Green synthesis of magnetic mesoporous silica nanocomposite and its adsorptive performance against organochlorine pesticides

Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N₂ adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment.     

Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

2004年春季沙尘天气对和田市空气质量的影响

利用沙尘暴监测网数据、常规气象资料以及MICAPS系统环流形势资料,对和田市2004年春季沙尘天气产生的污染进行了详细的对比分析。研究结果表明：和田市春季污染相当严重,主要以沙尘污染为主。整个春季79％时间API（环境污染指数）指数均达到500,且45％时间可吸入颗粒物PM10在TSP巾的浓度比例达50％。不同天气系统对和田市空气的污染贡献不同。从东路影响和田市的天气系统、高压底部型地面系统和浮尘天气所造成空气污染相当严重。其余天气系统和天气现象所产生的污染较小。     

A Comparative Study of Landsat‐7 and Landsat‐8 Data Using Image Processing Methods for Hydrothermal Alteration Mapping

Comparing spaceborne satellite images of Landsat‐8 Operational Land Imager (OLI) and Landsat‐7 Enhanced Thematic Mapper plus (ETM+) was undertaken to investigate the relative accuracy of mapping hydrothermal alteration minerals. The study investigated the northern part of Rabor, which contains copper mineralization occurrences, and is located in the Kerman Cenozoic magmatic assemblage (KCMA), Iran. Image processing methods of band ratio, principal component analysis (PCA), and spectral angle mapper (SAM) were used to map the distribution of hydrothermally altered rocks associated with the porphyry copper mineralization. The band ratio combination of both sensors for mapping altered areas showed similar outcomes. PCA exposed variations in the spatial distribution of hydroxyl‐bearing minerals. The representation of hydrothermal areas using OLI data was more satisfactory than when using ETM+ data. SAM analysis found similar results for mapping hydroxyl‐bearing zones. Verification of the results came through ground investigation and laboratory studies. Rock samples (n = 56) were collected to validate results using thin sections, X‐ray diffraction (XRD) and spectral analyses. Field observations and laboratory analysis revealed that phyllic and propylitic alterations dominate the alteration zones in the study area. Argillic and iron oxides/hydroxides alterations were observed to a lesser degree. The results indicate that alteration maps prepared by OLI data using PCA for visual interpretation are more suitable than those of ETM+ due to a higher radiometric resolution and lower interference between vegetation and altered areas. As the spectral bandwidth of ETM+ band 7 covers absorption feature of propylitic alteration, better mapping of propylitic alterations is achieved using ETM+ data.     

Vulnerability and adaptability of wheat production in different climatic zones of Pakistan under climate change scenarios

Ten wheat production sites of Pakistan were categorized into four climatic zones i.e. arid, semi-arid, sub-humid and humid to explore the vulnerability of wheat production in these zones to climate change using CSM-Cropsim-CERES-Wheat model. The analysis was based on multi-year (1971–2000) crop model simulation runs using daily weather series under scenarios of increased temperature and atmospheric carbon dioxide concentration (CO₂) along with two scenarios of water management. Apart from this, sowing date as an adaptation option to offset the likely impacts of climate change was also considered. Increase in temperature resulted in yield declines in arid, semi-arid and sub-humid zone. But the humid zone followed a positive trend of gain in yield with rise in temperature up to 4°C. Within a water regime, increase in CO₂ concentration from 375 to 550 and 700 ppm will exert positive effect on gain in wheat yield but this positive effect is significantly variable in different climatic zones under rainfed conditions than the full irrigation. The highest response was shown by arid zone followed by semi-arid, sub-humid and humid zones. But if the current baseline water regimes (i.e. full irrigation in arid and semi-arid zones and rainfed in sub-humid and humid zones) persist in future, the sub-humid zone will be most benefited in terms of significantly higher percent gain in yield by increasing CO₂ level, mainly because of its rainfed water regime. Within a CO₂ level the changes in water supply from rainfed to full irrigation shows an intense degree of responsiveness in terms of yield gain at 375 ppm CO₂ level compared to 550 and 700 ppm. Arid and semi-arid zones were more responsive compared to sub-humid and humid zones. Rise in temperature reduced the length of crop life cycle in all areas, though at an accelerated rate in the humid zone. These results revealed that the climatic zones have shown a variable intensity of vulnerability to different scenarios of climate change and water management due to their inherent specific and spatial climatic features. In order to cope with the negative effects of climate change, alteration in sowing date towards cooler months will be an appropriate response by the farmers.     

