Ni2SiO4-enthalphy of the olivine-spinel transition by solution calorimetry at 713°C

The high pressure spinel polymorph of Ni₂SiO₄ persists metastably at 713°C and atmospheric pressure. The enthalpy of the olivine-spinel transition was obtained by measuring the heats of solution of both polymorphs in a molten oxide solvent, 2PbO · B₂O₃, at that temperature. For Ni₂SiO₄(ol)→Ni₂SiO₄, ΔH₉₈₆⁰ = +1.4 ± 0.7kcal/mol. The heat content increments, H₉₈₆ ? H₂₉₇, were found to be: olivine, 25.73 ± 0.42kcal/mol, and spinel, 25.39 ± 0.20kcal/mol. The measured enthalpy of the transformation is consistent with the low slope of the phase boundary, ?P/?T = ～ 12b/deg, observed by Akimoto and others. The entropy of the olivine-spinel transition in Ni₂SiO₄ is accordingly about a factor of three smaller in magnitude (ΔS = ～ ?1cal/deg mol) than that for Co₂SiO₄,Fe₂SiO₄,Mg₂SiO₄or Mg₂GeO₄ (ΔS = ?3to?3.5cal/deg mol).     

Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Post‐European settlement response gradients of river sensitivity and recovery across the upper Hunter catchment,Australia

Most analyses of river adjustment have focused on parts of catchments where metamorphosis has occurred. This provides a non‐representative view of river responses to human‐disturbance. Although many rivers have been subjected to systematic land‐use change and disturbance, significant variability is evident in the form, extent and consequences of adjustment. This study documents the catchment‐wide distribution of river sensitivity and adjustment in the upper Hunter catchment, New South Wales, Australia in the period since European settlement. The spatial distribution and timing of lateral, vertical and wholesale river adjustments are used to assess river sensitivity to change. The type and pattern of rivers, influenced largely by valley setting, have induced a fragmented pattern of river adjustment in the upper Hunter catchment. Adjustments have been largely non‐uniform and localized, reflecting the predominance of bedrock‐controlled rivers which have limited capacity to adjust and are resilient to change. Less than 20% of river courses have experienced metamorphosis. Phases of reach‐scale geomorphic adjustment to human disturbance are characterized as a gradient of primary, secondary and tertiary responses. In general terms, primary responses such as cutoffs or straightening were followed by secondary responses such as channel expansion. These secondary responses occurred between 50–70 years after initial disturbance. A subsequent tertiary phase of river recovery, denoted as a transition from predominantly erosional to predominantly depositional geomorphic processes such as channel contraction, occurred around 70–120 years after initial disturbance. Such responses are ongoing across much of the upper Hunter catchment. Copyright © 2009 John Wiley & Sons, Ltd.     

Experimental study of polybaric REE partitioning between olivine, pyroxene and melt of the Yamato 980459 composition: Insights into the petrogenesis of depleted shergottites

