The Laal-Kan fluorite deposit,Zanjan Province,NW Iran: constraints on REE geochemistry and fluid inclusions

The Laal-Kan fluorite deposit (west of Zanjan city, NW Iran) mainly occurred as some open-space filling and vein/veinlet in the schist of the Paleozoic age. Mineralogically, calcite, fluorite types (white, smoky, and violet), and quartz are the principal constituents accompanied by a number of minor accessory minerals such as hemimorphite, hematite, barite, and clays. Based on chemical analyses, fluorites of various colors were found to have low rare earth element (REE) concentrations (4.16–25.67 ppm). The chondrite-normalized REE patterns indicated that early fluorites were enriched in LREE, relative to HREE, whereas late fluorites were enriched in HREE relative to LREE. This study, therefore, indicated that fugacity of oxygen likely played a significant role in the occurrence of positive Ce and negative anomaly in the late fluorite. Furthermore, the Gd behavior of the fluorite samples could be attributed to the Gd-F complex in ore-forming fluids. On the other hand, low pH hydrothermal fluids under alkaline conditions were probably the main mechanism responsible for the deposition of the early fluorites in this district. Fluorite-hosted fluid inclusion analyses also indicated that fluorite-forming fluids consisted of NaCl, MgCl₂, CaCl₂, and LiCl with a narrow T_H (118–151 °C) and high salinities (18.96–23.47 wt.% NaCl equiv.). Further, the diagram of Tb/La-Tb/Ca ratios revealed that fluorites were predominantly deposited in the hydrothermal environment and the late stage fluorites could be considered as the product of the secondary mineralization of the early fluorites due to the interaction of the fluid with the early fluorites.     

Pottery glaze—An excellent adsorbent for the removal of Cu(II) from aqueous solution

In the present study,pottery glaze was investigated as an excellent adsorbent for the removal of Cu(Ⅱ) ions from aqueous solution.Effect of concentration,contact time,pH,and effect of electrolyte concentration,adsorbent doses and temperature were studied by using batch process to optimize conditions for maximum adsorption. Equilibrium isotherm data were analyzed using Langmuir,Freundlich and Temkin isotherms at 30,40 and 50℃. Thermodynamic parameters such as standard enthalpy change(ΔH0),free energy change(ΔG 0)and entropy change (ΔS0)were also evaluated.These parameters indicated that adsorption process is endothermic and spontaneous in nature.The mean energy calculated from Dubinin-Radushkeuich(D-R)isotherms showed chemical nature of adsorption.The kinetic data were evaluated using the pseudo-first-order and pseudo-second order kinetic equations and it was found that data best fitted pseudo-second-order model over a wide range of initial Cu(Ⅱ)concentrations supporting that chemisorption process was involved.The adsorption and desorption studies carried out by batch process suggested 100% desorption of Cu(Ⅱ)ions with 0.1 N HCl solution.     

Incorporation of silica into the goethite structure: a microscopic and spectroscopic study

Quartz and iron (hydr)oxide are reactive surface phases that are often associated with one another in soils and sediments. Despite the several studies on the coating of quartz with iron oxides, the reactivity of dissolved species (Si) leached from quartz with iron (hydr)oxides has received limited attention. In this study, goethite synthesized on quartz substrates were characterized using field emission scanning electron microscopy, X-ray diffraction (XRD), transmission electron microscopy, and Fourier-transform infrared (FT-IR) spectroscopy. The SEM characterization revealed that bundles of thin parallel aligned goethite rods were formed at pH?>?10, while large pseudohexagonal crystals of twinned goethite needles were synthesized at pH?≤?10 after dehydration and hydration in the alkaline media. TEM analysis showed expanded and distorted lattice spacing of the crystal structure of iron (hydr)oxide due to silica incorporation. The characterization showed that silica increased the crystallite size of the goethite and transformed its acicular texture to a larger, twinned needle structure. FT-IR and XRD analyses revealed band shifts in crystal bonds as well as new bond formations, which indicate the presence of changes in the chemical environment of Fe–O and Si–O bonds. Thus, the presence of sorbed silicates modifies the crystal and lattice structure of goethite.     

