Carbon dioxide in Postojna Cave (Slovenia): spatial distribution,seasonal dynamics and evaluation of plausible sources and sinks

The CO₂ concentration of the air in Postojna Cave (400–7900 ppm) is found to be induced by CO₂ sources (human respiration contributing?~?20,000–58,000 ppm per breath, outgassing of dripwater and water seeping from the vadose zone/epikarst with a pCO₂ values of 5000–29,000 ppm, and underground Pivka River having pCO₂ at 2344–4266 ppm) and CO₂ dilution (inflow of outside air with a CO₂ concentration of?~?400 ppm). Measurements show that sinking Pivka River has the lowest CO₂ concentration among plausible CO₂ sources but still continuously exceeds the surrounding cave air CO₂ concentration. During the winter months, intensive ventilation reduces the cave air CO₂ concentration to outside levels (~?400 ppm), even in the centre of the cave system. CO₂ dilution is less pronounced in summer (CO_2(min)?≈?800 ppm), since the ventilation rate is not as strong as in winter and the outside air that enters the cave through breathing holes and fractures is enriched with soil CO₂. During spring and autumn, the daily alternation of the ventilation regime with a smaller rate of air exchange results in yearly cave air CO₂ peaks of up to?~?2400 ppm. Some dead-end passages can be much less affected by ventilation, resulting in a cave air CO₂ concentration of up to 7900 ppm. The strongest diurnal CO₂ peaks due to human respiration were recorded during the spring holidays (increase of up to 1300 ppm day^?1), compared to considerably smaller summer peaks despite peak visits (increase of?~?600 ppm day^?1).     

Material ejection

This paper reviews the major discussions and conclusions of the Flares 22 Workshop concerning the physical processes involved in mass ejecta events, with an emphasis on large-scale phenomena, especially Coronal Mass Ejections (CMEs). New insights have been gained from recent data obtained from the SMM andYohkoh spacecraft and from several new ground-based radio and optical instruments, as well as from theoretical advances concerning the origins, driving mechanisms and long-term evolution of CMEs.Report of Team 5, Flares 22 Workshop, Ottawa, May 25–28, 1993.     

Hydrothermal synthesis of kaolinite illustrated by X-ray diffractograms and scanning electron micrographs,part II

Summary The hydrothermal synthesis of kaolinite from various alumina and silica starting materials reacted at 200°C in aqueous solutions of oxalic acid and H₂SO₄ with the corresponding saturated water vapour pressure, in periods of time from 10 to 25 days, has been followed by X-ray diffraction measurements, scanning electron microscopy, and energy dispersive analysis of the products. The temperature and time periods of reactions were chosen on the basis of previously collected data on the effects of H₄EDTA, a complex-forming agent, and of H₂SO₄, an inorganic acid, on the rate of formation of kaolinite. Aluminium-complexing acids increase the rate of formation or decrease the temperature of formation of kaolinite as shown by evidence from X-ray diffraction patterns. The influence of the starting materials as sources of aluminum, amorphous aluminum hydroxides, pseudoboehmite, allophane or gibbsite, has also been examined by X-ray diffraction, scanning electron microscopy, and by energy dispersive analysis. Scanning electron micrographs indicated that silica is a more mobile phase than alumina, based on the progressive formation of a thin coating on gibbsite during early reaction, then by growth of clusters of platy crystals of kaolin, and finally by production of pellets of stacked crystal flakes. Where gibbsite was used in the reaction mixture, boehmite was commonly observed as an intermediate phase.With 16 Figures     

From inflexible national legislation to flexible local governance: management practices in the Pelister National Park,Republic of Macedonia

The involvement of local people in protected area management a key factor in the sustainable and efficient protection of wildlife, and an economically preferable approach for the effective everyday care and protection of the environment. This paper aims to explore the community participation and protected area management challenges faced by national park authorities in developing countries, through a case study of the Pelister National Park in the Republic of Macedonia. The paper focuses on the multiple social, economic and political expressions of flexibility in national park management at the local scale. These examinations are based on field research in Pelister, executed in the summer of 2006, and involving 20 in-depth interviews with local policy-makers, nature protection experts and local inhabitants, as well as a questionnaire survey of 140 residents of three villages in and around the park (Nizhepole, Malovishta and Brajchino).     

