Statistical assessment of air quality interventions

This paper presents a general spatio-temporal model for assessing the air quality impact of environmental policies which are introduced as abrupt changes. The estimation method is based on the EM algorithm and the model allows to estimate the impact on air quality over a region and the reduction of human exposure following the considered environmental policy. Moreover, impact testing is proposed as a likelihood ratio test and the number of observations after intervention is computed in order to achieve a certain power for a minimal reduction. An extensive case study is related to the introduction of the congestion charge in Milan city. The consequent estimated reduction of airborne particulate matters and total nitrogen oxides motivates the methods introduced while its derivation illustrates both implementation and inferential issues.     

Some analytical results about periodic orbits in the restricted three body problem with dissipation

We present some analytical results about the existence of periodic orbits for the planar restricted three body problem with dissipation considered recently by Celletti et?al. (CMDA 109, 265, 2011) We show that, under fairly general conditions on the dissipation term, the circular orbits cannot be continued to the dissipative framework. Moreover, we give general conditions for the occurrence or not of a Hopf bifurcation around the libration points L ₄ and L ₅. Our results are consistent with the numerical findings of Celletti et?al.     

The thermoelastic behavior of clintonite up to 10?GPa and 1,000°C

The thermoelastic behavior of a natural clintonite-1M [with composition: Ca_1.01(Mg_2.29Al_0.59Fe_0.12)_Σ3.00(Si_1.20Al_2.80)_Σ4.00O₁₀(OH)₂] has been investigated up to 10 GPa (at room temperature) and up to 960°C (at room pressure) by means of in situ synchrotron single-crystal and powder diffraction, respectively. No evidence of phase transition has been observed within the pressure and temperature range investigated. P–V data fitted with an isothermal third-order Birch–Murnaghan equation of state (BM-EoS) give V ₀ = 457.1(2) ?³, K _T0 = 76(3)GPa, and K′ = 10.6(15). The evolution of the “Eulerian finite strain” versus “normalized stress” shows a linear positive trend. The linear regression yields Fe(0) = 76(3) GPa as intercept value, and the slope of the regression line leads to a K′ value of 10.6(8). The evolution of the lattice parameters with pressure is significantly anisotropic [β(a) = 1/3K _T0(a) = 0.0023(1) GPa⁻¹; β(b) = 1/3K _T0(b) = 0.0018(1) GPa⁻¹; β(c) = 1/K _T0(c) = 0.0072(3) GPa⁻¹]. The β-angle increases in response to the applied P, with: β_P = β₀ + 0.033(4)P (P in GPa). The structure refinements of clintonite up to 10.1 GPa show that, under hydrostatic pressure, the structure rearranges by compressing mainly isotropically the inter-layer Ca-polyhedron. The bulk modulus of the Ca-polyhedron, described using a second-order BM-EoS, is K _T0(Ca-polyhedron) = 41(2) GPa. The compression of the bond distances between calcium and the basal oxygens of the tetrahedral sheet leads, in turn, to an increase in the ditrigonal distortion of the tetrahedral ring, with ∂α/∂P ≈ 0.1°/GPa within the P-range investigated. The Mg-rich octahedra appear to compress in response to the applied pressure, whereas the tetrahedron appears to behave as a rigid unit. The evolution of axial and volume thermal expansion coefficient α with temperature was described by the polynomial α(T) = α₀ + α₁ T ^−1/2. The refined parameters for clintonite are as follows: α₀ = 2.78(4) 10⁻⁵°C⁻¹ and α₁ = −4.4(6) 10⁻⁵°C^1/2 for the unit-cell volume; α₀(a) = 1.01(2) 10⁻⁵°C⁻¹ and α₁(a) = −1.8(3) 10⁻⁵°C^1/2 for the a-axis; α₀(b) = 1.07(1) 10⁻⁵°C⁻¹ and α₁(b) = −2.3(2) 10⁻⁵°C^1/2 for the b-axis; and α₀(c) = 0.64(2) 10⁻⁵°C⁻¹ and α₁(c) = −7.3(30) 10⁻⁶°C^1/2for the c-axis. The β-angle appears to be almost constant within the given T-range. No structure collapsing in response to the T-induced dehydroxylation was found up to 960°C. The HP- and HT-data of this study show that in clintonite, the most and the less expandable directions do not correspond to the most and the less compressible directions, respectively. A comparison between the thermoelastic parameters of clintonite and those of true micas was carried out.     