A synthetic composition representing the Yamato 980459 martian basalt (shergottite) has been used to carry out phase relation, and rare earth element (REE) olivine and pyroxene partitioning experiments. Yamato 980459 is a sample of primitive basalt derived from a reduced end-member among martian mantle sources. Experiments carried out between 1-2 GPa and 1350-1650 °C simulate the estimated pressure-temperature conditions of basaltic melt generation in the martian mantle. Olivine-melt and orthopyroxene-melt partition coefficients for La, Nd, Sm, Eu, Gd and Yb (D_REE values) were determined by LA-ICPMS, and are similar to the published values for terrestrial basaltic systems. We have not detected significant variation in D-values with pressure over the range investigated, and by comparison with previous studies carried out at lower pressure.We apply the experimentally obtained olivine-melt and orthopyroxene-melt D_REE values to fractional crystallization and partial melting models to develop a three-stage geochemical model for the evolution of martian meteorites. In our model we propose two ancient (∼4.535 Ga) sources: the Nakhlite Source, located in the shallow mantle, and the Deep Mantle Source, located close to the martian core-mantle boundary. These two sources evolved distinctly on the ε¹⁴³Nd evolution curve due to their different Sm/Nd ratios. By partially melting the Nakhlite Source at ∼1.3 Ga, we are able to produce a slightly depleted residue (Nakhlite Residue). The Nakhlite Residue is left undisturbed until ∼500 Ma, at which point the depleted Deep Mantle Source is brought up by a plume mechanism carrying with it high heat flow, melts and isotopic signatures of the deep mantle (e.g., ε¹⁸²W, ε¹⁴²Nd, etc.). The plume-derived Deep Mantle Source combines with the Nakhlite Residue producing a mixture that becomes a mantle source (herein referred to as “the Y98 source”) for Yamato 980459 and the other depleted shergottites with the characteristic range of Sm/Nd ratios of these meteorites. The same hot plume provides a heat source for the formation of enriched and intermediate shergottites. Our model reproduces the REE patterns of nakhlites and depleted shergottites and can explain high ε¹⁴³Nd in depleted shergottites. Furthermore, the model results can be used to interpret whole rock Rb-Sr and Sm-Nd ages of shergottites.     

Carbon and suspended sediment transport in an impounded alpine river (Isère,France)

Carbon and total suspended sediment (TSS) loads were investigated from April 2006 to March 2008 in the mountainous watershed of the Isère River, French Alps (5570 km²). The river bed has been highly impounded for hydroelectricity production during the last century. Hydraulic flushes are managed every year to prevent TSS storage within upstream dams. The Isère River has been instrumented for high‐frequency monitoring of water, TSS by turbidity and carbon (organic, inorganic, dissolved and particulate) in order to evaluate the impact of natural floods and hydraulic flushes on annual loads. Annual TSS load which was estimated between 1.3 and 2.3 MT y^?1 (i.e. 233 to 413 T km^?2 y^?1) highlighted the high erodibility of the Isère watershed. Annual carbon load was estimated between 173 10³ T y^?1 and 199 10³ T y^?1 (i.e 31 to 36 T km^?2 y^?1). About 80% of the annual carbon loads were inorganic. The impact of hydraulic flushes on annual loads appeared limited (less than 3% for annual TSS load and about 1.5% for annual carbon load), whereas the most important natural flood event contributed to 20% of the annual TSS load and 10% of the annual carbon load. Copyright © 2012 John Wiley & Sons, Ltd.     

A conceptual model of the copper–porphyry ore formation based on joint analysis of deep 3D geophysical models: Sorskoe complex (Russia) case study

Joint analysis of deep three-dimensional models of the electrical resistivity, seismic velocity, and density of the complex hosting the Sorskoe Cu–Mo deposit (Russia) is carried out aimed at finding geophysical markers characterizing the areas of ore generation, transportation and deposition. The three-dimensional lithology model of the study area is built based on the empirical relationship between the silica content of the rocks and seismic velocities. It is in agreement with geological and geochemical studies provided in this area earlier and could be used as a basis for forecasting locations of the copper–molybdenum ore deposits at depth. A conceptual model of the copper–porphyry complex explaining the mechanisms of ore generation, transportation from the lower to the upper crust and deposition in the upper crust is suggested. In particular, it is supposed that post-magmatic supercritical gas–water ore-bearing fluids are upwelling through the plastic crust due to the sliding of the fluid films along the cleavage planes of the foliated rocks while at the depths of the brittle upper crust this mechanism could be changed by volumetric fluid transportation along the network of large pores and cracks.     

