H-bonding scheme and cation partitioning in axinite: a single-crystal neutron diffraction and Mössbauer spectroscopic study

The crystal chemistry of a ferroaxinite from Colebrook Hill, Rosebery district, Tasmania, Australia, was investigated by electron microprobe analysis in wavelength-dispersive mode, inductively coupled plasma–atomic emission spectroscopy (ICP–AES), ⁵⁷Fe Mössbauer spectroscopy and single-crystal neutron diffraction at 293 K. The chemical formula obtained on the basis of the ICP–AES data is the following: \( ^{X1,X2} {\text{Ca}}_{4.03} \,^{Y} \left( {{\text{Mn}}_{0.42} {\text{Mg}}_{0.23} {\text{Fe}}^{2 + }_{1.39} } \right)_{\varSigma 2.04} \,^{Z1,Z2} \left( {{\text{Fe}}^{3 + }_{0.15} {\text{Al}}_{3.55} {\text{Ti}}_{0.12} } \right)_{\varSigma 3.82} \,^{T1,T2,T3,T4} \left( {{\text{Ti}}_{0.03} {\text{Si}}_{7.97} } \right)_{\varSigma 8} \,^{T5} {\text{B}}_{1.96} {\text{O}}_{30} \left( {\text{OH}} \right)_{2.18} \). The ⁵⁷Fe Mössbauer spectrum shows unambiguously the occurrence of Fe²⁺ and Fe³⁺ in octahedral coordination only, with Fe²⁺/Fe³⁺ = 9:1. The neutron structure refinement provides a structure model in general agreement with the previous experimental findings: the tetrahedral T1, T2, T3 and T4 sites are fully occupied by Si, whereas the T5 site is fully occupied by B, with no evidence of Si at the T5, or Al or Fe³⁺ at the T1–T5 sites. The structural and chemical data of this study suggest that the amount of B in ferroaxinite is that expected from the ideal stoichiometry: 2 a.p.f.u. (for 32 O). The atomic distribution among the X1, X2, Y, Z1 and Z2 sites obtained by neutron structure refinement is in good agreement with that based on the ICP–AES data. For the first time, an unambiguous localization of the H site is obtained, which forms a hydroxyl group with the oxygen atom at the O16 site as donor. The H-bonding scheme in axinite structure is now fully described: the O16–H distance (corrected for riding motion effect) is 0.991(1) Å and an asymmetric bifurcated bonding configuration occurs, with O5 and O13 as acceptors [i.e. with O16···O5 = 3.096(1) Å, H···O5 = 2.450(1) Å and O16–H···O5 = 123.9(1)°; O16···O13 = 2.777(1) Å, H···O13 = 1.914(1) Å and O16–H···O13 = 146.9(1)°].     

Did Saturn's rings form during the Late Heavy Bombardment?

The origin of Saturn's massive ring system is still unknown. Two popular scenarios—the tidal splitting of passing comets and the collisional destruction of a satellite—rely on a high cometary flux in the past. In the present paper we attempt to quantify the cometary flux during the Late Heavy Bombardment (LHB) to assess the likelihood of both scenarios. Our analysis relies on the so-called “Nice model” of the origin of the LHB [Tsiganis, K., Gomes, R., Morbidelli, A., Levison, H.F., 2005. Nature 435, 459-461; Morbidelli, A., Levison, H.H., Tsiganis, K., Gomes, R., 2005. Nature 435, 462-465; Gomes, R., Levison, H.F., Tsiganis, K., Morbidelli, A., 2005. Nature 435, 466-469] and on the size distribution of the primordial trans-neptunian planetesimals constrained in [Charnoz, S., Morbidelli, A., 2007. Icarus 188, 468-480]. We find that the cometary flux on Saturn during the LHB was so high that both scenarios for the formation of Saturn rings are viable in principle. However, a more detailed study shows that the comet tidal disruption scenario implies that all four giant planets should have comparable ring systems whereas the destroyed satellite scenario would work only for Saturn, and perhaps Jupiter. This is because in Saturn's system, the synchronous orbit is interior to the Roche Limit, which is a necessary condition for maintaining a satellite in the Roche Zone up to the time of the LHB. We also discuss the apparent elimination of silicates from the ring parent body implied by the purity of the ice in Saturn's rings. The LHB has also strong implications for the survival of the saturnian satellites: all satellites smaller than Mimas would have been destroyed during the LHB, whereas Enceladus would have had from 40% to 70% chance of survival depending on the disruption model. In conclusion, these results suggest that the LHB is the “sweet moment” for the formation of a massive ring system around Saturn.     

