Oxygen isotopic constraints on the origin of magnesian chondrules and on the gaseous reservoirs in the early Solar System

We report in situ ion microprobe analyses of the oxygen isotopic composition of the major silicate phases (olivine, low-Ca pyroxene, silica, and mesostasis) of 37 magnesian porphyritic (type I) chondrules from CV (Vigarano USNM 477-2, Vigarano UH5, Mokoia, and Efremovka) and CR (EET 92042, EET 92147, EET 87770, El Djouf 001, MAC 87320, and GRA 95229) carbonaceous chondrites. In spite of significant variations of the modal proportions of major mineral phases in CR and CV chondrules, the same isotopic characteristics are observed: (i) olivines are isotopically homogeneous at the ‰ level within a chondrule although they may vary significantly from one chondrule to another, (ii) low-Ca pyroxenes are also isotopically homogeneous but systematically ¹⁶O-depleted relative to olivines of the same chondrule, and (iii) all chondrule minerals analyzed show ¹⁶O-enrichments relative to the terrestrial mass fractionation line, enrichments that decrease from olivine (±spinel) to low-Ca pyroxene and to silica and mesostasis. The observation that, in most of the type I chondrules studied, the coexisting olivine and pyroxene crystals and glassy mesostasis have different oxygen isotopic compositions implies that the olivine and pyroxene grains are not co-magmatic and that the glassy mesostasis is not the parent liquid of the olivine. The δ¹⁸O and δ¹⁷O values of pyroxene and olivine appear to be strongly correlated for all the studied CR and CV chondrules according to:

     

Trace element associations with Fe- and Mn-oxides in soil nodules: Comparison of selective dissolution with electron probe microanalysis

Selective dissolution methods have been largely used to get insight on trace element association with solid phases. Modern instrumental techniques offer many tools to test the validity of selective dissolution methods and should be systematically used to this end. The association of trace elements with Fe- and Mn-oxides in soil nodules has been studied here by electron probe microanalysis. The results were compared with findings from an earlier study on selective dissolution of the same nodules by hydroxylamine hydrochloride, acidified hydrogen peroxide, and Na-citrate-bicarbonate-dithionite. Electron probe microanalysis results were consistent with previous findings using selective dissolution and showed that P, As and Cr were mainly present in Fe-oxides, while Co was mainly associated with Mn-oxide phases. These results support the applicability of the studied selective dissolution methods for fractionation of trace elements in soils and sediments containing appreciable amounts of Fe and Mn-oxide phases.     

Seasonal and spatial distribution of redox zones during lake bank filtration in Berlin,Germany

Redox processes during bank filtration were evaluated in Berlin, where bank filtered water is abstracted for drinking water production. The investigations included the mapping of the infiltration zone, a column study and hydrochemical analyses of the groundwater sampled between lake and production well. The organic carbon content increased and the permeability of the lake sediments decreased with distance from the shoreline. The most important changes with regard to the redox state of the infiltrate occurred within the first metre of flow. Infiltration was mostly anoxic, as oxygen was rapidly consumed within the organic rich sediments. The infiltration zone revealed a vertical redox stratification with hydrochemical conditions becoming more reducing with depth rather than with distance from the lake. The redox zones were found to be very narrow below the lake and wider towards the production wells, suggesting that other than differing flow paths, reaeration after infiltration may also occur and possible mechanisms are presented. Redox conditions were influenced by strong annual temperature variations of the surface water affecting the microbial activity. Aerobic infiltration only took place close to the shore in winter.     

Spatial Patterns of Larceny and Aggravated Assault in Miami–Dade County, 2007–2015

The combination of crime mapping and geospatial analysis methods has enabled law enforcement agencies to develop more proactive methods of targeting crime-prone neighborhoods based on spatial patterns, such as hot spots and spatial proximity to specific points of interest. In this article, we investigate the spatial and temporal patterns of the neighborhood crimes of aggravated assault and larceny in 297 census tracts in Miami–Dade County from 2007 to 2015. We use emerging hot spot analysis (EHSA) to identify the spatial patterns of emerging, persistent, continuous, and sporadic hot spots. In addition, we use geographically weighted regression to analyze the spatial clustering effects of sociodemographic variables, poverty rate, median age, and ethnic diversity. The hot spots for larceny are much more diffused than those for aggravated assaults, which exhibit clustering in the north over Liberty City and Miami Gardens and in the south near Homestead, and the ethnic heterogeneity index has a moderate and positive effect on the incidence of both larceny and aggravated assaults. The findings suggest that law enforcement can better target prevention programs for violent versus property crime using geospatial analyses. Additionally, the ethnic concentration of neighborhoods influences crime differently in neighborhoods of different socioeconomic status, and future studies should account for spatial patterns when estimating conventional regression models.     

