Geophysical models for the tectonic framework of the Lake Vostok region, East Antarctica

Aerogeophysical and seismological data from a geophysical survey in the interior of East Antarctica were used to develop a conceptual tectonic model for the Lake Vostok region. The model is constrained using three independent data sets: magnetic, seismic, and gravimetric. A distinct change in the aeromagnetic anomaly character across Lake Vostok defines a crustal boundary. Depth to magnetic basement estimates image a 400-km-wide and more than 10-km-deep sedimentary basin west of the lake. Analysis of teleseismic earthquakes suggests a relatively thin crust beneath Lake Vostok consistent with predictions from kinematic and flexural gravity modelling. Magnetic, gravity, and subglacial topography data reveal a tectonic boundary within East Antarctica. Based on our kinematic and flexural gravity modelling, this tectonic boundary appears to be the result of thrust sheet emplacement onto an earlier passive continental margin. No data presently exist to date directly either the timing of passive margin formation or the subsequent shortening phase. The preserved thrust sheet thickness is related to the thickness of the passive margin crust. Because a significant amount of time is required to erode the thrust sheet topography, we suggest that these tectonic events are Proterozoic in age. Minor normal reactivation of the thrust sheet offers a simple mechanism to explain the formation of the Lake Vostok Basin. A low level of seismicity exists in the vicinity of this tectonic boundary. The existence of a crustal boundary in the Antarctic interior provides new constraints on the Proterozoic architecture of the East Antarctic craton.     

Isotopic exchange of carbon-bound hydrogen over geologic timescales

The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50-100°C) exchange likely occurs on timescales of 10⁴ to 10⁸ yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (<1 Ma), cool sediments, but strong evidence for exchange in ancient (>350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity.Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D₂O indicate that the number of D atoms incorporated during structural rearrangements can be far less than the number of C-H bonds that are broken. Sample calculations indicate that, for steranes in immature sediments, the D/H ratio imparted by biosynthesis may be largely preserved in spite of significant structural changes.     

Extraterrestrial accretion from the GISP2 ice core

The rate of extraterrestrial accretion for particles in the size range 0.45 μm to ∼20 μm was determined from dust concentrates extracted from Greenland Ice Sheet Project 2 (GISP2) ice core samples. Using instrumental neutron activation analysis (INAA), we determined the iridium (Ir) content of the dust. Following a core-specific correction for terrestrial Ir and assuming a chondritic Ir abundance of 500 ppb, we measure an average accretion rate for 0.45 μm to ∼20 μm particles over the entire Earth of 0.22 (± 0.11) × 10⁹ g/yr (kton/yr) for 317 years of ice through the interval 6 to 20 ka. This is consistent with the interplanetary dust accretion rate of 0.17 (± 0.08) x 10⁹ g/yr that we derive from published ³He data for the GISP2 core. Accounting for particles that are larger and smaller than those detected by or experiment, our best estimate of the total accretion rate (including particle sizes up to about 4 cm in diameter) is 2.5 × 10⁹ g/yr. The uncertainty in this estimate is dominated by statistical fluctuations in the number of particles expected to end up in the ice core and not by measurement error. Based on Monte Carlo simulations, we estimate the upper limit for total extraterrestrial accretion to Earth of 6.25 × 10⁹ g/yr (95% confidence level). This accretion rate is consistent with some estimates from micrometeorite concentrations in polar ice, estimates from ground-based radar studies, and with accretion estimates of ³He-bearing interplanetary dust particles, assuming that ³He is correlated with particle surface area. It is, however, lower than estimates based on platinum group element studies of marine sediments. The conflict may indicate systematic errors with either the marine or the non-marine samples, departures from the assumed particle spectrum of Grün and coauthors, or time-variable accretion rates, with the early Holocene period being characterized by low levels of accretion.     

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.     

Sub-ice geology inland of the Transantarctic Mountains in light of new aerogeophysical data

The Transantarctic Mountains are a major geologic boundary that bisects the Antarctic continent, separating the low-lying, tectonically active terrains of West Antarctica from the East Antarctic craton. A new comprehensive aerogeophysical data set, extending 1150 km from the Ross Sea into the interior of East Antarctica provides insights into the complex structure inland of the Transantarctic Mountains. Geophysical maps, compiled from 21 000 km of gravity, magnetic and subglacial topography data, outline the boundaries of several geologic and tectonic segments within the survey area. The coherent pattern in magnetic data and mesa topography suggests a subglacial extent of the Transantarctic Mountains 400–500 km inland the last exposed rock outcrops. We estimate the maximum thickness of a potential sediment infill in the Wilkes Subglacial Basin to be less than 1 km, based on gravity modeling and source depth estimates from magnetic data. The coherent nature of the potential field and topography data, together with the northwest–southeast trends, define the Adventure Subglacial Trench and the Resolution Subglacial Highlands as a tectonic unit. The crustal structure and the strong similarity of the observed gravity with fold-and-thrust belts suggest a compressional scenario for the origin of the Adventure Subglacial Trench and the Resolution Subglacial Highlands. The complexity and apparent structural control of the Wilkes Subglacial Basin raise the issue of what influence pre-existing structures may have played in the formation of the Transantarctic Mountains system. The previous hypothesis of a thermal boundary beneath the mountains is difficult to reconcile with our new gravity data. The apparent difficulties to match our new data with certain key aspects of previous models suggests that a reassessment of the existing uplift models is necessary. We have modeled the prominent gravity anomaly over the Transantarctic Mountains with thicker crust.     