Comparison of three geostatistical methods for hydrofacies simulation: a test on alluvial sediments

The hydrodispersive properties of porous sediments are strongly influenced by the heterogeneity at fine scales, which can be modeled by geostatistical simulations. In order to improve the assessment of the properties of three different geostatistical simulation methods (Sequential indicator simulation, SISIM; Transition probability geostatistical simulation, T-PROGS; Multiple point simulation, MPS) a comparison test at different scales was performed for a well-exposed aquifer analogue. In the analysed volume (approximately 30,000?m³) four operative hydrofacies have been recognised: very fine sand and silt, sand, gravelly sand and open framework gravel. Several equiprobable realizations were computed with SISIM, MPS and T-PROGS for a test volume of approximately 400?m³ and for the entire volume, and the different outcomes were compared with visual inspection and connectivity analysis of the very or poorly permeable structures. The comparison of the different simulations shows that the geological model is best reproduced when the simulations are realised separately for each highest rank depositional element and subsequently merged. Moreover, the three methods yield different images of the volume; in particular MPS is efficient in mapping the geometries of the most represented hydrofacies, whereas SISIM and T-PROGS can account for the distribution of the less represented facies.     

Probable late Messinian tsunamiites near Monte Dei Corvi, Italy, and the Nijar Basin, Spain: expected architecture of offshore tsunami deposits

Three distinct, 30- to 80-cm-thick, graded, multilayered, coarse-grained sandstone layers, intercalated in the late Messinian mudstones of the Colombacci formation in Lago Mare facies of the Trave section are interpreted as tsunamiites (Ts1?CTs3). Each of these layers is sheet-like and could be followed along strike over several tens of meters. The lower two layers (Ts1?CTs2) occur in the lower part of the Colombacci formation and the third (Ts3) just below a conspicuous white ??colombacci?? limestone near the top of the formation. The three sandstone layers represent unique sedimentary events within the 120-m-thick San Donato-Colombacci mudstones, which contain many thin, fine-grained, possibly storm-related turbidites. Each of the three clastic layers is overall graded and strongly cross-bedded. A single layer consists of a stack of several graded sublayers that are eroded into the underlying mudstones and into each other. Absence of hummocky cross-stratification (HCS) indicates that the layers are not produced during a large, catastrophic storm event. Current ripples such as dm-sized trough cross-beds suggest strong, prolonged, unidirectional currents, capable of carrying coarse conglomeratic sands. Climbing ripples in middle-fine sand units indicate a high suspension load settling under waning current strength. Each of the Ts1?CTs3 beds satisfies a combination of criteria, described in this paper, that allow interpretation as a tsunamiite in an offshore environment. Tsunamiite Ts2 is underlain by a 15-cm-thick meshwork of synsedimentary fissures, filled with coarse sand. Ground movements induced by strong earthquakes probably caused these crevasses. The uniqueness of each layer, the erosion of the base of each of the sublayers into underlying mudstones and previously deposited sublayer and the consistent stacking of graded sandstone beds within each of the three layers, underlain by earthquake-produced fissures, strongly point to deposition by traction currents produced by the surges of a large tsunami event, triggered by a large vertical fault movements. Vertical fault displacements most likely occurred along the thrust faults like the Sibilline thrust at the SW of the Laga foreland basin, which were active at late Messinian times. A series of cyclic graded turbidites, underlain by seismically induced sand-filled fissures in the Late Messinian Feos formation in SE Spain, are interpreted as tsunamiites produced by a tsunami or seiche.     