Towards a standard measure of sea anemone size: assessing the accuracy and precision of morphological measures for cantilever‐like animals

Our capacity to detect and interrogate patterns in nature depends on the use of standard methods for measuring biological units. Consensus methods to quantify the size of individual animals and characteristics of biological communities are critical for comparisons across time and space. Nowhere is this more important than when dealing with organisms such as sea anemones that display high plasticity in body shape. Despite the need for accurate measures of anemone size for ecological comparisons, there is little consensus on the accuracy and precision of size inferences for these animals. We assessed several morphological parameters to determine which in‐field measure accurately and reliably reflects the reference size of an anemone measured in the laboratory: (i) column height, (ii) column diameter, (iii) limbus diameter, (iv) pedal disc diameter, (v) pedal disc area or (vi) pedal disc perimeter. The results revealed large variability in the accuracy and precision amongst measures, which have implications for their suitability as a standard method for in situ measurements. In general, measures of diameter were preferable to those of height, area and perimeter; and those associated with attachment (i.e. the limbus and pedal disc diameter) performed the best. Overall, considering concurrence with measures obtained from two differing but useful reference states, pedal disc diameter was the most accurate parameter (mean percentage difference = 0.6) with which to estimate the size of sea anemones in the field, and we thus recommend its use as an effective, non‐destructive means of gaining insights into their behavioural and evolutionary ecology.     

Two types of Archaean supracrustal belts in the Bundelkhand craton,India: Geology,geochemistry, age and implication for craton crustal evolution

Groundwater sampling was carried out in fast growing Vijayawada urban agglomeration in Andhra Pradesh state with a view to generate base line data and to assess groundwater quality, its variations vis-à-vis urbanization and hydrochemical characteristics. The groundwaters are found to be fresh to brackish, hard to very hard, often enriched with nitrate, phosphate,and faecal colliform indicating anthropogenic influence on groundwater on account of urbanization. Manganese and iron of geogenic origin are also found to be in high concentrations in some localities. The quality deterioration is more in shallow aquifers, as also in core urban and red soil covered areas. Spatial variations in groundwater quality are discernible, with high concentrations of SO₄^-4–,NO₃^- in core urban area suggesting the impact of urbanization. A wide range of chemical constituents indicate water rock interactions as influenced by anthropogenic activities controlling the urban aquifers. The order of abundance of cations is Na>Mg>Ca>K, while the order of abundance of anions is Cl>HCO₃>SO₄>NO₃. The baseline study suggests the need to protect the groundwater resource through sound environmental protection measures for the welfare of the inhabitants in the city around which the new capital is proposed to be constructed for newly formed Andhra Pradesh state in India.     

Heterozoan carbonates from the equatorial rocky reefs of the Galápagos Archipelago

Strongly influenced by seasonal and interannual (i.e. El Niño‐Southern Oscillation) upwelling, the equatorial setting of the Galápagos Archipelago is divided into well‐defined temperature, nutrient and calcium carbonate saturation (Ω_aragonite) regions. To understand the relationship between oceanographic properties and sediment grain associations, grain size, carbonate content and components from sea floor surface samples were analysed, representing the main geographical regions of the Galápagos Archipelago. The shallow‐water rocky reefs of the Galápagos Archipelago are characterized by mixed carbonate–siliciclastic slightly gravelly sands. Despite minor differences in carbonate content, major differences exist in the distribution and composition of key carbonate producing biota. Halimeda is absent and benthic foraminifera occur in extremely low abundance. The western side of the Galápagos Archipelago is strongly influenced by nutrient‐rich, low‐Ω_aragonite, subtropical water, which generates a heterozoan carbonate biofacies in a tropical realm resembling cold‐water counterparts (i.e. serpulid, echinoderm, gastropod, barnacle and bryozoan‐rich facies). The Central East region is composed of a transitional‐heterozoan biofacies. Biofacies observed in the northern region have an increased occurrence of tropical corals, albeit with a minor overall contribution to the carbonate components. Although the temperature gradient would allow for a broader distribution of photozoan biofacies, the increased nutrient concentration and related reduced light penetration from the upwelled waters favour heterozoan carbonate factories, mimicking cool‐water, deeper or higher latitude environments. The recent sedimentary record of the Galápagos Archipelago presents a range of tropical heterozoan carbonate communities, responding to more than simply latitude or temperature but a much more complex mixture of physical, evolutionary and geological processes.     

The stability of geodemographic cluster assignments over an intercensal period

A geodemographic classification provides a set of categorical summaries of the built and socio-economic characteristics of small geographic areas. Many classifications, including that developed in this paper, are created entirely from data extracted from a single decennial census of population. Such classifications are often criticised as becoming less useful over time because of the changing composition of small geographic areas. This paper presents a methodology for exploring the veracity of this assertion, by examining changes in UK census-based geodemographic indicators over time, as well as a substantive interpretation of the overall results. We present an innovative methodology that classifies both 2001 and 2011 census data inputs utilising a unified geography and set of attributes to create a classification that spans both census periods. Through this classification, we examine the temporal stability of the clusters and whether other secondary data sources and internal measures might usefully indicate local uncertainties in such a classification during an intercensal period.