Trace metal contamination of Beaufort's Dyke, North Channel, Irish Sea: a legacy of ordnance disposal

Beaufort’s Dyke is a disused ordnance disposal ground within the North Channel of the Irish Sea. Over 1 million tonnes of ordnance were disposed of in the dyke over a 40 year period representing a substantial volume of trace metal pollutants introduced to the seabed. Utilising particle transport modelling software we simulated the potential transport of metal particles from Beaufort’s Dyke over a 3 month period. This demonstrated that Beaufort’s Dyke has the potential to act as a source for trace metal contamination to areas beyond the submarine valley. Trace metal analysis of sediments from the Dyke and surrounding National Marine Monitoring Programme areas demonstrate that the Dyke is not the most contaminated site in the region. Particle transport modelling enables the transport pathways of trace metal contaminants to be predicted. Implementation of the technique in other munitions disposal grounds will provide valuable information for the selection of monitoring stations.     

Introduction to “Tsunamis in the World Ocean: Past,Present, and Future. Volume II”

Fifteen papers are included in Volume 2 of a PAGEOPH topical issue Tsunamis in the World Ocean: Past, Present, and Future. These papers are briefly introduced. They are grouped into three categories: reports and studies of recent tsunamis, studies on tsunami statistics and application to tsunami warning, and modeling studies of tsunami runup and inundation. Most of the papers were presented at the 24th International Tsunami Symposium held 14–16 July 2009 in Novosibirsk, Russia, and reflect the current state of tsunami science.     

Correlation Between Local Slip Rate and Local High-frequency Seismic Radiation in an Earthquake Fault

For any earthquake, the slipping fault and the source of high-frequency seismic waves, by and large, coincide. On a more local scale, however, the areas of high seismic slip rate and of increased high-frequency radiation output (seismic luminosity) need not match. To study in some detail how slip rate and seismic luminosity are interrelated, a systematic study is performed that uses 251 records of teleseismic P waves from 23 intermediate-depth earthquakes of magnitude 6.8 and above. From a broadband trace we extract two time histories: (1) displacement and (2) 0.5–2.5 Hz band-passed and squared velocity, or ``HF power', and calculate correlation coefficient, ρ between the two. To reduce the bias related to formation of P coda, a special procedure is applied to data. We estimated the average value ρ = 0.52 (range of event averages 0.35 to 0.65) for the correlation coefficient between the radiated time histories for displacement and ``HF power', which is considerably below the ``ideal' value of unity. We argue that the same or even lower value characterizes the degree of slip rate - seismic luminosity correlation at the fault. Two factors may contribute to the revealed decorrelation: (1) random fluctuations of observed HF power (inevitable for a signal with a limited bandwidth), and (2) the genuine mismatch of slip rate and mean luminosity. We show that these factors, acting separately, would result in the ρ values equal to, correspondingly, 0.72 and 0.80. We also show that genuine decorrelation is statistically significant. We conclude that the observed values of ρ indicate genuine differences between the distributions of the slip rate and the seismic luminosity over the fault area. These results provide important constraints both for the accurate wide-band simulation of strong ground motion and for theoretical dynamic source models.     

Constraining water age dynamics in a south-eastern Australian catchment using an age-ranked storage and stable isotope approach

Improving our knowledge of the travel times of water through catchments is critical for the management and protection of water resources and to improve our understanding of fundamental catchment behaviour. In this study we use the age-ranked storage framework StorAge Selection (SAS) to investigate travel times in the Corin catchment, a headwater catchment in the south-east of Australia covered by native Eucalyptus species. Few studies have applied the SAS framework globally and in energy-intensive areas where catchment losses are heavily in favour of evapotranspiration relative to streamflow. A combination of observed and modelled values of oxygen-18 (δ¹⁸O ), the stable isotope in water, are used to constrain storage selection preferences of streamflow and evapotranspiration and the size of the catchment active storage. The highest performing parameter combinations that could reproduce δ¹⁸O in streamflow were dependent on a strong preference for young water in evapotranspiration, and a mixture of weak young and old water preference in streamflow. The mean travel time of streamflow over the study period 2007–2019, weighted by the flow rate, is limited to within a probable range of 2.81–9.77 years. The size of the active storage, a key parameter in the SAS framework, was poorly identified, and in combination with the isotopic inputs into the model, contributed to the uncertainty of the results. We discuss the implications of the results with respect to the study area, as well as within the context of SAS research globally and identify ways to improve the modelling process.     

A taxonomy of quality assessment methods for volunteered and crowdsourced geographic information

The growing use of crowdsourced geographic information (CGI) has prompted the employment of several methods for assessing information quality, which are aimed at addressing concerns on the lack of quality of the information provided by non‐experts. In this work, we propose a taxonomy of methods for assessing the quality of CGI when no reference data are available, which is likely to be the most common situation in practice. Our taxonomy includes 11 quality assessment methods that were identified by means of a systematic literature review. These methods are described in detail, including their main characteristics and limitations. This taxonomy not only provides a systematic and comprehensive account of the existing set of methods for CGI quality assessment, but also enables researchers working on the quality of CGI in various sources (e.g., social media, crowd sensing, collaborative mapping) to learn from each other, thus opening up avenues for future work that combines and extends existing methods into new application areas and domains.     