Chandra and XMM–Newton observations of the low-luminosity X-ray pulsators SAX J1324.4−6200 and SAX J1452.8−5949

We present results from our Chandra and XMM–Newton observations of two low-luminosity X-ray pulsators  SAX J1324.4−6200  and  SAX J1452.8−5949  which have spin periods of 172 and 437 s, respectively. The XMM–Newton spectra for both sources can be fitted well with a simple power-law model of photon index,  Γ∼ 1.0  . A blackbody model can equally well fit the spectra with a temperature,   kT ∼  2 keV, for both sources. During our XMM–Newton observations,  SAX J1324.4−6200  is detected with coherent X-ray pulsations at a period of 172.86 ± 0.02 s while no pulsations with a pulse fraction greater than 18 per cent (at 95 per cent confidence level) in 0.2–12 keV energy band are detected in  SAX J1452.8−5949  . The spin period of  SAX J1324.4−6200  is found to be increasing on a time-scale of     which would suggest that the accretor is a neutron star and not a white dwarf. Using subarcsec spatial resolution of the Chandra telescope, possible counterparts are seen for both sources in the near-infrared images obtained with the son of infrared spectrometer and array camera (SOFI) instrument on the New Technology Telescope. The X-ray and near-infrared properties of  SAX J1324.4−6200  suggest it to be a persistent high-mass accreting X-ray pulsar at a distance  ≤8 kpc  . We identify the near-infrared counterpart of  SAX J1452.8−5949  to be a late-type main-sequence star at a distance ≤10 kpc, thus ruling out  SAX J1452.8−5949  to be a high-mass X-ray binary. However, with the present X-ray and near-infrared observations, we cannot make any further conclusive conclusion about the nature of  SAX J1452.8−5949  .     

A semi-analytic approach to angular momentum transport in stellar radiative interiors

A novel semi-analytic spectral method, based on eigenfunction expansions, is applied to model the angular momentum transport in stellar radiative interiors. The advantages of our approach are shown by applying it to a spin-down model for a 1M _⊙ main-sequence star. The evolution of the coupling between core and envelope is investigated for different values of the viscosity and different geometries and intensities of the poloidal field. We suggest that a quadrupolar poloidal field may explain the short coupling timescale (τ _c～10 Myr) needed to reproduce the observed rotational evolution of fast rotators on the zero age main sequence, while a dipolar geometry is indicated in the case of slow rotators (τ _c～100 Myr). Our method provides a rigorous analytic treatment of a classic MHD problem and allows us to explore the influence of various parameters on the rotational history of radiative interiors.     

Transpressional tectonics and nappe stacking along the Southern Variscan Front of Morocco

The Southern Variscan Front in the Tinerhir area involves Palaeozoic allochthonous units (Ouaklim and Tilouine units) thrust onto the northern edge of the West African Craton during late Carboniferous time. Illite crystallinity data highlight an anchizonal grade for the Ouaklim Unit, and a diagenesis-anchizone transition for the Tilouine Unit during deformation phase D1. The tectonic stack is crosscut by major dextral reverse faults bounding E–W trending domains of dominant shortening deformation (central domain) and strike-slip deformation (northern and southern domains), later segmented by a network of post-Variscan faults. This complex deformation pattern is the result of kinematic partitioning of dextral transpression along the Southern Variscan Front, coeval with the Neovariscan (300–290 Ma) oblique convergence observed at the scale of the whole Moroccan Variscides. Partitioning of dextral transpression described in the Tinerhir area is consistent with dextral wrench faulting along the Tizi n’ Test Fault, and with Appalachian-style south-directed thrusting in the Tinerhir and Bechar-Bou Arfa areas.     

