Does Pumping Volume Affect the Concentration of Micropollutants in Groundwater Samples?

Information on concentrations of micropollutants (such as pharmaceuticals, pesticides, and industrial chemicals) in most highly dynamic riverbank filtration (RBF) systems is lacking, in contrast to data on standard chemical parameters. Sampling protocols have thus far been based on the stabilization of standard chemical parameters in relatively pristine environments. To determine whether groundwater samples for micropollutant analysis can be taken at a similar pumping volume as samples for testing standard chemical parameters in both environments, three groundwater monitoring wells in an RBF system were sampled at two points in time (after pumping of 3 well volumes and after pumping of 15 well volumes). Micropollutant concentrations were not significantly different between the two sampling points; therefore, appropriate samples can be drawn after pumping 3 well volumes. For a specific microbiological parameter (leucin incorporation), a statistically significant difference was found.     

Classification issues within ensemble-based simulation: application to surge floods forecasting

The paper proposes a high-level conceptual and technological approach to manage the ensemble-based simulation, taking into account changing states of both simulated system and system of models. The approach includes systematization of ensemble-based modeling and simulation techniques, analysis of simulation results, quality assessments, and detailed analysis of ensemble management procedures using classification operators. The technological basis for such an approach includes ensemble-based simulation techniques using domain-specific software combined within a composite application; data science approaches for analysis of available datasets (simulation data, observations, situation assessments, etc.). Within this work, a set of case studies is addressed to examine the opportunities provided by the developed approach considering ensemble-based simulation of storm surges for flood prediction in St. Petersburg, Russia as an example.     

Wave observations from an array of directional buoys over the southern Brazilian coast

It is well known that the majority of buoy measurements are located around the US coast and along some Europeans countries. The lack of long-term and densely spaced in situ measurements in the Southern Hemisphere in general, and the South Atlantic in particular, hinders several investigations due to the lack of detailed metocean information. Here, we present an effort to overcome this limitation, with a dense network of buoys along the Brazilian coast, equipped with several meteorological and oceanographic sensors. Out of ten currently operational buoys, three are employed to present the main characteristics of waves in the Southern part of the network. For the first time, sensor characteristics and settings are described, as well as the methods applied to the raw wave data. Statistics and distributions of wave parameters, swell propagating events, comparison with a numerical model and altimeters and a discussion about the occurrence of freak waves are presented.     

Reintroduced large wood modifies fine sediment transport and storage in a lowland river channel

This paper explores changes in suspended sediment transport and fine sediment storage at the reach and patch scale associated with the reintroduction of partial large wood (LW) jams in an artificially over‐widened lowland river. The field site incorporates two adjacent reaches: a downstream section where LW jams were reintroduced in 2010 and a reach immediately upstream where no LW was introduced. LW pieces were organized into ‘partial’ jams incorporating several ‘key pieces’ which were later colonized by substantial stands of aquatic and wetland plants. Reach‐scale suspended sediment transport was investigated using arrays of time‐integrated suspended sediment samplers. Patch‐scale suspended sediment transport was explored experimentally using turbidity sensors to track the magnitude and velocity of artificially generated sediment plumes. Fine sediment storage was quantified at both reach and patch scales by repeat surveys of fine sediment depth. The results show that partial LW jams influence fine sediment dynamics at both the patch and reach scale. At the patch‐scale, introduction of LW led to a reduction in the concentration and increase in the time lag of released sediment plumes within the LW, indicating increased diffusion of plumes. This contrasted with higher concentrations and lower time lags in areas adjacent to the LW; indicating more effective advection processes. This led to increased fine sediment storage within the LW compared with areas adjacent to the LW. At the reach‐scale there was a greater increase in fine sediment storage through time within the restored reach relative to the unrestored reach, although the changes in sediment transport responsible for this were not evident from time‐integrated suspended sediment data. The results of the study have been used to develop a conceptual model which may inform restoration design. Copyright © 2017 John Wiley & Sons, Ltd.     

Evolutionary status of T Tauri stars

The problem of determining the masses and ages of T Tauri star(TTS) using their evolutionary status is discussed. We test four pre-main sequence evolutionary models using well determined observational parameters of 12 binary TTSs and two binary red dwarfs. It is shown that the masses derived using the tracks of all models are in good agreement with the masses obtained from the observations of TTSs with masses M 0.7 M_⊙(mean error ε ~ 10%). Low-mass stars with M ≤ 0.7 M_⊙have significantly greater mean error: ε ~ 50% for the tracks of Bressan et al. and Chen et al., and ε ~ 30% for the other tracks. The isochrones of all tested evolutionary models diverge for stars with masses M ≤ 0.7 M_⊙. The difference increases with the mass decrease and can reach 10% of KelvinHelmholtz time for stars with mass M = 0.2 M_⊙. The ages of most of the considered TTSs are smaller than the Kelvin-Helmholtz time. This confirms their evolutionary status of being pre-main sequence stars.     