Multi-objective Freshwater Management in Coastal Aquifers Under Uncertainty in Hydraulic Parameters

Natural Resources Research - This paper proposes a novel stochastic framework for groundwater quantity and quality management in aquifers threatened by saltwater intrusion. In this methodology, a...     

Validation of AIRS-Retrieved atmospheric temperature data over the Taklimakan Desert

The Taklimakan Desert, the world's second largest desert, plays an important role in regional climate change. Previous studies on its spatial temperature features suffered from sparse conventional detection data, but the Atmospheric Infrared Sounder(AIRS) provides excellent temperature retrievals with high spatiotemporal resolution. Validation of AIRS temperature retrievals over desert regions with high land-surface emissivity, the key contributor to inversion error, is essential before using these data in regional weather/climate modeling. This paper examines the correlation coefficients, root mean square error(RMSE) and mean BIAS between AIRS-retrieved atmospheric temperature data and radiosonde observations(RAOBs) in the Taklimakan Desert hinterland and oases in the morning and at dusk. Firstly, the AIRS retrievals are consistent with RAOBs and are more consistent in the morning than at dusk. The consistency is better over a small-scale desert oasis than over a large-scale oasis in the morning and exhibits the opposite trend at dusk. The correlation coefficient over the hinterland is high in the morning but negative at dusk due to high desert-surface emissivity. Second, the RMSEs, which are all smaller than 3 K, are generally higher over desert sites than over oasis sites and slightly lower over a small-scale oasis than over a large-scale oasis in the morning. At dusk, the RMSEs are higher over desert sites than over oases and slightly higher over a small-scale oasis than over a large-scale oasis. Furthermore, the RMSEs are generally higher in the morning than at dusk over a large-scale oasis and lower in the morning than at dusk over a small-scale oasis. Third, the absolute mean BIAS values are mostly lower than 1 K. In the morning, relative to RAOB temperatures, the retrieval temperatures are higher over desert sites but lower over oasis sites. At dusk, the retrieval temperatures are lower than RAOB temperatures over both desert and oasis sites. The retrieval temperatures are higher than RAOB temperatures over desert sites in the morning but slightly lower at dusk. Most absolute mean BIAS values are higher in the morning than at dusk over both oasis and desert sites. Finally, the consistency between the AIRS and RAOB temperature data is high from 700 hPa to 100 hPa in the morning and from 700 hPa to 300 hPa at dusk. The difference between the AIRS and RAOB temperature data is generally higher in the morning than that at dusk. The RMSE differences between the AIRS and RAOB data are slightly lower in the morning than at dusk and are lower in the middle layers between 700 hPa and 150 hPa than in the layers above 150 hPa during both the morning and night. The BIAS is lower in the morning than at dusk below 300 hPa but higher in the upper layers. Moreover, the BIAS value is positive in the middle layers between 500 hPa and 150 hPa and negative at other levels at both times. Generally, the AIRS retrieval temperatures are reliable and can be used in further studies in the Taklimakan Desert.     

Trenching effects on dynamic behavior of a steel catenary riser

The fatigue life of a steel catenary riser (SCR) near its touch-down zone (TDZ) is substantially affected by its interaction with the seabed. Therefore, accurate estimate of the fatigue life of a SCR requires the understanding and realistic modeling of this interaction. The interaction depends on several factors, such as soil properties, riser characteristics, and the development of trenching at the seabed. Existing approaches for modeling the seabed in interaction with a SCR approximate the behavior of the seabed soil by linear or nonlinear spring and dashpot, which represent the stiffness and damping of the soil, respectively. However, these approaches do not account for certain phenomena resulting from the plastic deformation of soil, such as trenching development at the seabed. In this study, a more realistic approach is developed for simulating the interaction between a SCR and the seabed. In addition to the use of a realistic P–y curve (where P stands for the supporting force of the seabed and y for the vertical penetration of the riser into the seabed) to simulate the soil deformation during its interaction with the riser, it considers the development of a trench caused by continuous impact of a riser on the seabed and then its feedback effect on the variation of the bending moment along the riser. It is found that the trenching development on the seabed may decrease the maximum variation of bending moment of a riser near its TDZ. Since the variation of bending moment dictates the fatigue damage to the SCR, the results based on this approach indicate that the trenching development at the seabed may increase the fatigue life of the SCR and hence it may have important application to the design of a SCR.     

