Modelling of deformation response and chemo‐mechanical coupling in chalk

A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.     

A major sulphur isotope event at c. 510 Ma: a possible anoxia–extinction–volcanism connection during the Early–Middle Cambrian transition?

A new approach to constraining seawater δ³⁴S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ³⁴S to +50‰ around the Early–Middle Cambrian boundary. Such high δ³⁴S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL^?1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ³⁴S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006     

Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

On The Concept Of Periapsis In Hill’s Problem

The concept of closest approach is analyzed in Hill’s problem, resulting in a partitioning of the position space. The different behavior between the direct and retrograde motion is explained analytically, resulting in a simple estimate of the variation of Hill’s periodic and quasi-circular orbits as a function of the Jacobi constant. The local behavior of the orbits on the zero velocity surfaces and an analytical definition of local escape and capture in Hill’s problem are also given.     

TRIFFID observations of the cores of the three globular clusters M15, M92 and NGC 6712

We present the results of TRIFFID simultaneous V - and B -band observations of the cores of the globular clusters M15, M92 and NGC 6712. A variability search of their dense centres was made feasible through performing post-exposure image sharpening on the images, increasing the image resolution by a factor of ∼2. The isis implementation of the image subtraction technique developed by Alard & Lupton was then used to detect flux variations in our image sets. We have obtained periods for all observable variables (in our field of view) in NGC 6712 and we have found two new RR Lyrae variables (an RRab and an RRc). We have confirmed three variables in our field of view of the M92. For M15, we detect 48 variables in our field of view, 23 of which are new discoveries. We obtain periods and amplitudes for all variables and classify new ones based on the light-curve shape, the most significant period and the mean magnitude in the V band. Among the detected RR Lyrae we find 19 RRc, 12 RRab and two RRd types. In the subsequent analysis we find a marked increase in RRc over RRab variables in the core. In a refined procedure to search for fainter objects we find no dwarf novae in our field of view of M15. Simulations performed on the data set to quantify our sensitivity to such objects indicate that an upper limit of 10 dwarf novae (at 92 per cent probability) exist in our field of view. The implications this result has on globular clusters are discussed.     

The D-CIXS X-ray mapping spectrometer on SMART-1

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.