The CM carbonaceous chondrite regolith Diepenveen

A carbonaceous chondrite was recovered immediately after the fall near the village of Diepenveen in the Netherlands on October 27, 1873, but came to light only in 2012. Analysis of sodium and poly‐aromatic hydrocarbon content suggests little contamination from handling. Diepenveen is a regolith breccia with an overall petrology consistent with a CM classification. Unlike most other CM chondrites, the bulk oxygen isotopes are extremely ¹⁶O rich, apparently dominated by the signature of anhydrous minerals, distributed on a steep slope pointing to the domain of intrinsic CM water. A small subset plots closer to the normal CM regime, on a parallel line 2 ‰ lower in δ¹⁷O. Different lithologies in Diepenveen experienced varying levels of aqueous alteration processing, being less aqueously altered at places rather than more heated. The presence of an agglutinate grain and the properties of methanol‐soluble organic compounds point to active impact processing of some of the clasts. Diepenveen belongs to a CM clan with ~5 Ma CRE age, longer than most other CM chondrites, and has a relatively young K‐Ar resetting age of ~1.5 Ga. As a CM chondrite, Diepenveen may be representative of samples soon to be returned from the surface of asteroid (162173) Ryugu by the Hayabusa2 spacecraft.     

Carbonaceous matter in the Sariçiçek meteorite

As of today, the Sariçiçek (SC) meteorite is the newest howardite and the only confirmed fall among the 17 known howardites. In this study, we present isotopic, infrared, and Raman data on three distinct pieces of the SC meteorite. Our oxygen isotopic measurements show that Δ¹⁷O values of the pieces are close to each other, and are in good agreement with other howardites, eucrites, and diogenites. The carbon isotopic measurements, which were conducted by combusting terrestrial contamination selectively at temperatures lower than 500–600 °C, show the presence of indigenous carbon in the SC specimens. The matrix of these specimens, investigated via infrared microspectroscopy, appears to be dominated by clinopyroxene/orthopyroxene, forsterite, and fayalite, with minor contributions from ilmenite, plagioclase, and enstatite. Carbon‐rich regions were mapped and studied via Raman imaging microspectroscopy, which reveals that both amorphous and graphitic carbon exist in these samples. Synchrotron‐based infrared microspectroscopy data show the presence of very little aliphatic and aromatic hydrocarbons. The SC meteorite is suggested to be originating from the Antonia impact crater in the Rheasilvia impact basin on 4 Vesta (Unsalan et al. 2019). If this is in fact the case, then the carbon phases present in the SC samples might provide clues regarding the impactor material (e.g., carbonaceous chondrites).     

The Chelyabinsk meteorite: Thermal history and variable shock effects recorded by the 40Ar-39Ar system

We studied three lithologies (light and dark chondritic and impact melt rock) differing in shock stage from the LL5 chondrite Chelyabinsk. Using the ⁴⁰Ar-³⁹Ar dating technique, we identified low- and high-temperature reservoirs within all samples, ascribed to K-bearing oligoclase feldspar and shock-induced jadeite–feldspar glass assemblages in melt veins, respectively. Trapped argon components had variable ⁴⁰Ar/³⁶Ar ratios even within low- and high-temperature reservoirs of individual samples. Correcting for trapped argon revealed a lithology-specific response of the K-Ar system to shock metamorphism, thereby defining two distinct impact events affecting the Chelyabinsk parent asteroid (1) an intense impact event ~1.7 ± 0.1 Ga ago formed the light–dark-structured and impact-veined Chelyabinsk breccia. Such a one-stage breccia formation is consistent with petrological observations and was recorded by the strongly shocked lithologies (dark and impact melt) where a significant fraction of oligoclase feldspar was transformed into jadeite and feldspathic glass; and (2) a young reset event ~30 Ma ago particularly affected the light lithology due to its low argon retentivity, while the more retentive shock-induced phases were more resistant against thermal reset. Trapped argon with ⁴⁰Ar/³⁶Ar ratios up to 1900 was likely incorporated during impact-induced events on the parent body, and mixed with terrestrial atmospheric argon contamination. Had it not been identified via isochrons based on high-resolution argon extraction, several geochronologically meaningless ages would have been deduced.     

Automated placement of supplementary contour lines

Supplementary contour lines are placed between regular contour lines to visualize small but important forms that regular contour lines are unable to show. On topographic maps, typical forms are hillcrests, depressions, saddles, terraces, banks, and levees. No automated method for the selection of supplementary contour lines has been described so far. We document cartographic design principles for the selection of supplementary contour lines for topographic maps, and present an automated method for their placement. Results of the automated method are similar to manually placed supplementary contour lines. Our method helps map authors to create contour line maps that more effectively illustrate relevant small details in maps showing terrain elevation or other scalar fields.