Testing and calibrating parametric wave transformation models on natural beaches

To provide coastal engineers and scientists with a detailed inter-comparison of widely used parametric wave transformation models, several models are tested and calibrated with extensive observations from six field experiments on barred and unbarred beaches. Using previously calibrated (“default”) values of a free parameter γ, all models predict the observations reasonably well (median root-mean-square wave height errors are between 10% and 20%) at all field sites. Model errors can be reduced by roughly 50% by tuning γ for each data record. No tuned or default model provides the best predictions for all data records or at all experiments. Tuned γ differ for the different models and experiments, but in all cases γ increases as the hyperbolic tangent of the deep-water wave height, H_o. Data from two experiments are used to estimate empirical, universal curves for γ based on H_o. Using the new parameterization, all models have similar accuracy, and usually show increased skill relative to using default γ.     

Determination of Precise and Accurate 51V/50V Isotope Ratios by Multi‐Collector ICP‐MS,Part 2: Isotopic Composition of Six Reference Materials plus the Allende Chondrite and Verification Tests

We present the first measurements of vanadium (V) stable isotopes for six reference materials – USGS PCC‐1, BHVO‐2, BCR‐2, BIR‐1a, GSP‐2 and AGV‐2 – plus the widely available carbonaceous chondrite Allende. We present standard addition and matrix spiking tests to assess the robustness and reproducibility of our data. Standard addition utilised an enriched ⁵⁰V solution designated VISSOX (Vanadium Isotope Standard Solution OXford). We further assessed the veracity of the method by spiking collected sample matrices with the same amount of a V standard solution, whose isotopic composition was defined as 0‰. Standard addition and matrix spiking tests recorded no appreciable artificial isotope fractionation. We estimate that the best currently attainable long‐term reproducibility of stable ⁵¹V/⁵⁰V isotope measurements in complex matrices is 0.15‰, which is in the same order as the reproducibility achievable with standard solutions. Finally, a large range of ～ 1.2‰ in stable V isotopic composition was documented, with ～ 0.5‰ of that variation in high temperature igneous materials alone. The range and resolving power of V stable isotopes, with respect to igneous material, compared favourably with the magnitude of fractionation reported for other non‐traditional stable isotope systems, which bodes well for the utility of this new system.     

Bias in the analysis of geological materials for gold using current methods

A consistent pattern has been observed in the results obtained for Au in three soil and two porphyry copper ore samples serving as control reference standards in geochemical analyses. The mean reported by wet chemical methods (regardless of the measurement technique) was less than the mean by fire assay-based methods which, in turn, was less than the mean reported by laboratories using direct instrumental neutron activation analysis (INAA). These data have been obtained from 16 laboratories, some employing more than one method. Compared to INAA, values obtained for Au (at the 30–300 ppb level) using aqua regia (AR) dissolution were low by 24–42%, while those reported by fire assay-based methods were low by 14–26%.Studies of these samples and 32 rocks of widely varying composition revealed that the amount of Au remaining in the residue after AR attack ranged from 4% to 59% of the total. Gold dissolved by AR was determined by graphite furnace atomic absorption spectrometry (GFAAS) after extraction into MIBK (methyl isobutyl ketone), whereas Au remaining in the residue was determined by INAA. The slope of the line obtained by plotting Au by INAA vs. the sum of Au by AR/GFAAS and Au in the residue was not significantly different from 1.0.Modifications to the AR procedure such as prior attack by HCl or HF did not improve the recovery of Au in the three reference soils. However, reduction of sample size from 10 g to 1 g while maintaining the volume of AR at about 30 ml did increase results for Au. Furthermore, addition of HF in the attack on 1-g samples yielded results virtually identical to those obtained by INAA. It is thought that the poor extraction efficiency by AR is due to non-wetting of the larger sized sample, a lack of intimate, prolonged contact between the grains of the sample and the acid mixture and the presence of insoluble gangue surrounding Au particles. Constant agitation of the sample during evaporation with AR is desirable.The mean values obtained for Au in the soils by fire assay methods were not significantly different from the results by INAA (low by 14–19%); this was not the case for the two copper ore samples (low by 26%). This probably reflects the difficulties encountered in fire assay by high concentrations of Cu which hinder effective collection and separation of Au into the Pb button. However, the accuracy of the INAA method has not been established and is dependent upon measurement procedures and the degree of certainty associated with the Au values assumed for the reference materials employed for calibration. While estimation of precision does not present a problem, accuracy is difficult to assess in the absence of certified reference materials for Au at concentrations in the 10–300 ppb range. However, it is concluded that methods based upon AR dissolution can lead to low results, the magnitude being dependent upon the sample matrix and the mineralogical association of the Au present.     