Martian atmospheric particulate spectral end-members recovery from PFS and IRIS data

We present an application of a multivariate analyses technique on data returned by the Planetary Fourier Spectrometer (PFS) instrument on board the ESA’s Mars Express (MEX) spacecraft in order to separate the atmospheric contribution from the observed radiation. We observe that Thermal/Far Infrared spectra returned from Mars, covering almost a whole martian year, can be represented by a linear model using a limited set of end-member spectra. We identify the end-members as the suspended mineral dust and water ice clouds, but no surface signature was found. We improve previous studies performed with data from the Thermal Emission Spectrometer (TES) thanks to the higher spectral resolution of PFS. This allows for distinguishing narrow gaseous bands present in the martian atmosphere. Furthermore, the comparison of results from PFS and TES with data collected in 1971 by the Mariner 9 Infrared Interferometer Spectrometer (IRIS) shows an atmospheric dust component with similar spectral behavior. This might indicate homogeneity of the dust source regions over a time period of more than 30 years.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

Using Laser Beacons for Daytime Adaptive Optics

This article examines the use of Laser Beacons for daytime astronomical observations. There are two potential applications: the diffraction limited observation of (1) the structure in the solar corona at all wavelengths, and (2) non-solar astronomical objects in the thermal infrared part of the spectrum. We examine the brightness of the Laser Beacon required as well as the limitations imposed by the daytime sky brightness and sky/telescope thermal emission on the observable magnitude limits. For both applications the use of Laser Beacon adaptive optics in daytime results in important research opportunities.     

A Global Inventory of Burned Areas at 1 Km Resolution for the Year 2000 Derived from Spot Vegetation Data

Biomass burning constitutes a major contribution to global emissions of carbon dioxide, carbon monoxide, methane, greenhouse gases and aerosols. Furthermore, biomass burning has an impact on health, transport, the environment and land use. Vegetation fires are certainly not recent phenomena and the impacts are not always negative. However, evidence suggests that fires are becoming more frequent and there is a large increase in the number of fires being set by humans for a variety of reasons. Knowledge of the interactions and feedbacks between biomass burning, climate and carbon cycling is needed to help the prediction of climate change scenarios. To obtain this knowledge, the scientific community requires, in the first instance, information on the spatial and temporal distribution of biomass burning at the global scale. This paper presents an inventory of burned areas at monthly time periods for the year 2000 at a resolution of 1 kilometer (km) and is available to the scientific community at no cost. The burned area products have been derived from a single source of satellite-derived images, the SPOT VEGETATION S1 1 km product, using algorithms developed and calibrated at regional scales by a network of partners. In this paper, estimates of burned area, number of burn scars and average size of the burn scar are described for each month of the year 2000. The information is reported at the country level. This paper makes a significant contribution to understanding the effect of biomass burning on atmospheric chemistry and the storage and cycling of carbon by constraining one of the main parameters used in the calculation of gas emissions.     

Interactions of river discharge and tidal modulation in a tropical estuary, NE Brazil

Observations of thermohaline properties and currents were undertaken in the Curimataú River estuary (6°18′S), Rio Grande do Norte state (RN), Brazil, during consecutive neap–spring tidal cycles in the austral autumn rainy season. Highly asymmetric neap tide along channel velocities (−0.4 to 0.9 m s⁻¹) and highly stratified conditions were generated by an increase of the buoyancy energy from the freshwater input (R _iE≈5.6). During the spring-tidal cycle the river discharge decreased and the longitudinal velocity components were higher, less asymmetrical (−0.8 to 1.1 m s⁻¹) and semidiurnal, associated with moderately stratified conditions (R _iE≈0.1) due to the increase of the kinetic tidal energy forcing mechanism. The overall salinity variation from surface to bottom during two tidal cycles was from 20.5 to 36.3 and 29 to 36.7 in the neap and spring tide experiments, respectively; in the last experiment, the tropical water (TW) mass intrusion was enhanced. The net salt transport reversed from down to up estuary during the neap and spring tide experiments, respectively, varied from 6.0 to –2.0 kg m⁻¹ s⁻¹, an indication of changes in the main forcing of the estuary dynamics. Evaluation of a classical steady analytical model, in comparison with nearly steady experimental vertical profiles of velocity, shows an agreement classifiable as reasonably fair.