Effect of diurnal and seasonal temperature variation on Cussac cave ventilation using co2 assessment

Cussac cave was investigated to assess the cave air temperature variations and to understand its ventilation regime. This cave is located in an active karst system in the south west part of France. It has a single entrance and is considered as a cold air trap. In this study, air mass exchanges were probed. Measurements of temperature and Pco₂ with a 30-min frequency were made in several locations close to the cave entrance. Speed of the air flow was also measured at the door of cave entrance. Results show that cave air Pco₂ varies from 0.18 to 3.33 %. This cave appears to be a CO₂ source with a net mass of 2319 tons blown in 2009. Carbon-stable isotope of CO₂ (¹³Cco₂) ranges from −20.6 ‰ in cold season to −23.8 ‰ in warm season. Cave air is interpreted as a result of a mix between external air and an isotopically depleted air, coming from the rock environment. The isotopic value of the light member varies through time, from −23.9 to −22.5 ‰. Furthermore, this study ascertains that the cave never stops in communicating with the external air. The ventilation regime is identified. (1) In cold season, the cave inhales at night and blows a little at the warmest hours. However, in warm season, (2) cave blows at night, but (3) during the day, a convection loop takes place in the entrance area and prevents the external air from entering the cave, confirming the cold air trap.

     

Underground pumped storage hydroelectricity using abandoned works (deep mines or open pits) and the impact on groundwater flow

Underground pumped storage hydroelectricity (UPSH) plants using open-pit or deep mines can be used in flat regions to store the excess of electricity produced during low-demand energy periods. It is essential to consider the interaction between UPSH plants and the surrounding geological media. There has been little work on the assessment of associated groundwater flow impacts. The impacts on groundwater flow are determined numerically using a simplified numerical model which is assumed to be representative of open-pit and deep mines. The main impact consists of oscillation of the piezometric head, and its magnitude depends on the characteristics of the aquifer/geological medium, the mine and the pumping and injection intervals. If an average piezometric head is considered, it drops at early times after the start of the UPSH plant activity and then recovers progressively. The most favorable hydrogeological conditions to minimize impacts are evaluated by comparing several scenarios. The impact magnitude will be lower in geological media with low hydraulic diffusivity; however, the parameter that plays the more important role is the volume of water stored in the mine. Its variation modifies considerably the groundwater flow impacts. Finally, the problem is studied analytically and some solutions are proposed to approximate the impacts, allowing a quick screening of favorable locations for future UPSH plants.     

VIRGO: Experiment for helioseismology and solar irradiance monitoring

The scientific objective of the VIRGO experiment (Variability of solar IRradiance and Gravity Oscillations) is to determine the characteristics of pressure and internal gravity oscillations by observing irradiance and radiance variations, to measure the solar total and spectral irradiance and to quantify their variability over periods of days to the duration of the mission. With these data helioseismological methods can be used to probe the solar interior. Certain characteristics of convection and its interaction with magnetic fields, related to, for example, activity, will be studied from the results of the irradiance monitoring and from the comparison of amplitudes and phases of the oscillations as manifest in brightness from VIRGO, in velocity from GOLF, and in both velocity and continuum intensity from SOI/MDI. The VIRGO experiment contains two different active-cavity radiometers for monitoring the solar constant, two three-channel sunphotometers (SPM) for the measurement of the spectral irradiance at 402, 500 and 862 nm, and a low-resolution imager (LOI) with 12 pixels, for the measurement of the radiance distribution over the solar disk at 500 um. In this paper the scientific objectives of VIRGO are presented, the instruments and the data acquisition and control system are described in detail, and their measured performance is given.died 13 October 1994     

Effective two-phase flow through highly heterogeneous porous media: Capillary nonequilibrium effects

We consider the two-phase flow through a dual-porosity medium, characterized by a period of heterogeneity ω, a ratio of global permeabilities ∈_K, and a ratio of the order of capillary forces ∈_c. The limit when ω tends to zero at different values of ∈_K and ∈_c gives four classes of global behavior, differing by the type of elementary flows at the one-cell level. We propose a diagram of their predominance. A macro-scale model is constructed by formal homogenization techniques for one of these classes; it shows a nonlinear kinetic relationship for the averaged capillary pressure functions, and leads to a decomposition for the effective phase permeability tensors. A capillary relaxation time is explicitly determined. This revised version was published online in August 2006 with corrections to the Cover Date.     