Future global SLR network evolution and its impact on the terrestrial reference frame

Satellite laser ranging (SLR) is an important technique that contributes to the determination of terrestrial geodetic reference frames, especially to the realization of the origin and the scale of global networks. One of the major limiting factors of SLR-derived reference frame realizations is the datum accuracy which significantly suffers from the current global SLR station distribution. In this paper, the impact of a potential future development of the SLR network on the estimated datum parameters is investigated. The current status of the SLR network is compared to a simulated potential future network featuring additional stations improving the global network geometry. In addition, possible technical advancements resulting in a higher amount of observations are taken into account as well. As a result, we find that the network improvement causes a decrease in the scatter of the network translation parameters of up to 24%, and up to 20% for the scale, whereas the technological improvement causes a reduction in the scatter of up to 27% for the translations and up to 49% for the scale. The Earth orientation parameters benefit by up to 15% from both effects.     

An Exploration of Future Patterns of the Contributions to OpenStreetMap and Development of a Contribution Index

OpenStreetMap (OSM) represents one of the most well‐known examples of a collaborative mapping project. Major research efforts have so far dealt with data quality analysis but the modality of OSM's evolution across space and time has barely been noted. This study aims to analyze spatio‐temporal patterns of contributions in OSM by proposing a contribution index (CI) in order to investigate the dynamism of OSM. The CI is based on a per cell analysis of the node quantity, interactivity, semantics, and attractivity (the ability to attract contributors). Additionally this research explores whether OSM has been constantly attracting new users and contributions or if OSM has experienced a decline in its ability to attract continued contributions. Using the Stuttgart region of Germany as a case study the empirical findings of the CI over time confirm that since 2007, OSM has been constantly attracting new users, who create new features, edit the existing spatial objects, and enrich them with attributes. This rate has been dramatically growing since 2011. The utilization of a Cellular Automata‐Markov (CA‐Markov) model provides evidence that by the end of 2016 and 2020, the rise of CI will spread out over the study area and only a few cells without OSM features will remain.     

Land cover dynamics monitoring with Landsat data in Kunming,China: a cost-effective sampling and modelling scheme using Google Earth imagery and random forests

Changes in forest composition impact ecological services, and are considered important factors driving global climate change. A hybrid sampling method along with a modelling approach to map current and past land cover in Kunming, China is reported. MODIS land cover (2001–2011) data-sets were used to detect pixels with no apparent change. Around 3000 ‘no change points’ were systematically selected and sampled using Google Earth’s high-resolution imagery. Thirty-five per cent of these points were verified and used for training and validation. We used Random forests to classify multi-temporal Landsat imagery. Results show that forest cover has had a net decrease of 14385?ha (1.3% of forest area), which was primary converted to shrublands (11%), urban and barren land (2.7%) and agriculture (2.5%). Our validation indicates an overall accuracy (Kappa) of 82%. Our methodology can be used to consistently map the dynamics of land cover change in similar areas with minimum costs.     

Backscatter coefficient as an attribute for the classification of full-waveform airborne laser scanning data in urban areas

Airborne laser scanning (ALS) data are increasingly being used for land cover classification. The amplitudes of echoes from targets, available from full-waveform ALS data, have been found to be useful in the classification of land cover. However, the amplitude of an echo is dependent on various factors such as the range and incidence angle, which makes it difficult to develop a classification method which can be applied to full-waveform ALS data from different sites, scanning geometries and sensors. Additional information available from full-waveform ALS data, such as range and echo width, can be used for radiometric calibration, and to derive backscatter cross section. The backscatter cross section of a target is the physical cross sectional area of an idealised isotropic target, which has the same intensity as the selected target. The backscatter coefficient is the backscatter cross section per unit area. In this study, the amplitude, backscatter cross section and backscatter coefficient of echoes from ALS point cloud data collected from two different sites are analysed based on urban land cover classes. The application of decision tree classifiers developed using data from the first study area on the second demonstrates the advantage of using the backscatter coefficient in classification methods, along with spatial attributes. It is shown that the accuracy of classification of the second study area using the backscatter coefficient (kappa coefficient 0.89) is higher than those using the amplitude (kappa coefficient 0.67) or backscatter cross section (kappa coefficient 0.68). This attribute is especially useful for separating road and grass.     

Acid catalysis of alkyl hydrogen exchange and configurational isomerisation reactions: acyclic isoprenoid acids

Acid-catalysed alkyl hydrogen exchange and configurational isomerisation has been studied in a series of acyclic isoprenoid acids when they were heated at 160°C in the presence of a montmorillonite. Hydrogen exchange occurred between the adsorbed water of the clay surface and the a position of the isoprenoid acids. In cases where this position was chiral, exchange was accompanied by configurational isomerisation. Configurational isomerisation occurred more slowly in experiments conducted without a clay matrix in the presence of water. These results have been rationalized in terms of a reaction mechanism involving protonation of the carbonyl oxygen causing enolization and consequent hydrogen exchange at the a position of the acids. This mechanism was used to account for the relatively fast rate of isomerisation of C-2 chiral centres in sedimentary acyclic isoprenoid acids during maturation.