Submerged caves of Croatia: distribution,classification and origin

Presently, 235 submerged caves and pits have been recorded along the Croatian coast and islands, partly or completely submerged by sea water. Contrary to the inland situation, recorded submerged features are predominantly horizontal (60%), though there are indications that the real situation is similar to that of the continental part where 69% are vertical pits. Completely marine conditions are established in 126 caves and the rest are anchihaline caves and submarine springs. Speleothems are found in more than 140 caves. By their origin, the investigated caves are all continental features formed in Mesozoic and Palaeogene carbonates, subsequently submerged owing to sea transgression. Due to the relatively low wave energy, rapid sea level rise and maturity of the host rock, they do not fit into concepts of a sea cave or a flank margin cave development, but they fulfil several conditions for being the blue holes. Since the term ‘blue hole’ is mainly associated with the Bahamian karst, our attempt is only to show the possible similarities with no intention of ascribing that term to the Croatian caves. Beside karstological issues, Croatian submerged caves are unique environmental, archaeological and tourism assets.     

The Jurassic Prehodavci Formation of the Julian Alps: easternmost outcrops of Rosso Ammonitico in the Southern Alps (NW Slovenia)

The Julian Alps are located in NW Slovenia and structurally belong to the Julian Nappe where the Southern Alps intersect with the Dinarides. In the Jurassic, the area was a part of the southern Tethyan continental margin and experienced extensional faulting and differential subsidence during rifting of the future margin. The Mesozoic succession in the Julian Alps is characterized by a thick pile of Upper Triassic to Lower Jurassic platform limestones of the Julian Carbonate Platform, unconformably overlain by Bajocian to Tithonian strongly condensed limestones of the Prehodavci Formation of the Julian High. The Prehodavci Formation is up to 15 m thick, consists of Rosso Ammonitico type limestone and is subdivided into three members. The Lower Member consists of a condensed red, well-bedded bioclastic limestone with Fe–Mn nodules, passing into light-grey, faintly nodular limestone. The Middle Member occurs discontinuously and consists of thin-bedded micritic limestone. The Upper Member unconformably overlies the Lower or Middle Members. It is represented by red nodular limestone, and by red-marly limestone with abundant Saccocoma sp. The Prehodavci Formation unconformably overlies the Upper Triassic to Lower Jurassic platform limestone of the Julian Carbonate Platform; the contact is marked by a very irregular unconformity. It is overlain by the upper Tithonian pelagic Biancone (Maiolica) limestone. The sedimentary evolution of the Julian High is similar to that of Trento Plateau in the west and records: (1) emergence and karstification of part of the Julian Carbonate Platform in the Pliensbachian, or alternatively drowning of the platform and development of the surface by sea-floor dissolution; (2) accelerated subsidence and drowning in the Bajocian, and onset of the condensed pelagic sedimentation (Prehodavci Formation) on the Julian High; (3) beginning of sedimentation of the Biancone limestone in the late Tithonian.     

Inverse modeling of natural tracer transport in a granite massif with lumped-parameter and physically based models: case study of a tunnel in Czechia

This study deals with numerical modelling of hydraulic and transport phenomena in granite of the Bohemian massif in Bedrichov, Czechia (Czech Republic). Natural tracers represented by stable isotopes δ¹⁸O and δ²H were collected at the tunnel outflow points and nearby catchment and their concentrations were monitored for seven years. The study compared transport simulations by a two-dimensional (2D) physically based model (advection-dispersion) developed in Flow123d software and a simpler lumped-parameter model, calculated with FLOWPC. Both variants were calibrated with UCODE software, either fitting the concentration data alone, or including the tunnel inflow rates in the case of the 2D model calibration (either in separate steps or within a single optimization problem). Since each of the models describes the tracer transport with different parameters, the models were compared based on the mean transit time as a postprocessed quantity. Besides this, two different options for processing the recharge data (input for both models) were evaluated. Calibration and data interpretation were possible for three of the four observed places in the tunnel, thus determining the depth limit of applicability of the stable isotopes. The estimates for discharge sampling at 25–35 m depth based on inverse modelling provide reasonable values of mean transit time (20–40 months) for the lumped parameter models, little revising the results of previous studies at the site. The resulting transport parameters of the advection-dispersion model (porosity and dispersivity) are in accordance with the hydrogeological structures present at the sampling sites.

     