The use of iron chemical analysis of podzols to date the Late Pleistocene–Holocene deglaciation history of the Central Italian Alps

Podzols that have developed on glacial and periglacial features provide the opportunity to reconstruct glacial evolution after the Last Glacial Maximum (LGM) using different soil indices. Analysing 17 soils classified as podzol, we used the crystallinity ratio of free iron oxides (CRF) on both the A and Bs horizons, and absolute ages for the same landforms containing the soil profile, to create dating curves. Two equations were generated: age = 4566.9 × ln (CRF) + 1760 (1), and age = 3907 × ln (CRF) + 3508.2 (2). The reliability of the curves was evaluated with the Fe_o/Fe_d ratio, and with the difference of ages calculated using both equations. Equation (2) is considered more reliable because the A horizon may be influenced by new pedogenesis on the pre-existing podzol, leading to the development of a new type of soil. By dating the soils, we reconstructed the glacial history of the three main upper branches of the LGM Adda Glacier in the Central Italian Alps, specifically the Stelvio Pass area (ST), Gavia Pass area (GV), and the Val Viola valley (VV). Seven glacial advances were identified at 16.7–14.7 ka (phase I), 12.3 ka (phase II), 11 ka (phase III), 10–9.7 ka (phase IV), 9 ka (phase V), 7.5 ka (phase VI) and 5.3 ka (phase VII). The first five phases are chronologically similar to the main Late Pleistocene–Early Holocene phases recorded in the Central European Alps. The last two Holocene phases, which are both longer in duration than the Little Ice Age, are recorded in ST and GV. Interestingly, these phases generally are not recorded in the rest of the Central European Alps, where the late Holocene glaciers were smaller than their present size.     

Neo-deterministic definition of seismic input for residential seismically isolated buildings

This paper deals with the neo-deterministic definition of the seismic input in the municipality of Nimis (Italy), aimed at the design of residential seismically isolated buildings. The seismic input is defined by the computation of realistic synthetic seismograms considering different levels of detail for the earthquake source, both for a bedrock model and taking into account the specific site conditions. The horizontal response spectrum, calculated in the centre of the municipality by modelling the most dangerous source, advises against the construction of a building with a fixed base, but it is compatible with the seismic isolation, and it has been, therefore, used for the design of a residential seismically isolated building. The maximum displacement for the isolation system has been estimated about 17 cm, a value much lower than that provided by the code design response spectrum (28 cm). The importance of the realistic modelling, which permits the generalization of empirical observations by means of, physically sound, theoretical considerations, is evident, as it allows for the optimisation of the structural design with respect to the site of interest.     

Earthquake‐induced turbidites triggered by sea level oscillations in the Upper Cretaceous and Paleocene of Italy

Earthquakes are widely recognized as triggers for turbidites, submarine debris flows and slumps. In tectonically active areas, surprisingly small changes in stress can trigger seismic events, implying that past sea level changes may be important in controlling the timing of seismicity and the occurrence of turbidites. We apply this idea in an analysis of turbidites from the upper Cretaceous–Paleocene Scaglia Rossa Formation of the Umbria‐Marches region of Italy. These turbidites are composed of resedimented foraminiferal tests derived from fluidizing deep‐water (∼1500 m), pelagic sediments; seismic triggering is the most likely triggering mechanism given this setting and composition. The timing of these turbidites (and associated synsedimentary slumps), constrained by biostratigraphy and magnetostratigraphy, reveals an unusual, non‐random temporal pattern that appears to correlate well with proposed eustatic fluctuations. This correlation between turbidites and eustatic fluctuations leads us to suggest that stress and pore fluid pressure changes associated with changing sea level may trigger periods of increased seismicity in the geological past.     

Comparison of Integrated Geodetic Data Models and Satellite Radar Interferograms to Infer Magma Storage During the 1991–1993 Mt. Etna Eruption

We compare the results obtained from the modelling of EDM, GPS, levelling and tilt data measured in the first part of the 1991–1993 eruption at Etna to the InSAR data acquired during the second part. The geodetic changes are very marked in the first half of the eruption and constrain a deflation source located at a few kilometers of depth ( 3 km b.s.l.), in agreement with other independent geophysical evidence. SAR data, available during the second part of the eruption, were analysed for different time intervals in the second part of the eruption. The interpretation of SAR interferograms reveals a large-scale but less marked deflation of the volcano that could be caused by a deeper source. This second source is in accord with a second deeper anomaly revealed by recent seismic investigations. The combination of geodetic data modelling and SAR images suggests a complex plumbing system composed at least of two possible storage regions located at different depths.