A Landsat surface reflectance dataset for North America, 1990-2000

The Landsat Ecosystem Disturbance Adaptive Processing System (LEDAPS) at the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center has processed and released 2100 Landsat Thematic Mapper and Enhanced Thematic Mapper Plus surface reflectance scenes, providing 30-m resolution wall-to-wall reflectance coverage for North America for epochs centered on 1990 and 2000. This dataset can support decadal assessments of environmental and land-cover change, production of reflectance-based biophysical products, and applications that merge reflectance data from multiple sensors [e.g., the Advanced Spaceborne Thermal Emission and Reflection Radiometer, Multiangle Imaging Spectroradiometer, Moderate Resolution Imaging Spectroradiometer (MODIS)]. The raw imagery was obtained from the orthorectified Landsat GeoCover dataset, purchased by NASA from the Earth Satellite Corporation. Through the LEDAPS project, these data were calibrated, converted to top-of-atmosphere reflectance, and then atmospherically corrected using the MODIS/6S methodology. Initial comparisons with ground-based optical thickness measurements and simultaneously acquired MODIS imagery indicate comparable uncertainty in Landsat surface reflectance compared to the standard MODIS reflectance product (the greater of 0.5% absolute reflectance or 5% of the recorded reflectance value). The rapid automated nature of the processing stream also paves the way for routine high-level products from future Landsat sensors.     

Avoiding Dangerous Anthropogenic Interference with the Climate System

The UN Framework Convention on Climate Change calls for the avoidance of “dangerous anthropogenic interference with the climate system”. Among the many plausible choices, dangerous interference with the climate system may be interpreted as anthropogenic radiative forcing causing distinct and widespread climate change impacts such as a widespread demise of coral reefs or a disintegration of the West Antarctic ice sheet. The geological record and numerical models suggest that limiting global warming below critical temperature thresholds significantly reduces the likelihood of these eventualities. Here we analyze economically optimal policies that may ensure this risk-reduction. Reducing the risk of a widespread coral reef demise implies drastic reductions in greenhouse gas emissions within decades. Virtually unchecked greenhouse gas emissions to date (combined with the inertia of the coupled natural and human systems) may have already committed future societies to a widespread demise of coral reefs. Policies to reduce the risk of a West Antarctic ice sheet disintegration allow for a smoother decarbonization of the economy within a century and may well increase consumption in the long run.     

植物挥发性有机物的分析方法

为了分析植物排放到大气中的挥发性有机物，在2000年1-6月期间，与美国国家大气研究中心（NCAR）的科学家共同发展和研究了一套自动的气相色谱系统和分析方法。该系统引入一个小型冰箱以除去空气样品进样时的水分，得到了对挥发性有机物样品进行分析时比较好的准确度。在5℃以及稳定的进样速率的条件下，可以得到比较好的除水效果。对NCAR附近的大气进行了采样，并利用此系统做了分析。本简单介绍此自动系统以及样品分析结果。实验结果表明，此套系统具有良好的重复性和稳定性，主要的挥发性有机物的成分如异戊二烯和单萜烯等具有明显的日变化。     

Composite detrital and thermal remanent magnetization in tuffs from Aeolian Islands (southern Tyrrhenian Sea) revealed by magnetic anisotropy

