Numerical modelling of organic waste dispersion from fjord located fish farms

In this study, a three-dimensional particle tracking model coupled to a terrain following ocean model is used to investigate the dispersion and the deposition of fish farm particulate matter (uneaten food and fish faeces) on the seabed due to tidal currents. The particle tracking model uses the computed local flow field for advection of the particles and random movement to simulate the turbulent diffusion. Each particle is given a settling velocity which may be drawn from a probability distribution according to settling velocity measurements of faecal and feed pellets. The results show that the maximum concentration of organic waste for fast sinking particles is found under the fish cage and continue monotonically decreasing away from the cage area. The maximum can split into two maximum peaks located at both sides of the centre of the fish cage area in the current direction. This process depends on the sinking time (time needed for a particle to settle at the bottom), the tidal velocity and the fish cage size. If the sinking time is close to a multiple of the tidal period, the maximum concentration point will be under the fish cage irrespective of the tide strength. This is due to the nature of the tidal current first propagating the particles away and then bringing them back when the tide reverses. Increasing the cage size increases the likelihood for a maximum waste accumulation beneath the fish farm, and larger farms usually means larger biomasses which can make the local pollution even more severe. The model is validated by using an analytical model which uses an exact harmonic representation of the tidal current, and the results show an excellent agreement. This study shows that the coupled ocean and particle model can be used in more realistic applications to help estimating the local environmental impact due to fish farms.     

Adsorption of BTEX on Surfactant Modified Granulated Natural Zeolite Nanoparticles: Parameters Optimizing by Applying Taguchi Experimental Design Method

In this paper, a novel adsorbent developed by means of granulating of natural zeolite nanoparticles (i.e., clinoptilolite) was evaluated for possible removal of the petroleum monoaromatics (i.e., benzene, toluene, ethylbenzene, and xylene, BTEX). To do this, the natural zeolite was ground to produce nanosized particulate, then modified by two cationic surfactants and granulated. The effect of various parameters including temperature, initial pH of the solution, total dissolved solids (TDS), and concentration of a competitive substance (i.e., methyl tert‐butyl ether, MTBE) were studied and optimized using a Taguchi statistical approach. The results ascertained that initial pH of the solution was the most effective parameter. However, the low pH (acidic) was favorable for BTEX adsorption onto the developed adsorbents. In this study, the experimental parameters were optimized and the best adsorption condition by determination of effective factors was chosen. Based on the S/N ratio, the optimized conditions for BTEX removal were temperature of 40°C, initial pH of 3, TDS of 0 mg/L, and MTBE concentration of 100 µg/L. At the optimized conditions, the uptake of each BTEX compounds reached to more than 1.5 mg/g of adsorbents.     

Modification of MCM‐41 with Anionic Surfactant: A Convenient Design for Efficient Removal of Cationic Dyes from Wastewater

The potential of MCM‐41 for the removal of cationic dyes from water solution was evaluated using sodium dodecyl sulfate (SDS) for the surface modification of this mesoporous material. Admicelle structures formed on the surface of the calcined MCM‐41 are capable of removing organic pollutants and cationic species from water environment. The structural, textural, and surface chemical characteristics of the prepared SDS‐modified MCM‐41 (SDS‐MCM‐41) were studied. The adsorption capacity of SDS‐MCM‐41 was evaluated for methylene blue (MB) as a target cationic dye. Equilibrium adsorption isotherm data were manipulated employing nonlinear regression analysis. The Langmuir, Freundlich, and Sips isotherm models were examined. The adsorption data were well fitted to both Langmuir and Sips isotherm models. The maximum adsorption capacity of SDS‐MCM‐41 for MB, based on Langmuir and Sips models, were 290.8 and 297.3 mg g^?1, respectively. Ethanol was found to be an effective solvent for partial regeneration of the adsorbent.     

