Elastic properties and stability of coexisting 3T and 2M 1 phengite polytypes

The elastic properties of coexisting natural 3T and 2M ₁ phengite samples (Cima Pal, Sesia Zone; Val Savenca; Western Alps, Italy) with similar chemical compositions have been studied by room temperature–high pressure powder diffraction, using synchrotron radiation on the ID9A beam-line at ESRF (Grenoble, France). The P–V curves have been modelled by the Birch–Murnaghan model; a third-order expansion fitted to the experimental data yields for 3T and 2M ₁ K ₀=60.4(±0.7) GPa, K′=5.79(±0.11) at V ₀=703.8851 ų, and K ₀=57.3(±1.0) GPa, K′=6.97(±0.24) at V ₀=938.8815 ų, respectively. The relative stability of 3T vs. 2M ₁ has been explored as a function of pressure and temperature in terms of configuration and deformation contributions to the Gibbs energy, using the elastic properties determined here and other thermodynamic parameters from earlier investigations. The results presented agree with the hypothesis of stability of the 3T polytype in the high pressure regime.     

Resilience and brittleness in the ALERTA RIO system: a field study about the decision-making of forecasters

Natural disasters, particularly those triggered by heavy rainfall, may cause major damage and death. However, if an accurate early warning is issued, the damage can be mitigated. In Latin America and Brazil, characteristics of socioeconomic development often lead to a disorderly growth of cities and, consequently, occupation and irregular construction in risk areas. Therefore, forecasts of heavy rainfall, as well as preventative and mitigatory actions based on meteorological data/alerts, are essential to saving lives and minimizing material loss. An event that would have benefited from such actions is that which occurred in the mountainous region of Rio de Janeiro in January 2011, when over 800 people lost their lives. This work describes the first research initiative on resilience engineering domain in systems to forecast heavy rains in Rio de Janeiro. The results indicate important sources of brittleness in the system that supports the work of meteorologists, mainly related to the technical and organizational framework, and suggests that the main source of resilience in dealing with critical situations is the tacit knowledge of experts.     

Quality assessment of the Italian Landslide Inventory using GIS processing

Landslides constitute one of the most important natural hazards in Italy as they are widespread and result in considerable damage and fatalities every year. The Italian Landslide Inventory (IFFI) Project was launched in 1999 with the aim of identifying and mapping landslides over the entire Italian territory. The inventory currently holds over 480,000 landslides and has been available by means of Web services since 2005. The aim of this study is to define quality indices for evaluation of the homogeneity and completeness of the IFFI database. In order to estimate the completeness of the landslide attribute information, a heuristic approach has been used to assign weighting values to significant parameters selected from the landslide data sheet. The completeness and homogeneity of the landslide mapping has been evaluated by means of three different methods: an area-frequency distribution analysis; the proximity of the landslides surveyed to urban areas; variation of the landslide index within the same lithology. The quality indices have allowed identification of areas with a high level of completeness and critical areas in which the data collected have been underestimated or are not very accurate. The quality assessment of collected and stored data is essential in order to use the IFFI database for definition and implementation of landslide susceptibility models and for land use planning and management.     

Major changes in volcano behaviour after a sector collapse: insights from Stromboli, Italy

In recent years, increasing numbers of volcanoes are being recognized as having undergone large sector collapses. How far such events can change the succeeding behaviour of the volcano is poorly known, despite the importance for natural hazards and economic applications. By analysing the last 100‐kyr geological history of Stromboli (Italy), which has involved multiple collapses, this paper illuminates the feedback effect between sector collapse and magma upwelling and emplacement. The collapsed zone of Stromboli is episodically unbuttressed, draining magma preferentially with formation of eruptive centres in the collapse amphitheatre and dyking along the collapse shoulders. After a collapse, there were no further linear eruptions across the cone on opposing middle–lower slopes, but these occurred again after rebuilding of the cone. The time‐averaged eruption rate increased immediately before the first collapse and remained higher during the succeeding period of frequent collapses.     

Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.     

Structural evolution of a 2M 1 phengite mica up to 11 GPa: an in situ single-crystal X-ray diffraction study

The structural evolution at high pressure of a natural 2M ₁-phengite [(K_0.98Na_0.02)_Σ=1.00(Al_1.55Mg_0.24Fe_0.21Ti_0.02)_Σ=2.01(Si_3.38Al_0.62)O₁₀(OH)₂; a = 5.228(2), b = 9.057(3), c = 19.971(6)Å, β = 95.76(2)°; space group: C2/c] from the metamorphic complex of Cima Pal (Sesia Zone, Western Alps, Italy) was studied by single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions up to ~11 GPa. A series of 12 structure refinements were performed at selected pressures within the P range investigated. The compressional behaviour of the same phengite sample was previously studied up to ~25 GPa by synchrotron X-ray powder diffraction, showing an irreversible transformation with a drastic decrease of the crystallinity at P > 15–17 GPa. The elastic behaviour between 0.0001 and 17 GPa was modelled by a third-order Birch–Murnaghan Equation of State (BM-EoS), yielding to K _T0 = 57.3(10) GPa and K′ = ?K _T0/?P = 6.97(24). The single-crystal structure refinements showed that the significant elastic anisotropy of the 2M ₁-phengite (with β(a):β(b):β(c) = 1:1.17:4.60) is mainly controlled by the anisotropic compression of the K-polyhedra. The evolution of the volume of the inter-layer K-polyhedron as a function of P shows a negative slope, Fitting the P–V(K-polyhedron) data with a truncated second-order BM-EoS we obtain a bulk modulus value of K _T0(K-polyhedron) = 26(1) GPa. Tetrahedra and octahedra are significantly stiffer than the K-polyhedron. Tetrahedra behave as quasi-rigid units within the P range investigated. In contrast, a monotonic decrease is observed for the octahedron volume, with K _T0 = 120(10) GPa derived by a BM-EoS. The anisotropic response to pressure of the K-polyhedron affects the P-induced deformation mechanism on the tetrahedral sheet, consisting in a cooperative rotation of the tetrahedra and producing a significant ditrigonalization of the six-membered rings. The volume of the K-polyhedron and the value of the ditrigonal rotation parameter (α) show a high negative correlation (about 93%), though a slight discontinuity is observed at P >8 GPa. α increases linearly with P up to 7–8 GPa (with ?α/?P ≈ 0.7°/GPa), whereas at higher Ps a “saturation plateau” is visible. A comparison between the main deformation mechanisms as a function of pressure observed in 2M ₁- and 3T-phengite is discussed.     