Towards hydrological triggering mechanisms of large deep-seated landslides

It is a widely accepted idea that hydrologically triggered deep-seated landslides are initiated by an increase in pore-water pressure on potential slip surface induced by rising groundwater level after prolonged period of intense rainfall although the process is not fully understood. In order to contribute to better understanding, the rainfall–groundwater relationships, hydrogeological monitoring and repeated geoelectrical imaging were carried out from March 2007 to April 2011 in large deep-seated landslide near ?ubietová (Western Carpathians) catastrophically reactivated at the end of February 1977. Based on our observations, groundwater level (GWL) response to precipitation differs considerably with respect to both overall hydrological conditions and GWL mean depth. While the rate of GWL increase up to 25 cm/day were measured after some rainfall events during wet periods, noticeably lower recharge rate (up to 1–2 cm/day) and delayed GWL response to rainfall (usually from 2 weeks to 2–4 months) were observed at the beginning of the wet season after considerable depression of GWLs due to previous effective rainfall deficit. Likewise, slow GWL fluctuations without short-term oscillations are typical for deeper GWLs. Thus, long-term (several seasons to several years) hydrological conditions affect markedly groundwater response to rainfall events in the studied landslide and can be crucial for its behaviour. Comparison of hydrological conditions characterising the analysed period with those that accompanied the landslide reactivation in 1977 allow us to assume that slightly above-average rainy season following the prolonged wet period can be far more responsible for movement acceleration (and possibly failure initiation) in deep landslides than the isolated season of extreme precipitation following a longer dry period. This is true especially for landslides in regions with significant seasonal temperature changes where potential effective precipitation (PEP), calculated as excess of precipitation (P) over potential evapotranspiration (PET), may be efficiently used for estimation of slope saturation condition.     

Epigenetic dolomitization of the Přaídolí formation (Upper Silurian), the Barrandian basin,Czech Republic: implications for burial history of Lower Paleozoic strata

Stratabound epigenetic dolomite occurs in carbonate facies of the Barrandian basin (Silurian and Devonian), Czech Republic. The most intense dolomitization is developed in bioclastic calcarenites within the transition between micritic limestone and shaledominated Přídolí and Lochkov formations deposited on a carbonate slope. Medium-crystalline (100–400 μm), inclusion-rich, xenotopic matrix dolomite (δ ¹⁸O=−4.64 to −3.40‰ PDB;δ ¹³C=+1.05 to +1.85‰ PDB) which selectively replaced most of the bioclastic precursor is volumetrically the most important dolomite type. Coarse crystalline saddle dolomite (δ ¹⁸O=−8.04 to −5.14‰ PDB;δ ¹⁸C=+0.49 to +1.49 PDB) which precipitated in fractures and vugs within the matrix dolomite represents a later diagenetic dolomitization event. In some vugs, saddle dolomite coprecipitated with petroleum inclusion-rich authigenic quartz crystals and minor sulfides which, in turn, were post-dated by semisolid asphaltic bitumen. The interpretation of the dolomitization remains equivocal. Massive xenotopic dolomite, although generally characteristic of a deeper burial setting, may have been formed by a recrystallization of an earlier, possibly shallow burial dolomite. Deeper burial recrystallization by reactive basinal pore fluids that presumably migrated through the more permeable upper portion of the Přídolí sequence appears as a viable explanation for this dolomitization overprint. Saddle dolomite cement of the matrix dolomite is interpreted as the last dolomitization event that occurred during deep burial at the depth of the oil window zone. The presence of saddle dolomite, the fluid inclusion composition of associated quartz crystals, and vitrinite paleogeothermometry of adjacent sediments imply diagenetic burial temperatures as high as 160°C. Although high geothermal gradients in the past or the involvement of hydrothermally influenced basinal fluids can account for these elevated temperatures, burial heating beneath approximately 3-km-thick sedimentary overburden of presumably post-Givetian strata, no longer preserved in the basin, appears to be the most likely interpretation. This interpretaion may imply that the magnitude of post-Variscan erosion in the Barrandian area was substantially greater than previously thought.     

Age and geochemical constraints for partial melting of granulites in Estonia

Summary The rocks of the crystalline basement of the East European Craton in southern Estonia show effects of partial melting under granulite facies conditions. Zircons extracted from partial melting products (tonalite from the Tapa Zone – 1824 ± 26, tonalite from the South Estonian Zone – 1788 ± 16 Ma and charnockite from the Tapa Zone – 1761 ± 11 Ma) yield U–Pb crystallisation ages that span over approximately 80 Ma, suggesting a prolonged high-grade metamorphism or several separate events. U–Pb zircon age of one sample of charnockite is concordant with the Nd model age of partial melting of its host mafic granulite facies gneiss (intercept at 1.76 Ga). Linear geochemical trends and similar initial Nd isotopic compositions of mafic granulites and charnockites suggest their possible genetic relationship. From our new and previously published data it follows that the peak granulite metamorphic conditions and formation of tonalites and charnockites (850 °C and 6 kbar) in the Estonian basement occurred at 1788–1778 Ma. Then, the rocks cooled down, passing through the garnet closure temperature of approximately 650–700 °C at 1728 ± 24 Ma. The age of metamorphism of the Estonian granulites is lower than the metamorphic ages known from southern Finland, but it is similar to the age of metamorphism reported from the Belarus-Baltic Granulite Belt in Latvia.