Regional gravimetric quasi-geoid model and transformation surface to national height system for Turkey (THG-09)

Turkish regional geoid models have been developed by employing a reference earth gravitational model, surface gravity observations and digital terrain models. The gravimetric geoid models provide a ready transformation from ellipsoidal heights to the orthometric heights through the use of GPS/leveling geoid heights determined through the national geodetic networks. The recent gravimetric models for Turkish territory were computed depending on OSU91 (TG-91) and EGM96 (TG-03) earth gravitational models. The release of the Earth Gravitational Model 2008 (EGM08), the collection of new surface gravity observations, the advanced satellite altimetry-derived gravity over the sea, and the availability of the high resolution digital terrain model have encouraged us to compute a new geoid model for Turkey. We used the Remove-Restore procedure based on EGM08 and applied Residual Terrain Model (RTM) reduction of the surface gravity data. Fast Fourier Transformation (FFT) was then used to obtain the residual quasigeoid from the reduced gravity. We restored the individual contributions of EGM08 and RTM to the whole quasi-geoid height (TQG-09). Since the Helmert orthometric height system is adopted in Turkey, the quasi-geoid model (TQG-09) was then converted to the geoid model (TG-09) by making use of Bouguer gravity anomalies and digital terrain model. After all we combined a gravimetric geoid model with GPS/leveling geoid heights in order to obtain a hybrid geoid model (THG-09) (or a transformation surface) to be used in GPS applications. The RMS of the post-fit residuals after the combination was found to be ± 0.95 cm, which represents the internal precision of the final combination. And finally, we tested the hybrid geoid model with GPS/leveling data, which were not used in the combination, to assess the external accuracy. Results show that the external accuracy of the THG-09 model is ± 8.4 cm, a precision previously not achieved in Turkey until this study.     

An integrated earthquake vulnerability assessment framework for urban areas

In this paper, an integrated urban earthquake vulnerability assessment framework, which considers vulnerability of urban environment in a holistic manner and performs the vulnerability assessment for the neighborhood scale, is proposed. The main motivation behind this approach is the inability to implement existing vulnerability assessment methodologies for countries like Turkey, where the required data are usually missing or inadequate for the decision-makers in prioritization their limited resources for risk reduction in the administrative units from which they are responsible for. The methodology integrates socio-economical, structural, coastal, ground condition, vulnerabilities (fragilities), as well as accessibility to critical services. The proposed methodology is implemented for Eskisehir, which is one of the metropolitans of Turkey. In the implementation of the proposed framework, geographic information system (GIS) is used. While the overall vulnerabilities obtained for neighborhoods are mapped in GIS, the overall vulnerabilities obtained for buildings are visualized in 3D city model. The main reason behind using different mapping and visualization tools for vulnerabilities is to provide better ways for communicating with decision-makers. The implementation of the proposed vulnerability assessment methodology indicates that an urban area may have different vulnerability patterns in terms of structural, socio-economical, and accessibility to critical services. When such patterns are investigated, effective vulnerability reduction policies can be designed by the decision-makers. The proposed methodology well serves for this purpose.     

Identifying and Analyzing Problematic Soils

Problematic soils are those that make the construction of foundations extremely difficult. They include expansive soils, collapsing soils, and sanitary landfill. Their distribution can vary widely, both areally and with depth. However, the ability to identify these soils would be invaluable to developers and geotechnical engineers. This paper aims at discussing criteria for identifying these soils and analyze only the collapse related data to determine their nature and extent of the variability. Analysis of data at different depths showed high dispersion tendencies. Regression model showed linear variation and identified strongly related collapse parameters with validation by factor analysis.     

Direct Shear Tests on Waste Tires–Sand Mixtures

Waste tires are used in some engineering applications and thereby reduce the potential impact on the environment, for example, as lightweight materials in geotechnical engineering projects. This paper presents a brief literature review on geotechnical applications of processed waste tires, and a laboratory study on the effect of tire shreds on the physical properties of two different sands (fine angular sand and coarse rotund sand). Each type of sand was mixed four different percentages of rubber particles; 5, 10, 20 and 50% by dry weight. Direct shear tests were employed to investigate the effect of rubber particles on the shear strength of sands and internal friction angle. The addition of shredded waste rubber particles slightly decreased both the internal angle of friction and the shear strengths of the sands within the tested stress and strain levels. Additionally, a prediction model using stepwise regression (SR) method is proposed to calculate the shear strength of sands with the increasing rubber content. The performance of accuracies of proposed SR models are quite satisfactory. The proposed SR models are presented as relatively simple explicit mathematical functions for further use by researchers.     