Adaptation financing for projects focused on food systems through the UNFCCC

Investments in adaptation are required to reduce vulnerability and strengthen the resilience of food systems to the impacts of climate change. For low-income nations, international financing plays a central role in supporting adaptation. In this article, we document and examine adaptation projects targeting food systems financed through funding bodies of the United Nations Framework Convention on Climate Change (UNFCCC). We find that between 2004 and 2015, 3% (n?=?96) of adaptation projects supported through the UNFCCC explicitly focused on the production, processing, distribution, preparation and/or consumption of food, with US$546 m mobilized through funding bodies directly and US$1.44bn through co-financing. Agriculture is the most common sector supported, with extreme weather events the primary climate change-related impact motivating nations to apply for adaptation financing. The majority of actions are documented to adapt the food production component of food systems, with limited focus within projects on the full range of food system vulnerability and the implications on food security.

Key policy insights

• Enhanced international adaptation financing targeting food systems is needed, and in particular financing to address limited adaptation readiness

• Supported food system projects should include holistic assessments of the entire food system in order to prioritize sector and food system component issue areas for short- and long-term efficiency

• To better analyse food system linkages and aid in the prioritization of adaptation activities, adaptation-directed funds should consider placing a higher emphasis on a cross-sectoral approach within projects

• Linkages between official development assistance and adaptation-directed funds could help optimize financing for food systems and mainstream food system adaptation efforts

     

Characterization of mesostasis regions in lunar basalts: Understanding late‐stage melt evolution and its influence on apatite formation

Recent studies geared toward understanding the volatile abundances of the lunar interior have focused on the volatile‐bearing accessory mineral apatite. Translating measurements of volatile abundances in lunar apatite into the volatile inventory of the silicate melts from which they crystallized, and ultimately of the mantle source regions of lunar magmas, however, has proved more difficult than initially thought. In this contribution, we report a detailed characterization of mesostasis regions in four Apollo mare basalts (10044, 12064, 15058, and 70035) in order to ascertain the compositions of the melts from which apatite crystallized. The texture, modal mineralogy, and reconstructed bulk composition of these mesostasis regions vary greatly within and between samples. There is no clear relationship between bulk‐rock basaltic composition and that of bulk‐mesostasis regions, indicating that bulk‐rock composition may have little influence on mesostasis compositions. The development of individual melt pockets, combined with the occurrence of silicate liquid immiscibility, exerts greater control on the composition and texture of mesostasis regions. In general, the reconstructed late‐stage lunar melts have roughly andesitic to dacitic compositions with low alkali contents, displaying much higher SiO₂ abundances than the bulk compositions of their host magmatic rocks. Relevant partition coefficients for apatite‐melt volatile partitioning under lunar conditions should, therefore, be derived from experiments conducted using intermediate compositions instead of compositions representing mare basalts.     

Revisiting the Gow Lake impact structure,Saskatchewan, Canada

The ~5 km diameter Gow Lake impact structure formed in the Canadian Shield of northern Saskatchewan approximately 197 Myr ago. This structure has not been studied in detail since its discovery during a regional gravity survey in the early 1970s. We report here on field observations from a 2011 expedition that, when combined with subsequent laboratory studies, have revealed a wealth of new information about this poorly studied Canadian impact structure. Initially considered to be a prototypical central peak (i.e., a complex) impact structure, our observations demonstrate that Gow Lake is actually a transitional impact structure, making it one of only two identified on Earth. Despite its age, a well-preserved sequence of crater-fill impactites is preserved on Calder Island in the middle of Gow Lake. From the base upward, this stratigraphy is parautochthonous target rock, lithic impact breccia, clast-rich impact melt rock, red clast-poor impact melt rock, and green clast-poor impact melt rocks. Discontinuous lenses of impact melt-bearing breccia also occur near the top of the red impact melt rocks and in the uppermost green impact melt rocks. The vitric particles in these breccias display irregular and contorted outlines. This, together with their setting within crater-fill melt rocks, is indicative of an origin as flows within the transient cavity and not an airborne mode of origin. Following impact, a hydrothermal system was initiated, which resulted in alteration of the crater-fill impactites. Major alteration phases are nontronite clay, K-feldspar, and quartz.