Vertical exchange due to horizontal density gradients in lakes; the case of Lake Lucerne

Recent field investigations have shown that differential mixing causes a significant density driven exchange between the two eastern basins of Lake Lucerne, Gersauersee and Urnersee. The long term vertical mixing characteristics during the winter mixing period and the influence of the resulting exchange flow on water quality are examined through the analysis of ten years (1964 to 1974) of monthly limnological data. Vertical homogenization of the state variables (temperature, electric conductivity and density) occurred on average once every two years in Urnersee, but not once in Gersauersee where the ten year average winter mixed-layer depth extended to 120 m. In Urnersee intense mixing was evident over the whole water column for every year. In contrast intense mixing in the deeper layers of Gersauersee occurred approximately once every four years. A three layer model shows that theT/ ₂₀ signature of the Gersauersee intermediate water correlates best with the Urnersee deep water confirming the regular occurrence of a density driven exchange. For the lower layers the oxygen consumption rate in Urnersee was approximately twice that for Gersauersee. It appears the exchange flow can act either as a source or sink for the oxygen balance of Urnersee deep water. The larger rate in Urnersee hypolimnion might also be associated with the larger sediment input to this system. Density driven exchange resulting from differential mixing is probably an important contribution to the vertical water replenishment in many lakes.     

Chemical weathering of a marine terrace chronosequence, Santa Cruz, California I: Interpreting rates and controls based on soil concentration-depth profiles

The spatial and temporal changes in element and mineral concentrations in regolith profiles in a chronosequence developed on marine terraces along coastal California are interpreted in terms of chemical weathering rates and processes. In regoliths up to 15 m deep and 226 kyrs old, quartz-normalized mass transfer coefficients indicate non-stoichiometric preferential release of Sr > Ca > Na from plagioclase along with lesser amounts of K, Rb and Ba derived from K-feldspar. Smectite weathering results in the loss of Mg and concurrent incorporation of Al and Fe into secondary kaolinite and Fe-oxides in shallow argillic horizons. Elemental losses from weathering of the Santa Cruz terraces fall within the range of those for other marine terraces along the Pacific Coast of North America.Residual amounts of plagioclase and K-feldspar decrease with terrace depth and increasing age. The gradient of the weathering profile b_s is defined by the ratio of the weathering rate, R to the velocity at which the profile penetrates into the protolith. A spreadsheet calculator further refines profile geometries, demonstrating that the non-linear regions at low residual feldspar concentrations at shallow depth are dominated by exponential changes in mineral surface-to-volume ratios and at high residual feldspar concentrations, at greater depth, by the approach to thermodynamic saturation. These parameters are of secondary importance to the fluid flux q_h, which in thermodynamically saturated pore water, controls the weathering velocity and mineral losses from the profiles. Long-term fluid fluxes required to reproduce the feldspar weathering profiles are in agreement with contemporary values based on solute Cl balances (q_h = 0.025-0.17 m yr⁻¹).During saturation-controlled and solute-limited weathering, the greater loss of plagioclase relative to K-feldspar is dependent on the large difference in their respective solubilities instead of the small difference between their respective reaction kinetics. The steady-state weathering rate under such conditions is defined as

     

Multiscale Edge Detection in the Corona

Coronal Mass Ejections (CMEs) are challenging objects to detect using automated techniques, due to their high velocity and diffuse, irregular morphology. A necessary step to automating the detection process is to first remove the subjectivity introduced by the observer used in the current, standard, CME detection and tracking method. Here we describe and demonstrate a multiscale edge detection technique that addresses this step and could serve as one part of an automated CME detection system. This method provides a way to objectively define a CME front with associated error estimates. These fronts can then be used to extract CME morphology and kinematics. We apply this technique to a CME observed on 18 April 2000 by the Large Angle Solar COronagraph experiment (LASCO) C2/C3 and a CME observed on 21 April 2002 by LASCO C2/C3 and the Transition Region and Coronal Explorer (TRACE). For the two examples in this work, the heights determined by the standard manual method are larger than those determined with the multiscale method by ≈10% using LASCO data and ≈20% using TRACE data.