This paper reports on the complex relation between rock emplacement and remanence acquisition in tuffs deposited by pyroclastic density currents, disclosed by systematic measurements of the anisotropy of magnetic susceptibility and natural remanent magnetization (NRM). Thermal demagnetization shows that the NRM consists of two components with different blocking-temperature spectra. The direction of the low-temperature component is consistent with the geocentric axial dipole value, whereas the high-temperature component has dispersed directions. The magnetic fabric is oblate, the magnetic foliation is close to the bedding and the lineations are generally dispersed along a girdle within the foliation plane. The directions of the magnetic lineation and the high-temperature remanence component of individual specimens are close to each other. This correspondence suggests that the high blocking-temperature grains acquired a remanence aligned to their long dimension before deposition, while cooling within the explosive cloud and the moving pyroclastic current. Thereafter, during deposition, the traction processes at the base of the current oriented the grains along the flow direction and affected both fabric and high-temperature remanence. This NRM component results from mechanical orientation of previously magnetized grains and is thus detrital in origin. A second, thermal component was then acquired during the cooling of the low blocking-temperature grains after deposition. These results show that NRM in fine-grained pyroclastic rocks is affected by the Earth’s magnetic field as well as the emplacement processes and that magnetic fabric data are essential to unravel its complex nature.     

Dynamical controls on the diurnal cycle of temperature in complex topography

We examine the climatological diurnal cycle of surface air temperature in a 6 km resolution atmospheric simulation of Southern California from 1995 to the present. We find its amplitude and phase both have significant geographical structure. This is most likely due to diurnally-varying flows back and forth across the coastline and elevation isolines resulting from the large daily warming and cooling over land. Because the region’s atmosphere is generally stably stratified, these flow patterns result in air of lower (higher) potential temperature being advected upslope (downslope) during daytime (nighttime). This suppresses the temperature diurnal cycle amplitude at mountaintops where diurnal flows converge (diverge) during the day (night). The nighttime land breeze also advects air of higher potential temperature downslope toward the coast. This raises minimum temperatures in land areas adjacent to the coast in a manner analogous to the daytime suppression of maximum temperature by the cool sea breeze in these same areas. Because stratification is greater in the coastal zone than in the desert interior, these thermal effects of the diurnal winds are not uniform, generating spatial structures in the phase and shape of the temperature diurnal cycle as well as its amplitude. We confirm that the simulated characteristics of the temperature diurnal cycle as well as those of the associated diurnal winds are also found in a network of 30 observation stations in the region. This gives confidence in the simulation’s realism and our study’s findings. Diurnal flows are probably mainly responsible for the geographical structures in the temperature diurnal cycle in other regions of significant topography and surface heterogeneity, their importance depending partly on the degree of atmospheric stratification.     

Land use change effects on catchment streamflow response in a humid tropical montane cloud forest region,central Veracruz,Mexico

Tropical montane cloud forests (TMCF) are recognized for their capacity to maintain high dry-season baseflow and a host of other ecosystem services. Substantial areas of TMCF have been converted to pasture and crops such as coffee, while in other areas TCMF are recovering. However, little is known about the effects of this complex dynamic on catchment hydrology. We investigated the effect of land use on rainfall-runoff response in five neighbouring headwater micro-catchments in central Veracruz, Mexico, dominated by either mature TMCF (MF), young (20 year-old) and intermediate (40 year-old) naturally regenerating TMCF (YF and IF, respectively), shaded coffee (SC), and an intensively grazed pasture (IP). We used a 4-year record of high-resolution rainfall and streamflow (10 min) data collected from 2015 to 2019. These data were analysed via comparison of hydrologic metrics that summarize streamflow responses at various time scales and magnitudes. Results showed no statistical difference in the regulation capacity of high flows in the micro-catchment with 20 years of natural regeneration, compared to the MF. In terms of baseflow sustenance, our results support the hypothesis that MF and IF better promote this hydrologic service than the other land uses. SC exhibited a high capacity to modulate peak flows comparable to that of MF, and an intermediate capacity to sustain baseflow, suggesting that the integrated functioning of this micro-catchment was largely preserved. Finally, 40 years of intense pasture management was found to have degraded the soil hydraulic properties of IP; mainly, reducing its infiltration capacity, causing a fivefold greater peak flow response and a lower baseflow compared to MF.