A study of aerosol properties over Lahore (Pakistan) by using AERONET data

It is well established that aerosols affect the climate in a variety of ways. In order to understand these effects, we require an insight into the properties of aerosols. In this paper we present a study of aerosol properties such as aerosol optical depth (AOD), single scattering albedo (SSA) and aerosol radiative forcing (ARF) over mega city of Lahore (Pakistan). The data from Aerosol Robotic Network (AERONET) have been used for the period December 2009 to October 2011. The seasonal average values of AOD, asymmetry parameter (ASY) and volume size distribution in coarse mode were observed to be highest in summer. On the other hand, the average values of Angstrom exponent (AE) and imaginary part of refractive index (RI) were found to be maximum in winter. The average value of real part of RI was found to be higher in spring than in all other seasons. The SSA exhibited an increasing trend with wavelength in the range 440 nm–1020 nm in spring, summer and fall indicating the dominance of coarse particles (usually dust). However, a decreasing trend was found in winter in the range 675 nm–1020 nm pointing towards the dominance of biomass and urban/industrial aerosols. As far as aerosol radiative forcing (ARF) is concerned, we have found that during the spring season ARF was lowest at the surface of Earth and highest at top of the atmosphere (TOA). This indicates that the atmosphere was warmer in spring than in all the remaining seasons.     

The effects of intermediate principle stress on the mechanical behavior of transversely isotropic rocks: Insights from DEM simulations

The discrete element method (DEM) is used to study the response of anisotropic rocks under true triaxial testing. Numerical samples of seven different bedding orientations (β = 0^o, 15^o, 30^o, 45^o, 60^o, 75^o, and 90^o) are created. Six series of test simulations (σ₃ = 0, 10, 30, 50, 70, and 100 MPa) are conducted on each sample, with five different σ₂ values, varied from σ₃ to σ₁. The effects of anisotropy and intermediate stress on the peak strength, brittle-ductile transition, and degree of anisotropy are subsequently explained through underlying micromechanics. Results show a “fan-shaped” variation of the peak strength with σ₂, displaying an ascending-then-descending trend. An increasing brittleness with σ₂ is observed at lower confining pressures for all, but medium anisotropy angles. For higher confining pressures, increasing ductility with σ₂ is seen for every anisotropy angle. A U-shaped variation of peak strength with anisotropy angles is noted that flattens under high intermediate stress. Hence, for numerical models of Posidonia shale under normalized σ₂ higher than 0.76, the anisotropy effect is found to be negligible. Micromechanical analyses reveal that the stress asymmetry, suppression of weak plane action as well as the localization and coalescence of microcracks in the intact rock matrix, due to σ₂, are the contributors towards the obtained trends. Since existing failure criteria do not weigh in these features in geotechnical assessments, this paper helps future studies by providing a deeper understanding of these effects and a comprehensive data set for the analyses of anisotropic rocks under polyaxial stress conditions.     

The ideal resonance problem,a comparison of two formal solutions,II

This paper is a sequel to an earlier article of the same title. The two formal analytical solutions of the Ideal Resonance Problem developed respectively by Garfinkel and Jupp are here compared, atsecond-order in the appropriate small parameter, with numerical integrations; the second-order circulation solution for Jupp's theory being presented for the first time. It transpires that throughout most of the deep resonance regime the second-mentioned solution provides greater accuracy. In addition, it is demonstrated that the first solution is not appropriate when general initial values of the variables are prescribed.