Mineralogy and geochemistry of Nb-, Ta-, Sn-, U-, Th-, and Zr-bearing granitic rocks from Abu Rusheid shear zones,South Eastern Desert,Egypt

Granite-hosted,Nb-,Ta-,Sn-,U-,Th-,and Zr(Hf)-bearing mineralization from the Abu Rusheid shear zones occurs about 97 km southwest of the town of Marsa Alam,South Eastern Desert,Egypt.The SSE-trending brittle-ductile Abu Rusheid shear zones crosscut the peralkalic granitic gneisses and cataclastic to mylonitic rocks(mylonite,protomlyonite,and ultramylonite).The northern shear zone varies in width from 1 to 3 m with a strike length of >500 m,and the southern shear zone is 0.5 to 8 m wide and >1 km long.These shear zones locally host less altered lamprophyre and locally sheared granitic aplite-pegmatite dykes.The rare-metal minerals,identified from the peralkalic granitic gneisses and cataclastic to mylonitic rocks are associated with muscovite,chlorite,quartz,fluorite,pyrite,magnetite,and rare biotite that are restricted to the Abu Rusheid shear zones;these are columbite-tantalite and pyrochlore(var.betafite) in the northern shear zone and ferrocolumbite in the southern shear zone.Cassiterite occurs as inclusions in the columbite-tantalite minerals.U-and Th-minerals(uraninite,thorite,uranothorite,ishikawaite,and cheralite) and Hf-rich zircon coexist.Magmatic(?) zircon contains numerous inclusions of rutile,fluorite,U-Th and REE minerals,such as uranothorite,cheralite,monazite,and xenotime.Compositional variations in Ta/(Ta+Nb) and Mn/(Mn+Fe) in columbite range from 0.07-0.42 and 0.04-0.33,respectively,and Hf contents in zircon from 1.92-6.46 of the two mineralized shear zones reflect the extreme degree of magmatic fractionation.Four samples of peralkalic granitic gneisses and cataclastic to mylonitic rocks from the southern shear zone have very low TiO2(0.02 wt%-0.04 wt%),Sr [(15-20)×10-6],and Ba [(47-78)×10-6],with high Fe2O3T(0.94 wt%-1.99 wt%),CaO(0.14 wt%-1.16 wt%),alkalis(9.2 wt%-10.1 wt%),Rb [(369-805)×10-6],Zr [(1033-2261)×10-6],Nb [(371-913)×10-6],U [(51-108)×10-6],Th [(36-110)×10-6],Ta [(38-108)×10-6],Pb [(39-364)×10-6],Zn [(21-424)×10-6],Y [(8-304)×10-6],Hf [(29-157)×10-6],and ∑REE [(64-304)×10-6],especially HREE [(46-167)×10-6].Three samples from the northern shear zone also have very low TiO2(0.03 wt%),Sr [(11-16)×10-6],and Ba [(38-47)×10-6],with high Fe2O3T(1.97 wt%-2.91 wt%),CaO(0.49 wt%-1.01 wt%),alkalis(7.2 wt%-8.3 wt%),Rb [(932-978)×10-6],Zr [(1707-1953)×10-6],Nb [(853-981)×10-6],Ta [(100-112)×10-6],U [(120-752)×10-6],Th [(121-164)×10-6],Pb [(260-2198)×10-6],Zn [(483-1140)×10-6],Y [(8-304)×10-6],Hf [(67-106)×10-6],and ∑REE [(110-231)×10-6],especially HREE [(91-177)×10-6].The very high Rb/Sr(57.5-88.9),and low Zr/Hf(16.9-25.6),Nb/Ta(7.7-9.8),and Th/U(0.21-1.01) are consistent with very frac-tionated fluorine-bearing granitic rocks that were altered and sheared.The field evidence,textural relations,and compositions of the ore minerals suggest that the main mineralizing event was magmatic(629+/-5 Ma,CHIME monazite),with later hydrothermal alteration and local remobilization of the high-field-strength elements.