Influences of fisheries management measures on biological characteristics of threadfin bream (Nemipterus virgatus) in the Beibu Gulf,South China Sea

Long-term variations in population structure, growth, mortality, length at median sexual maturity, and exploitation rate of threadfin bream(Nemipterus virgatus) are reported based on bottom trawl survey data collected during 1960–2012 in the Beibu Gulf, South China Sea. Laboratory-based analyses were conducted on 16 791 individuals collected quarterly in eight different sampling years. Average body length, estimated asymptotic length, and percentage of large individuals have decreased significan...     

High-α-Metal-Rich stars in the LAMOST-MRS survey and its connection with the galactic bulge

We report the detection of a large sample of high-α-metal-rich stars on the low giant branch with 2.6＜log g＜3.3 dex in the LAMOST-MRS survey.This special group ...     

Time–space fractional governing equations of one‐dimensional unsteady open channel flow process: Numerical solution and exploration

Although fractional integration and differentiation have found many applications in various fields of science, such as physics, finance, bioengineering, continuum mechanics, and hydrology, their engineering applications, especially in the field of fluid flow processes, are rather limited. In this study, a finite difference numerical approach is proposed to solve the time–space fractional governing equations of 1‐dimensional unsteady/non‐uniform open channel flow process. By numerical simulations, results of the proposed fractional governing equations of the open channel flow process were compared with those of the standard Saint‐Venant equations. Numerical simulations showed that flow discharge and water depth can exhibit heavier tails in downstream locations as space and time fractional derivative powers decrease from 1. The fractional governing equations under consideration are generalizations of the well‐known Saint‐Venant equations, which are written in the integer differentiation framework. The new governing equations in the fractional‐order differentiation framework have the capability of modelling nonlocal flow processes both in time and in space by taking the global correlations into consideration. Furthermore, the generalized flow process may possibly shed light on understanding the theory of the anomalous transport processes and observed heavy‐tailed distributions of particle displacements in transport processes.     

Phosphorus export dynamics and hydrobiogeochemical controls across gradients of scale,topography and human impact

Concentration‐discharge (c‐Q) plots are routinely used as an integrated signal of watershed response to infer solute sources and travel pathways. However, the interpretation of c‐Q data can be difficult unless these data are fitted using statistical models. Such models are frequently applied for geogenic solutes, but it is unclear to what extent they might aid in the investigation of nutrient export patterns, particularly for total dissolved phosphorus (TDP) which is a critical driver of downstream eutrophication problems. The goal of the present study was therefore to statistically model c‐Q relations (where c is TDP concentrations) in a set of contrasting watersheds in the Northern Great Plains—ranging in size from 0.2 to 1000+ km²—to assess the controls of landscape properties on TDP transport dynamics. Six statistical models were fitted to c‐Q data, notably (a) one linear model, (b) one model assuming that c‐Q relations are driven by the mixing of end‐member waters from different landscape locations (i.e., hydrograph separation), (c) one model relying on a biogeochemical stationarity hypothesis (i.e., power law), (d) one model hypothesizing that c‐Q relations change as a function of the solute subsurface contact time (i.e., hyperbolic model), and (e) two models assuming that solute fluxes are mostly dependent on reaction rates (i.e., chemical models). Model performance ranged from mediocre (R² < 0.2) to very good (R² > 0.9), but the hydrograph separation model seemed most universal. No watershed was found to exhibit chemostatic behaviour, but many showed signs of dilution or enrichment behaviour. A tendency toward a multi‐model fit and better model performance was observed for watersheds with moderate slope and higher effective drainage area. The relatively poor model performance obtained outside these conditions illustrates the likely importance of controls on TDP concentrations in the region that are independent of flow dynamics.