Lithospheric flexure, uplift and expected horizontal strain rate in the Pannonian Carpathian region

The Apuseni Mountains are located between the Pannonian Basin and the Transylvanian Basin along a direction of SE convergence with the Carpathian belt. A flexural model based on the cylindrical bending of a semi-infinite, isostatically supported, thin elastic plate is here examined with the Apuseni playing the role of flexural bulge, and under the assumption that the plate is deforming under the action of a vertical shear force and a bending moment applied at the end of the plate, beneath the Carpathians. The model yields estimates of the plate thickness ranging between 13 and 14.5 km, depending on the assumed density contrast between crust/sediments and mantle providing buoyancy. The vertical shear force which is necessary to bend the plate is in the range between 60 and 300 × 10¹¹ N m^− 1, depending on the assumed density contrast. This force is shown to be modelled by a gravitational ‘slab pull’ force, using model parameters derived from seismic tomography. If the height of the flexural bulge, after correction for erosion, is allowed to increase, the model yields an estimate of the horizontal strain rate at the top of the bulge. For example, 5 mm/yr vertical change of the flexural bulge of a 14 km thick plate results in a horizontal deformation rate of approximately 7 nanostrain/yr at the top of the bulge, a value which is at the threshold of sensitivity of continuous GPS measurements. Different vertical rates will change the horizontal strain rate almost proportionally.     

Physical properties and petrologic description of rock samples from an IOCG mineralized area in the northern Fennoscandian Shield, Sweden

The Tjårrojåkka Fe–Cu-prospect in northern Sweden is considered an example of a Fe-oxide Cu–Au (IOCG) deposit and is hosted in metamorphosed Paleoproterozoic volcanic and intrusive rocks. Rock samples from 24 outcrops were collected for petrophysical analysis (magnetic susceptibility, remanent magnetization, variation of magnetic susceptibility with temperature, Curie temperature and density). The major Cu-prospect in the area has been studied by magnetic and electron microprobe analyses of four selected rock samples. The samples are from an exploration well that intersects the main Cu-mineralized body.The magnetic analyses show that magnetite is the dominant magnetic mineral, while hematite and other Fe-minerals are present in minor amounts. The electron microprobe observations confirm the presence of magnetite and further indicate that hematite is an alteration product of magnetite. Moreover, microprobe observations indicate that Fe-sulfides are present in negligible amounts in the samples from the Tjårrojåkka area. The strong spatial relationship of Cu-minerals (e.g., chalcopyrite) and the oxidation of magnetite to hematite suggest that the presence of rocks with low magnetic susceptibility in areas dominated by high susceptibility rocks may be a signal of related Cu-prospects.     

The thermal stability of sideronatrite and its decomposition products in the system Na2O–Fe2O3–SO2–H2O

The thermal stability of sideronatrite, ideally Na₂Fe³⁺(SO₄)₂(OH)·3(H₂O), and its decomposition products were investigated by combining thermogravimetric and differential thermal analysis, in situ high-temperature X-ray powder diffraction (HT-XRPD) and Fourier transform infrared spectroscopy (HT-FTIR). The data show that for increasing temperature there are four main dehydration/transformation steps in sideronatrite: (a) between 30 and 40 °C sideronatrite transforms into metasideronatrite after the loss of two water molecules; both XRD and FTIR suggest that this transformation occurs via minor adjustments in the building block. (b) between 120 and 300 °C metasideronatrite transforms into metasideronatrite II, a still poorly characterized phase with possible orthorhombic symmetry, consequently to the loss of an additional water molecule; X-ray diffraction data suggest that metasideronatrite disappears from the assemblage above 175 °C. (c) between 315 and 415 °C metasideronatrite II transforms into the anhydrous Na₃Fe(SO₄)₃ compound. This step occurs via the loss of hydroxyl groups that involves the breakdown of the [Fe³⁺(SO₄)₂(OH)] _∞ ^2? chains and the formation of an intermediate transient amorphous phase precursor of Na₃Fe(SO₄)₃. (d) for T > 500 °C, the Na₃Fe(SO₄)₃ compound is replaced by the Na-sulfate thenardite, Na₂SO₄, plus Fe-oxides, according to the Na₃Fe³⁺(SO₄)₃ → 3/2 Na₂(SO₄) + 1/2 Fe₂O₃ + SO_x reaction products. The Na–Fe sulfate disappears around 540 °C. For higher temperatures, the Na-sulfates decomposes and only hematite survives in the final product. The understanding of the thermal behavior of minerals such as sideronatrite and related sulfates is important both from an environmental point of view, due to the presence of these phases in evaporitic deposits, soils and sediments including extraterrestrial occurrences, and from the technological point of view, due to the use of these materials in many industrial applications.