazard

Abstract— The potential hazard of a meteorite impact in the ocean is controversial with respect to the destructive power of generated large ocean waves (tsunamis). We used numerical modeling of hypervelocity impact to investigate the generation mechanism and the characteristics of the resulting waves up to a distance of 100–150 projectile radii. The wave signal is primarily controlled by the ratio between projectile diameter and water depth, and can be roughly classified into deep‐water and shallow‐water impacts. In the latter, the collapse of the crater rim results in a wave signal similar to solitary waves, which propagate and decay in agreement with shallow‐water wave theory. The much more likely scenario for an asteroid impact on Earth is a relatively small body (much smaller than the water depth) striking the deep sea. In this case, the collapse of the transient crater results in a significantly different and much more complex wave signal that is characterized by strong nonlinear behavior. We found that such waves decay much more rapidly than previously assumed and cannot be treated as long waves. For this reason, the shallow‐water theory is not applicable for the computation of wave propagation, and more complex models (full solution of the Boussinesq equations) are required.     

Kinetics of the Reactions of IO with HO2 and O(3P)

A discharge-flow tube coupled with resonance fluorescence and chemiluminescence detection has been used to investigate the reactions IO + HO₂ products (1) and IO + O(³P) I + O₂(2), at T = 296 ± 1 K and P = 1.7 - 2 Torr. The rate constants k_-1 and k₂ have been found to be (7.1 ± 1.6) × 10^-11 cm³ molecule^-1 s^-1 and (1.35 ± 0.15) × 10^-10 cm³ molecule^-1 s^-1, respectively.     

Magma mixing in the Aleutian arc: evidence from cognate inclusions and composite xenoliths

The complexity of igneous processes in the Aleutian calc-alkaline magma series can be inferred from study of xenolithic fragments. Composite xenoliths and cognate inclusions provide direct evidence for magma—magma and wall-rock—magma mixing processes. Using distributions of Cr in clinopyroxene, compositional endmembers involved in mixing are identified within the xenoliths. The basaltic mixing endmember is more mafic than calc-alkaline lavas in the arc. Magma mixing and wall-rock assimilation within calc-alkaline basaltic to andesitic magmas is identified in phenocrystic assemblages as well as in xenoliths, and appears to be a widespread phenomenon in Aleutian calc-alkaline magmas.     

Multivariate statistical estimates of Holocene vegetation and climate change,forest-tundra transition zone,NWT, Canada

Newly derived fossil pollen data were obtained from four sites along a transect from the boreal forest limit into tundra in the eastern Northwest Territories. Multivariate statistical analyses were employed to interpret the pollen assemblages. Transfer functions were constructed between the pollen data and climatic data, and paleoclimatic estimates were derived. The objective nature of the reconstructions provides an independent verification of the general outlines of the chronology of tree-line movements during the mid- and late-Holocene as established in previous paleosol and pollen studies. Boreal forest extended to approximately 62°N, associated with mean July temperatures 1 to 3°C above modern means, from at least 5500 to 3700 yr B.P. Although a major episode of southward displacement of tree line at about 3700 yr B.P. is recorded, later events are not clearly represented. Considerations of the statistics, the time scales, and the nature of the pollen rain suggest only conservative interpretations of the results are possible. It is suggested that the pollen sites may have been sensitive recorders of regional vegetation change only when they were near the ecotone, corresponding to a climatic threshold.     

The importance of grain size and shape in controlling the dispersion of the Vedde cryptotephra

Volcanic ash is dispersed in the atmosphere according to meteorology and particle properties, including size and shape. However, the multiple definitions of size and shape for non-spherical particles affect our ability to use physical particle properties to understand tephra transport. Moreover, although particles are often excluded from operational ash dispersion model setups, ash in tephra deposits 1000 km from source can exceed . Here we measure the shape and size of samples of Vedde ash from Iceland, an exceptionally widespread tephra layer in Europe, collected in Iceland and Norway. Using X-ray computed tomography and optical microscopy, we show that distal ash is more anisotropic than proximate ash, suggesting that shape exerts an important control on tephra dispersion. Shape also impacts particle size measurements. Particle long axis, a parameter often reported by tephrochronologists, is on average greater than geometric size, used by dispersion modellers. By using geometric size and quantifying shape, we can explain the transport of Vedde ash particles more than 1200 km from source. We define a set of best practices for measuring the size and shape of cryptotephra shards and discuss the benefits and limitations of using physical particle properties to understand cryptotephra transport.     

Alkali ion migration in albite and K-feldspar

As part of a study of ion migration mechanisms in feldspars, the dynamical behaviour of the alkali metal cations ions in albite and K-feldspar has been investigated using a combination of dielectric spectroscopy and atomistic computer simulation techniques. The low-frequency dielectric properties of these minerals have been studied from room temperature to 1100 K. At each temperature, the dielectric constant, conductivity and dielectric loss were determined over a range of frequencies from 100 Hz to 10 MHz. At high temperatures a distinct Debye-type relaxation in the dielectric loss spectra was observed for both albite and K-feldspar; the activation energy for these processes was determined to be 1.33 eV in both albite and K–feldspar. Atomistic simulation techniques were used to elucidate the mechanism and energetics of the cation migration processes. Mechanisms involving the conventional hopping of Na⁺ and K⁺ ions between cation sites in the (010) plane were found to give calculated energy barriers in good agreement with the experimentally determined activation energies. These results assist in understanding the nature of the processes responsible for the observed dielectric behaviour.     

Out there and in here: studying Eastern Europe in the West

This paper seeks to explore the challenge of studying geographies of Eastern Europe in Western Europe. It reflects on the growing relationships – imagined and material – between Eastern and Western Europe and engages in contemporary debates over 'relational geographies' to make a case for geographies which imagine our plural, European spatial connections, which connect different parts of the continent and which encourage the re-examination and renegotiation of ideas across East and West in the post-Cold War world. In these ways, the paper borrows from postcolonial frameworks and the ongoing reassessment of area studies to call for studies of Eastern and Western Europe which reinvigorate our "sense of Europe".     

Griffith Taylor Lecture,Geographical Society of New South Wales, 2004: Australia and the ‘State of Nature/Native’

This account sets itself against the binarism of physical versus cultural determinism that drives population–environment debate over people's place on the Australian continent. In reading back into colonial times, it evokes ‘our’ unresolved sense of relation to nature on a continent that has pressed awkward buttons since the time the botanist on Cook's Endeavour, Joseph Banks, first mused over the apparent contradiction on the east coast of human presence and uncultivated land. Australia's ‘state of nature’, including its inhabitants, elicited tensions in Anglo-Celtic peoples’ ambiguous relation with nature that have never gone away or been resolved. Indeed, I argue, against the background of what was considered in eighteenth-century Enlightenment thought to be a distinctly human separation from, and capacity to rise above, nature, that the Australian state of nature/native precipitated a crisis in prevailing ideas of ‘the human’. As consternation grew into the nineteenth century about the very capacity of Aboriginal people for improvement, and particularly for cultivation, I argue they challenged the basis upon which the unity of humankind had been assumed in Enlightenment thought. They could not be comprehended, according to the prevailing conception of racial difference, as a mere variety of the human. The radical idea of innate human difference may thus be understood as arising out of this incomprehension, as an attempt to account for the ontologically inexplicable difference of the Australian Aborigine. This lecture's excursion into the origins of ‘race’ is by way of highlighting the uncertainty of the divide between the human and non-human worlds. Imagining an entangled world of living things may help to craft fresh lines of debate about modes of environmental belonging and becoming on this continent that overcome the stale binaries and blind spots of Australia's population–environment debate.