Remplacements isomorphiques par synthèses hydrothermales dans les silicates fluores: Topaze et zunyite

The substituted topaz Al₂GeO₄(OH,F)₂, Al₂(Si_xGe_1-x)O₄(OH,F)₂ and Ga₂GeO₄(OH,F)₂, as well as the substituted zunyite Al₁₃Ge₅O₂₀(OH,F)₁₆F₂Cl have been synthetised. The unit-cell parameters of these artificial minerals, isomorphs of natural compounds, have been determined; the corresponding lists of d_hkl are given. The study by I.R. spectroscopy of these compounds with a total or a partial replacement of Si by Ge in the same way as Ga-Ge topaz suggests the assignment of certain absorption bands to characteristic structural groups. The thermal decomposition of AlSi and AlGe topaz into mullite has been studied.     

Statistical Characterization of the Flow Structure in the Rhine Valley

The flow structure at the intersection between the Rhine and the Seez valleys nearthe Swiss city of Bad Ragaz has been documented by means of wind and pressuremeasurements collected from 9 September to 10 November 1999 during the MesoscaleAlpine Programme (MAP) experiment. To understand better the dynamics of theageostrophic winds that develop in this part of the Rhine valley, some key questionsare answered in this paper including the following: (i) How does air blow at theintersection of the Rhine and Seez valleys? and (ii) what are the dynamical processes(mechanical or thermal) driving the flow circulations in the valleys? Statistical analysis of the wind and pressure patterns at synoptic scale and at the scaleof the valley shows that five main flow patterns, SE/S, NW/W, NW/N, NW/S, SE/N(wind direction in the Seez valley/wind direction in the Rhine valley) prevail. The SE/S regime is the flow splitting situation. It is mainly driven by a strong pressure gradient across the Alps leading to foehn, even though some nocturnal cases are generated bylocal thermal gradients. The NW/W and NW/N regimes are mechanically forced bythe synoptic pressure gradient (as the flow splitting case). The difference between thetwo regimes is due to the synoptic flow direction [westerly (northerly) synoptic flowfor the NW/W (NW/N) regime], showing that the Rhine valley (particularly from BadRagaz to Lake Constance) is less efficient in channelling the flow than the Seez valley.The NW/S (occurring mainly during nighttime) and SE/N (occurring mainly duringdaytime) regimes are mainly katabatic flows. However, the SE/N regime is also partlyforced at the synoptic scale during the foehn case that occurred between 18 October and 20 October 1999, with a complex layered vertical structure. This analysis also shows that, contrary to what was observed in a broad section of theupper Rhine valley near Mannheim, very few countercurrents were observed near BadRagaz where the valley width is much smaller.     

Les minéralisations Cu(NiBiUAuAg) d'Ifri (district du Haut Seksaoua,Maroc) : apport de l'étude texturale au débat syngenèse versus épigenèse

The Cu ore of Ifri is a chalcopyrite stockwork hosted by Cambrian formations and was until now interpreted as a syngenetic massive sulphide deposit. Textural studies highlight two generations of pyrite early (Py I) and late (Py II) with respect to the regional deformation. The chalcopyrite stockwork overprinted Py II, outlining the epigenetic nature of the Cu mineralization. Regarding the origin of Cu-depositing fluids, the presence in the stockwork paragenesis of an U, W, Sn association and preliminary Pb/Pb dating of a brannerite belonging to this association suggest a contribution of the Tichka granite. To cite this article: L. Barbanson et al., C. R. Geoscience 335 (2003).     

From strike-slip faulting to oblique subduction: A survey of the Alpine Fault-Puysegur Trench transition,New Zealand,results of cruise Geodynz-sud leg 2

The Geodynz-sud cruise on board the R/V l'Atalante collected bathymetric, side-scan sonar and seismic reflection data along the obliquely convergent boundary between the Australian and Pacific plates southwest of the South Island, New Zealand. The survey area extended from 44°05 S to 49°40 S, covering the transition zone between the offshore extension of the Alpine Fault and the Puysegur Trench and Puysegur Ridge. Based on variations in the nature and structure of the crust on either side of the margin, the plate boundary zone can be divided into three domains with distinctive structural and sedimentary characteristics. The northern domain involves subduction of probably thinned continental crust of the southern Challenger Plateau beneath the continental crust of Fiordland. It is characterized by thick sediments on the downgoing slab and a steep continental slope disrupted by fault scarps and canyons. The middle domain marks the transition between subduction of likely continental and oceanic crust defined by a series of en echelon ridges on the downgoing slab. This domain is characterized by a large collapse terrace on the continental slope which appears to be due to the collision of the en echelon ridges with the plate margin. The southern domain involves subduction of oceanic crust beneath continental and oceanic crust. This domain is characterized by exposed fabric of seafloor spreading on the downgoing slab, a steep inner trench wall and linear ridges and valleys on the Puysegur ridge crest. The data collected on this cruise provide insights into the nature and history of both plates, and factors influencing the distribution of strike-slip and compressive strain and the evolution of subduction processes along a highly oblique convergent margin.